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| 1 | Rational design of MoS_(2) nanosheets decorated on mesoporous hollow carbon spheres as a dual-functional accelerator in sulfur cathode for advanced pouch-type Li–S batteries显示文摘Developing sulfur cathodes with high catalytic activity on accelerating the sluggish redox kinetics of lithium polysulfides(Li PSs) and unveiling their mechanisms are pivotal for advanced lithium–sulfur(Li–S)batteries. Herein, MoS2 is verified to reduce the Gibbs free energy for rate-limiting step of sulfur reduction and the dissociation energy of lithium sulfide(Li2 S) for the first time employing theoretical calculations. The Mo S2 nanosheets coated on mesoporous hollow carbon spheres(MHCS) are then reasonably designed as a sulfur host for high-capacity and long-life Li–S battery, in which MHCS can guarantee the high sulfur loading and fast electron/ion transfer. It is revealed that the shuttle effect is efficiently inhibited because of the boosted conversion of Li PSs. As a result, the coin cell based on the MHCS@Mo S2-S cathode exhibits stable cycling performance maintaining 735.7 mAh g^(-1) after 500 cycles at 1.0 C. More importantly, the pouch cell employing the MHCS@Mo S2-S cathodes achieves high specific capacity of1353.2 m Ah g^(-1) and prominent cycle stability that remaining 960.0 m Ah g^(-1) with extraordinary capacity retention of 79.8% at 0.1 C after 170 cycles. Therefore, this work paves a new avenue for developing practical high specific energy and long-life pouch-type Li–S batteries. | Qinjun Shao Pengfei Lu Lei Xu Decai Guo Jing Gao Zhong Shuai Wu jian Chen | 2020 | Journal of Energy Chemistry2020，29，12： | 7 |
| 2 | Temperature-induced Lifshitz transition in topological insulator candidate HfTe_5显示文摘The ongoing discoveries and studies of novel topological quantum materials have become an emergent and important field of condensed matter physics.Recently,HfTe_5 ignited renewed interest as a candidate of a novel topological material.The single-layer HfTe_5 is predicted to be a two-dimensional large band gap topological insulator and can be stacked into a bulk that may host a temperature-driven topological phase transition.Historically,HfTe_5 attracted considerable interest for its anomalous transport properties characterized by a peculiar resistivity peak accompanied by a sign reversal carrier type.The origin of the transport anomaly remains under a hot debate.Here we report the first high-resolution laser-based angle-resolved photoemission measurements on the temperature-dependent electronic structure in HfTe_5.Our results indicated that a temperature-induced Lifshitz transition occurs in HfTe_5,which provides a natural understanding on the origin of the transport anomaly in HfTe_5.In addition,our observations suggest that HfTe_5 is a weak topological insulator that is located at the phase boundary between weak and strong topological insulators at very low temperature. | Yan Zhang Chenlu Wang Guodong Liu Aiji Liang Lingxiao Zhao Jianwei Huang Qiang Gao Bing Shen Jing Liu Cheng Hu Wenjuan Zhao Genfu Chen Xiaowen Jia Li Yu Lin Zhao Shaolong He Fengfeng Zhang Shenjin Zhang Feng Yang Zhimin Wang Qinjun Peng Zuyan Xu Chuangtian Chen Xingjiang Zhou | 2017 | Science Bulletin2017，62，13： | 4 |
| 3 | Incorporation of layered tin(Ⅳ) phosphate in graphene framework for high performance lithium-sulfur batteries显示文摘To anchor the polysulfide and enhance the conversion kinetics of polysulfide to disulfide/sulfide is critical for improving the performance of lithium-sulfur battery.For this purpose,the graphene-supported tin(Ⅳ) phosphate(Sn(HPO_4)_2·H_2 O,SnP) composites(SnP-G) are employed as the novel sulfur hosts in this work.When compared to the graphene-sulfur and carbon-sulfur composites,the SnP-G-sulfur composites exhibit much better cycling performance at 1.0 C over 800 cycles.Meanwhile,the pouch cell fabricated with the SnP-G-sulfur cathodes also exhibits excellent performance with an initial capacity of1266.6 mAh g^(-1)(S) and capacity retention of 76.9% after 100 cycles at 0.1 C.The adsorption tests,density functional theory(DFT) calculations in combination with physical cha racterizations and electrochemical measurements provide insights into the mechanism of capture-accelerated conversion mechanism of polysulfide at the surface of SnP.DFT calculations indicate that the Li-O bond formed between Li atom(from Li_2 S_n,n=1,2,4,6,8) and O atom(from PO_3-OH in SnP) is the main reason for the strong interactions between Li_2 S_n and SnP.As a result,SnP can effectively restrain the shuttle effect and improving the cycling performance of Li-S cell.In addition,by employing the climbing-image nudged elastic band(ciNEB) methods,the energy barrier for lithium sulfide decomposition(charging reaction) on SnP is proved to decrease significantly compared to that on graphene.It can be concluded that SnP is an effective sulfur hosts acting as dual-functional accelerators for the conversion reactions of polysulfude to sulfide(discharging reaction) as well as polysulfide to sulfur(charging reaction). | Haifeng Yuan Na Zhang Leiwu Tian Lei Xu Qinjun Shao Syed Danish Ali Zaidi Jianping Xiao Jian Chen | 2021 | Journal of Energy Chemistry2021，30，2： | 2 |
