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| 1 | Highly efficient K-Fe/C catalysts derived from metal-organic frameworks towards ammonia synthesis显示文摘Fe-based catalysts have been discovered as the best elementary metal-based heterogeneous catalysts for the ammonia synthesis in industrial application during the last century.Herein,a novel and scalable strategy is developed to prepare the K-promoted Fe/C catalyst with extremely high Fe loading (> 50 wt.%) through pyrolysis of the Fe-based metal-organic framework (MOF) xerogel.The obtained K-Fe/C catalysts exhibited superior activity and stability towards ammonia synthesis.The weight-specific reaction rate of Fe/C with K2O as promoter can achieve 12.4 mmol·g-1·h-1 at 350 ℃ and 30.4 mmol·g-1·h-1 at 400 ℃,approximately four and two times higher than that of the commercial fused-iron catalyst (3.4 mmol·g-1·h-1 at 350 ℃ and 16.7 mmol·g-1·h-1 at 400 ℃) under the same condition,respectively.The excellent performance of K-Fe/C can be ascribed to the inherited structure derived from the metal-organic frame precursors and the promotion of potassium,which can modify the binding energy of reactant molecules on the Fe surface,transfer electrons to iron for effective activation of nitrogen,prevent agglomeration of Fe nanoparticle (NPs) and restrain side reaction of carbon matrix to methane. | Pengqi Yan Wenhan Guo Zibin Liang Wei Meng Zhen Yin Siwei Li Mengzhu Li Mengtao Zhang Jie Yan Dequan Xiao Ruqiang Zou Ding Ma | 2019 | Nano Research2019，12，9： | 4 |
| 2 | Practice and understanding of developing new technologies and equipment for green and low-carbon production of oilfields显示文摘The core of China’s low-carbon development includes optimization of industrial structure,clean energy technologies,emission reduction technologies,and innovation of relevant systems and institutions.China National Petroleum Corporation(CNPC)has always been a proactive participant in developing low-carbon economy,shouldering the responsibilities of safeguarding oil and gas supply,conserving energy,and reducing emission.Therefore,CNPC fulfills those responsibilities as a substantial part of its overall strategy.Guided by low carbon and driven by innovation,petroleum corporations have taken constant innovation of low-carbon technologies,especially the development of green and low-carbon petroleum engineering technologies and equipment,as major measures for energy conservation and emission reduction.Large-scale development mode o f unconventional resource anhydrous fracturing should be innovated.And supercritical C 02 should be used to replace water for fracturing operation,in order to achieve multiple objectives of C 02 burying,conserve water resource,improve single well production and ultimate recovery,realizing reduced emission and efficient utilization o f C 02 resources.Artificial lifting energy-saving and efficiencyincreasing technologies and injection-production technology in the same well should also be innovated.Energy consumption of high water-cut wells is reduced to support the new low-carbon operation mode of high water-cut oilfields and realize energy saving and efficiency improvement during oil production by developing the operation efficiency of the lifting system and reducing the ineffective lifting of formation water.These technologies have been widely recognized by local and international experts and have greatly enhanced CNPC's international influence.This study expounds the key technologies and equipment with regard to the development of green and low-carbon petroleum engineering and provide relevant suggestions. | He LIU Jianwen YAN Siwei MENG Qinghai YANG Zixiu YAO Shijia ZHU | 2019 | Frontiers of Engineering Management2019，6，4： | 3 |