| 4 | Emergence of superconductivity from fully incoherent normal state in an iron-based superconductor (Ba_(0.6)K_(0.4))Fe_2As_2显示文摘In unconventional superconductors, it is generally believed that understanding the physical properties of the normal state is a pre-requisite for understanding the superconductivity mechanism. In conventional superconductors like niobium or lead, the normal state is a Fermi liquid with a well-defined Fermi surface and well-defined quasipartcles along the Fermi surface. Superconductivity is realized in this case by the Fermi surface instability in the superconducting state and the formation and condensation of the electron pairs(Cooper pairing). The high temperature cuprate superconductors, on the other hand, represent another extreme case that superconductivity can be realized in the underdoped region where there is neither well-defined Fermi surface due to the pseudogap formation nor quasiparticles near the antinodal regions in the normal state. Here we report a novel scenario that superconductivity is realized in a system with well-defined Fermi surface but without quasiparticles along the Fermi surface in the normal state.High resolution laser-based angle-resolved photoemission measurements have been performed on an optimally-doped iron-based superconductor(Ba_(0.6)K_(0.4))Fe_2As_2. We find that, while sharp superconducting coherence peaks emerge in the superconducting state on the hole-like Fermi surface sheets, no quasiparticle peak is present in the normal state. Its electronic behaviours deviate strongly from a Fermi liquid system. The superconducting gap of such a system exhibits an unusual temperature dependence that it is nearly a constant in the superconducting state and abruptly closes at Tc. These observations have provided a new platform to study unconventional superconductivity in a non-Fermi liquid system. | Jianwei Huang Lin Zhao Cong Li Qiang Gao Jing Liu Yong Hu Yu Xu Yongqing Cai Dingsong Wu Ying Ding Cheng Hu Huaxue Zhou Xiaoli Dong Guodong Liu Qingyan Wang Shenjin Zhang Zhimin Wang Fengfeng Zhang Feng Yang Qinjun Peng Zuyan Xu Chuangtian Chen Xingjiang Zhou | 2019 | Science Bulletin2019，64，1： | 1 |
| 5 | The effect of oxygen on the epitaxial growth of diamond显示文摘We studied the effect of oxygen on the growth quality of diamond epitaxial layers. After oxygen is added during the growth of the diamond epitaxial layer, as the thickness of the epitaxial layer increases, the full width at half maximum of the rocking curve of the(004) plane of diamond epitaxial layer increases continuously, and, in addition, the intensities of both the Raman peaks and the free exciton emission peaks of the diamond epitaxial layer decrease continuously. These experimental results demonstrate that as the thickness of the diamond epitaxial layer increases, the quality of the diamond epitaxial layer degrades. The strong etching effect of the OH radical groups in the plasma on the diamond epilayers leads to the degradation of their crystallinity. | Meng Gong Yanan Chen Wancheng Yu Peng Jin Zhanguo Wang Zhimin Wang Shenjin Zhang Feng Yang Fengfeng Zhang Qinjun Peng Zuyan Xu | 2018 | Journal of Semiconductors2018，39，12： | 1 |
| 6 | Frequency of mitochondrial 12S rRNA gene A1555G and 961 insC mutations among children with sensorineural deafness in China显示文摘Objective: To investigate the frequency of mitochondrial 12S rRNA gene A1555G and 961 insC mutations among Chinese with sensorineural deafness. Methods: Blood samples from 78 sporadic cases with sensorineural deafness were obtained and DNA was extracted from the leukocytes, then the mitochondrial DNA target fragments were amplified by polymerase chain reaction(PCR). The 1555G mutations were detected by BsmA I restriction endonuclease digestion, every fragment was analyzed by sequencing; All the 961 insC mutation were detected by direct sequencing. Results: The percent age of A1555G mutation and mt961C insertion were 6.4% and 2.6% in the hearing-impaired Chinese subjects respectively. Conclusion: A1555G and 961insC mutations in mitochondrial DNA 12S rRNA gene regions may play a role in the pathogenesis of hearing loss in the sporadic cases. | Xia Xu Guangqian Xing Qinjun Wei Zhibin Chen Hongbo Cheng Xin Cao Xingkuan Bu | 2006 | Journal of Nanjing Medical University2006，20，5： | 1 |