| 3 | Machine Learning-Assisted High-Throughput Virtual Screening for On-Demand Customization of Advanced Energetic Materials显示文摘Finding energetic materials with tailored properties is always a significant challenge due to low research efficiency in trial and error.Herein,a methodology combining domain knowledge,a machine learning algorithm,and experiments is presented for accelerating the discovery of novel energetic materials.A high-throughput virtual screening(HTVS)system integrating on-demand molecular generation and machine learning models covering the prediction of molecular properties and crystal packing mode scoring is established.With the proposed HTVS system,candidate molecules with promising properties and a desirable crystal packing mode are rapidly targeted from the generated molecular space containing 25112 molecules.Furthermore,a study of the crystal structure and properties shows that the good comprehensive performances of the target molecule are in agreement with the predicted results,thus verifying the effectiveness of the proposed methodology.This work demonstrates a new research paradigm for discovering novel energetic materials and can be extended to other organic materials without manifest obstacles. | Siwei Song Yi Wang Fang Chen Mi Yan Qinghua Zhang | 2022 | Engineering2022，8，3： | 3 |
| 4 | Comparison of Three Microwave/Chemical Pretreatment Processes for Enzymatic Hydrolysis of Rice Straw显示文摘 | Shengdong Zhu Yuanxin Wu Ziniu Yu Cunwen Wang Faquan Yu Siwei Jin Yigang Ding Ru’an Chi Jintao Liao Yan Zhang | 2005 | Biosystems Engineering2005，，3： | 1 |
| 5 | Introduction to AVS2 Scene Video Coding Techniques显示文摘The second generation Audio Video Coding Standard(AVS2) is the most recent video coding standard. By introducing several new coding techniques, AVS2 can provide more efficient compression for scene videos such as surveillance videos, conference videos,etc. Due to the limited scenes, scene videos have great redundancy especially in background region. The new scene video coding techniques applied in AVS2 mainly focus on reducing redundancy in order to achieve higher compression. This paper introduces several important AVS2 scene video coding techniques. Experimental results show that with scene video coding tools, AVS2 can save nearly 40% BD-rate(Bj?ntegaard-Delta bit-rate) on scene videos. | Jiaying Yan Siwei Dong Yonghong Tian Tiejun Huang | 2016 | ZTE Communications2016，14，1： | 1 |
| 6 | Conservation of weathered historic sandstone with biomimetic apatite显示文摘The conservation of weathered historic sandstone with apatite was studied.Based on the growth mechanism of bone,calcium and phosphorus were introduced into weathered sandstone and then mineralized at room temperature.The conservation efficiency was investigated by scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDX),transmission electron microscopy(TEM),selected area electron diffraction(SAED),X-ray diffraction(XRD),and compressive strength,capillary water uptake,water vapor permeability and weather resistance tests.The SEM,EDX,TEM,SAED and XRD results showed that the produced hydroxyapatite could reunite the weathered stone blocks and provide sufficient reinforcement to hold them together.The results of the various tests indicated that the compressive strength and weather resistance of the treated samples was improved significantly.In addition,because of the porous nature of apatite,the water vapor permeability of the treated stone was not affected and its breathability was maintained. | YANG FuWei LIU Yan ZHU YuanCheng LONG ShiJia ZUO GuoFang WANG ChangQing GUO Feng ZHANG BingJian JIANG SiWei | 2012 | Chinese Science Bulletin2012，57，17： | 1 |
| 7 | Early Pattern of Epstein-Barr Virus Infection in Gastric Epithelial Cells by “Cell-in-cell”显示文摘Epstein-Barr virus(EBV)is an important human dsDNA virus,which has been shown to be associated with several malignancies including about 10%of gastric carcinomas.How EBV enters an epithelial cell has been an interesting project for investigation.'Cell-in-cell'infection was recently reported an efficient way for the entry of EBV into nasopharynx epithelial cells.The present approach was to explore the feasibility of this mode for EBV infection in gastric epithelial cells and the dynamic change of host inflammatory reaction.The EBV-positive lymphoblastic cells of Akata containing a GFP tag in the viral genome were co-cultured with the gastric epithelial cells(GES-1).The infection situation was observed under fluorescence and electron microscopies.Real-time quantitative PCR and Western-blotting assay were employed to detect the expression of a few specific cytokines and inflammatory factors.The results demonstrated that EBV could get into gastric epithelial cells by'cell-in-cell'infection but not fully successful due to the host fighting.IL-1β,IL-6 and IL-8 played prominent roles in the cellular response to the infection.The activation of NF-κB and HSP70 was also required for the host antiviral response.The results imply that the gastric epithelial cells could powerfully resist the virus invader via cell-in-cell at the early stage through inflammatory and innate immune responses. | Wenxing Yue Meijuan Zhu Lielian Zuo Shuyu Xin Jing Zhang Lingzhi Liu Shen Li Wei Dang Siwei Zhang Yan Xie Fanxiu Zhu Jianhong Lu | 2019 | Virologica Sinica2019，34，3： | 1 |
| 8 | Pressure-Induced Topochemical Polymerization toward Advanced Energetic Materials显示文摘Pressure produces closely packed,high-density materials,thereby providing a promising strategy to obtain high-energy-density materials.However,new phases or structures of energetic materials at high pressure are often not quenchable under ambient conditions.In this work,high-pressure topochemical methodology is first introduced for the preparation of stable energetic materials under ambient conditions.A pressure-induced polymerizable energetic material named PIP-1 is designed and prepared.The experimental measurements demonstrate that the polymerization of PIP-1 is caused by the breakage of C≡C bonds and the generation of C=C bonds.In accord with the experimental results,density functional theory calculations further revealed that the monomer PIP-1 is polymerized to generate 1D PIP-1 tape,and the density of polymerized PIP-1 is increased by 4.9%upon decompression.The successful realization of high-energy-density structure using high pressure showcases a new design strategy for advanced polymerizable energetic materials. | Guangyu Qi Siwei Song Zhiying Deng Dajian Huang Fang Chen Bingmin Yan Huiyang Gou Qinghua Zhang Yi Wang | 2023 | CCS Chemistry2023，5，8： | 0 |
| 9 | Histological,transcriptomic,and gene functional analyses reveal the regulatory events underlying gibberellin-induced parthenocarpy in tomato显示文摘Gibberellin(GA)is one of the major plant hormones that promote parthenocarpy,a highly valuable agronomic trait.Here,we demonstrated that exogenous GA3application triggered the formation of parthenocarpic fruits with smaller size but unchanged shape in tomato(Solanum lycopersicum).These fruits exhibited a thicker pericarp,undeveloped ovules,and few jelly tissues,leading to smaller locules with empty cavities.Histological investigation showed that GA treatment produced more cell layers with larger cells in the pericarp,suggesting its promotion in both cell division and expansion.Transcriptomic analyses between GA-3and mock-treated unpollinated ovaries/fruits identified a large number of differentially expressed genes related to hormones,cell division,cell expansion,and transcription factors,implying that they coordinately regulated parthenocarpy conferred by GA.In particular,the downregulation of five reported repressors of tomato parthenocarpy,including two auxin signaling components,AUXIN RESPONSE FACTOR5(SlARF5)and Sl ARF7,and three MADS-box genes,TOMATO APETALA3(TAP3),TOMATO PISTILLATA(TPI),and AGAMOUS-LIKE6(SlAGL6),after GA treatment might play a key role in this process.Furthermore,we found that the knockdown of a GA signaling factor SlMYB33,which was depressed by GA treatment,induced parthenocarpic fruit set in tomato,an effect that might have been achieved by enhancing GA biosynthesis and decreasing the expression of some repressors of tomato parthenocarpy.Thus,our results provide a basis for understanding the regulatory mechanism of GA in tomato parthenocarpy. | Shaobo Niu Yu He Siwei Yan Zhengliang Sun Run Cai Yan Zhang | 2024 | Horticultural Plant Journal2024，10，1： | 0 |