| 7 | Non-invasive glucose sensing with near-infrared spectroscopy enhanced by optical measurement eonditions reproduction technique显示文摘 | Qiu Qinjun Jiang Jingying | 2005 | Optics and Lasers in Engineering2005，13，10： | 1 |
| 8 | Intravenous route to choroidal neovascularization by macrophage-disguised nanocarriers for mTOR modulation显示文摘Retinal pigment epithelial(RPE) is primarily impaired in age-related macular degeneration(AMD), leading to progressive loss of photoreceptors and sometimes choroidal neovascularization(CNV). mTOR has been proposed as a promising therapeutic target, while the usage of its specific inhibitor,rapamycin, was greatly limited. To mediate the mTOR pathway in the retina by a noninvasive approach, we developed novel biomimetic nanocomplexes where rapamycin-loaded nanoparticles were coated with cell membrane derived from macrophages(termed as MRaNPs). Taking advantage of the macrophage-inherited property, intravenous injection of MRaNPs exhibited significantly enhanced accumulation in the CNV lesions, thereby increasing the local concentration of rapamycin. Consequently, MRaNPs effectively downregulated the mTOR pathway and attenuate angiogenesis in the eye. Particularly, MRaNPs also efficiently activated autophagy in the RPE, which was acknowledged to rescue RPE in response to deleterious stimuli. Overall, we design and prepare macrophage-disguised rapamycin nanocarriers and demonstrate the therapeutic advantages of employing biomimetic cell membrane materials for treatment of AMD. | Weiyi Xia Chao Li Qinjun Chen Jiancheng Huang Zhenhao Zhao Peixin Liu Kai Xu Lei Li Fangyuan Hu Shujie Zhang Tao Sun Chen Jiang Chen Zhao | 2022 | Acta Pharmaceutica Sinica B2022，12，5： | 1 |
| 9 | 4350<ce:hsp sp='0.25'/>W quasi-continuous-wave operation of a diode face-pumped ceramic Nd: YAG slab laser显示文摘 | Junchi Chen Jiang Li Jialin Xu Wenbin Liu Yong Bo Xiqi Feng Yiting Xu Dongliang Jiang Zhongzheng Chen Yubai Pan Yading Guo Biao Yan Chang Guo Lei Yuan Hongtao Yuan Yanyong Lin Yunsheng Xiao Qinjun Peng Wenqiang Lei Dafu Cui Zuyan Xu | 2014 | Optics and Laser Technology2014，，： | 1 |
| 10 | Development and Analysis of the Magnetic Circuit on Double-Radial Permanent Magnet and Salient-Pole Electromagnetic Hybrid Excitation Generator for Vehicles显示文摘With the improvement of vehicles electrical equipment, the existing silicon rectification generator and permanent magnet generator cannot meet the requirement of the electric power consumption of the modern vehicles electrical equipment. It is di cult to adjust the air gap magnetic field of the permanent magnet generator. Consequently, the output voltage is not stable. The silicon rectifying generator has the problems of low e ciency and high failure rate.In order to solve these problems, a new type of hybrid excitation generator is developed in this paper. The developed hybrid excitation generator has a double-radial permanent magnet, a salient-pole electromagnetic combined rotor,and a fractional slot winding stator, where each rotor pole corresponds to 4.5 stator teeth. The equivalent magnetic circuit diagram of permanent magnet rotor and magnetic rotor is established. Magnetic field finite element analysis(FEA) software is used to conduct the modeling and simulation analysis on double-radial permanent magnet magnetic field, salient-pole electro-magnetic magnetic field and hybrid magnetic field. The magnetic flux density mold value diagram and vector diagram are obtained. The diagrams are used to verify the feasibility of this design. The designed electromagnetic coupling regulator controller can ensure the stable voltage export by changing the magnitude and direction of the excitation current to adjust the size of the air gap magnetic field. Therefore, the problem of output voltage instability in the wide speed range and wide load range of the hybrid excitation generator is solved. | Xueyi Zhang Qinjun Du Jinbin Xu Yuzhen Zhao Shilun Ma | 2019 | Chinese Journal of Mechanical Engineering2019，32，2： | 0 |