| 10 | Molecular Identification and Genetic Characterization of Public Health Threatening Ticks — Chongming Island, China, 2021–2022显示文摘Summary What is already known about this topic?Although ticks and tick-borne diseases are prevalent throughout China,there remains a knowledge gap regarding their biology and potential risk of distribution to human and animal populations on Chongming Island.The island,being China’s third largest and a crucial component in the ecological preservation of the Yangtze Delta region,has yet to be comprehensively studied in this context. | Siwei Fei Hanqing Zhao Jingxian Yin Li Wang Zhishan Sun Wenge Zhang Yan Zhang Ke Dong Shan Lyu Xiaokui Guo Xiao-nong Zhou Kokouvi Kassegne | 2023 | China CDC weekly2023，5，37： | 0 |
| 11 | Over 18% binary organic solar cells enabled by isomerization of non-fullerene acceptors with alkylthiophene side chains显示文摘Side-chain engineering has been demonstrated as an effective method for fine-tuning the optical,electrical,and morphological properties of organic semiconductors toward efficient organic solar cells(OSCs).In this work,three isomeric non-fullerene small molecule acceptors(SMAs),named as BTP-4F-T2C8,BTP-4F-T2EH and BTP-4F-T3EH,with linear and branched alkyl chains substituted on the α or β positions of thiophene as the side chains,were synthesized and systematically investigated.The results demonstrate that the size and substitution position of alkyl side chains can greatly affect the electronic properties,molecular packing as well as crystallinity of the SMAs.After blending with donor polymer D18-Cl,the prominent device performance of 18.25% was achieved by the BTP-4F-T3EH-based solar cells,which is higher than those of the BTP-4F-T2EH-based(17.41%)and BTP-4F-T2C8-based(15.92%)ones.The enhanced performance of the BTP-4F-T3EH-based devices is attributed to its stronger crystallinity,higher electron mobility,suppressed bimolecular recombination,and the appropriate intermolecular interaction with the donor polymer.This work reveals that the side chain isomerization strategy can be a practical way in tuning the molecular packing and blend morphology for improving the performance of organic solar cells. | Ao Shang Siwei Luo Jianquan Zhang Heng Zhao Xinxin Xia Mingao Pan Chao Li Yuzhong Chen Jicheng Yi Xinhui Lu Wei Ma He Yan Huawei Hu | 2022 | Science China Chemistry2022，65，9： | 0 |
| 12 | Dynamic changes of autophagy during hypertrophic scar formation and the role of autophagy intervention显示文摘Background:The role of autophagy in the formation of hypertrophic scars(HS)remains unclear.This study aimed to explore the role and potential mechanism of autophagy during the development of HS.Methods:RNA and protein expression levels of Beclin-1,p62,and LC3II in normal skin tissues and HS specimens from different patients were examined.Autophagy inducers and inhibitors were used to cure established HS in rabbit ears,and the expression of Beclin-1,p62,and LC3II at the RNA and protein level was determined.Lastly,the effects of autophagy inducers and inhibitors on HS development were analyzed.Results:Compared to normal skin tissues,the expression of LC3II and Beclin-1 was higher(P<0.05),while that of p62 was lower(P<0.05)in HS tissues.In addition,the LC3II/LC3I ratio was increased during HS formation,and the altered expression of the three proteins stabilized after one year.Administration of autophagy inducers enhanced the formation of HS as well as the expression levels of LC3II and Beclin-1 but decreased p62 expression.Meanwhile,administration of autophagy inhibitors increased the expression of LC3II,Beclin-1,and p62,along with reduced HS formation.Conclusion:Autophagic activity increased during HS initiation and subsequent stabilization.In addition,autophagy inhibitors were able to inhibit HS formation by suppressing autophagy,whereas autophagy inducers promoted scar hyperplasia by enhancing autophagy。 | Yu Liu Xiaoxia Chen Yuan Fang Yu Yan Bin He Junlin Liao Ke Cao Xi Zhang Siwei Qu Jianda Zhou | 2021 | Chinese Journal Of Plastic and Reconstructive Surgery2021，3，3： | 0 |
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