| 11 | Advanced nano-based strategies for mRNA tumor vaccine显示文摘Tumor vaccine is a promising strategy for cancer immunotherapy by introducing tumor antigens into the body to activate specific anti-tumor immune responses.Along with the technological breakthroughs in genetic engineering and delivery systems,messenger ribonucleic acid(mRNA)technology has achieved unprecedented development and application over the last few years,especially the emergency use authorizations of two mRNA vaccines during the COVID-19 pandemic,which has saved countless lives and makes the world witness the powerful efficacy of mRNA technology in vaccines.However,unlike infectious disease vaccines,which mainly induce humoral immunity,tumor vaccines also need to activate potent cellular immunity to control tumor growth,which creates a higher demand for mRNA delivery to the lymphatic organs and antigen-presenting cells(APCs).Here we review the existing bottlenecks of mRNA tumor vaccines and advanced nano-based strategies to overcome those challenges,as well as future considerations of mRNA tumor vaccines and their delivery systems. | Yangqi Qu Jingjing Xu Tong Zhang Qinjun Chen Tao Sun Chen Jiang | 2024 | Acta Pharmaceutica Sinica B2024，14，1： | 0 |
| 12 | Detection of Low Density Lipoprotein Receptor Related Protein Gene Polymorphism and Serum Lipid Levels in Renal Transplant Recipients显示文摘 | Yuxin Wang Qingqin Li Hequn Zou Yuanshan Lu Qinjun Xu Xiaodao Tang Dai Li | 2008 | 器官移植内科学杂志2008，3，4： | 0 |
| 13 | Expression of bFGF and Its Receptor mRNA in Kidney Transplant Recipients with Hyperlipidemia and Its Treatment显示文摘 | Yuxin Wang Hequn Zou Qingqin Li Yuanshan Lu Qinjun Xu Xiaoda Tang | 2009 | 器官移植内科学杂志2009，4，4： | 0 |
| 14 | Effect of Apolipoprotein E Gene Polymorphism on Serum Lipid Level before and after Renal Transplantation显示文摘 | Yuxin Wang Yuanshan Lu Hequn Zou Qinjun Xu | 2008 | 器官移植内科学杂志2008，3，3： | 0 |
| 15 | A hyperspectral detection model for permeability coefficient of debris flow fine-grained sediments, Southwestern China显示文摘Fine-grained sediments are Quaternary sediments with grain sizes of not more than 2 mm.They startfirst when meeting water,their stability is related to the initial water volume triggering debrisflow,and thus plays an important role in debrisflow hazards early warning.The permeability coefficient is the inter-controlled factor offine-grained sediment stability.However,there is no hyperspectral model for detecting thefine-grained sediment permeability coefficient in large areas,which seriously affects the progress of debrisflow hazards early warning.Therefore,it is of great significance to establish a hyperspectral detection model for the permeability coefficient offine-grained sediments.Taking Beichuan County,Southwestern China as the case,a permeability coefficient hyperspectral detection model was established.The results show that eight bands are sensitive to the permeability coefficient with correlation coefficient(R)of 0.6343.T-test on the model shows that P-a values for sensitive bands are all less than 0.05,indicating the established model has a good prediction ability with a precision of 85.83%.These sensitive bands also indicate the spectral characteristics of the permeability coefficient.Therefore,it provides a scientific basis forfine-grained sediment stability detection in large areas and lays a theoretical foundation for debrisflow hazards’early warning. | Qinjun Wang Jingjing Xie Jingyi Yang Peng Liu Dingkun Chang Wentao Xu | 2023 | International Journal of Digital Earth2023，16，1： | 0 |
| 16 | Integrating NLP and Ontology Matching into a Unified System for Automated Information Extraction from Geological Hazard Reports显示文摘Many detailed data on past geological hazard events are buried in geological hazard reports and have not been fully utilized. The growing developments in geographic information retrieval and temporal information retrieval offer opportunities to analyse this wealth of data to mine the spatiotemporal evolution of geological disaster occurrence and enhance risk decision making. This study presents a combined NLP and ontology matching information extraction framework for automatically recognizing semantic and spatiotemporal information from geological hazard reports. This framework mainly extracts unstructured information from geological disaster reports through named entity recognition, ontology matching and gazetteer matching to identify and annotate elements, thus enabling users to quickly obtain key information and understand the general content of disaster reports. In addition, we present the final results obtained from the experiments through a reasonable visualization and analyse the visual results. The extraction and retrieval of semantic information related to the dynamics of geohazard events are performed from both natural and human perspectives to provide information on the progress of events. | Qinjun Qiu Zhen Huang Dexin Xu Kai Ma Liufeng Tao Run Wang Jianguo Chen Zhong Xie Yongsheng Pan | 2023 | Journal of Earth Science2023，34，5： | 0 |
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