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| 1 | Influence of the post-treatment of HZSM-5 zeolite on catalytic performance for alkylation of benzene with methanol显示文摘The porous material HZSM-5 zeolite with micro-mesopore hierarchical porosity was prepared by post-treatment(combined alkali treatment and acid leaching) of parent zeolite and its catalytic performance for benzene alkylation with methanol was investigated. The effect of post-treatment on the textural properties was characterized by various techniques(including ICP-AES, XRD, nitrogen sorption isotherms, SEM, NH3-TPD, Py-IR and TG). The results indicated that the post-treatment could modify the structural and acidic properties of HZSM-5 zeolite. In this procedure, not only additional mesopores were created by selective extraction of silicon but also the acidity was tuned. Consequently, the modified HZSM-5 zeolite showed larger external surface area with less acid sites as compared to the parent zeolite. It was found out that the modified zeolite exhibited a higher benzene conversion and xylene selectivity for alkylation of benzene with methanol as well as excellent life span of the catalyst than conventional ones. This can be explained by the facts that the presence of additional mesopores improved the diffusion property in the reactions. Furthermore, the modified zeolite showed an appropriate Br?nsted acidity for effective suppression of the side reaction of methanol to olefins, thus reduced the accumulation of coke on the HZSM-5 zeolite, which was favorable for the catalyst stability. In comparison with the parent HZSM-5 zeolite,the modified zeolite by alkali treatment and acid leaching showed better performance for the benzene alkylation with methanol. | Qingtao Wang Wenwen Han Hualei Hu Jinghui Lyu Xiaolong Xu Qunfeng Zhang Hongjing Wang Xiaonian Li | 2017 | Chinese Journal of Chemical Engineering2017，25，12： | 13 |
| 2 | Benzene alkylation with methanol over phosphate modified hierarchical porous ZSM-5 with tailored acidity显示文摘The acidity and acid distribution of hierarchical porous ZSM-5 were tailored via phosphate modification. The catalytic results showed that both benzene conversion and selectivity of toluene and xylene increased with the presence of appropriate amount of phosphorus. Meanwhile, side reactions such as methanol to olefins related with the formation of by-product ethylbenzene formation and isomerization of xylene to meta-xylene were suppressed efficiently. The acid strength and sites amount of Br?nsted acid of the catalyst were crucial for improving benzene conversion and yield of xylene, whereas passivation of external surface acid sites played an important role in breaking thermodynamic equilibrium distribution of xylene isomers. | Jinghui Lyu Hualei Hu Carolyn Tait Jiayao Rui Caiyi Lou Qingtao Wang Wenwen Han Qunfeng Zhang Zhiyan Pan Xiaonian Li | 2017 | Chinese Journal of Chemical Engineering2017，25，9： | 11 |
| 3 | Synthesized high-silica hierarchical porous ZSM-5 and optimization of its reaction conditions in benzene alkylation with methanol显示文摘In our present work, the high-silica hierarchical porous ZSM-5 with appropriate Br(o|¨)nsted acidity and hierarchical porous structure was synthesized by sol-gel method for continuously catalytic conversion of benzene alkylation with methanol to xylene. The effects of temperature, pressure, benzene/methanol molar ratio and weight hour space velocity(WHSV) on the catalytic performance of the catalyst were investigated as well. As a result, the high-silica hierarchical porous ZSM-5 showed great performance as the yield of xylene was up to 41.1% under the optimum reaction conditions(500 ℃,0.1 MPa,M_(benzene)/M_(methanol)= 1:1.5 and WHSV=4 h 1), while the selectivity to by-product, ethylbenzene, was well suppressed(below 0.1%). In addition, the catalyst structure and properties were characterized by the means of XRD, IR, TPD,SEM, TEM and N_2 physical adsorption technologies. | Jiayao Rui Jinghui Lyu Hualei Hu Qunfeng Zhang Qingtao Wang Xiaonian Li | 2019 | Chinese Chemical Letters2019，30，3： | 5 |
| 4 | A leaf shape mutant provides insight into PINOID Serine/Threonine Kinase function in cucumber(Cucumis sativus L.)显示文摘Optimizing leaf shape is a major challenge in efforts to develop an ideal plant type. Cucumber leaf shapes are diverse;however, the molecular regulatory mechanisms underlying leaf shape formation are unknown. In this study, we obtained a round leaf mutant(rl) from an ethyl methanesulfonate-induced mutagenesis population. Genetic analysis revealed that a single recessive gene, rl, is responsible for this mutation. A modified Mut Map analysis combined linkage mapping identified a single nucleotide polymorphism within a candidate gene,Csa1 M537400, as the mutation underlying the trait.Csa1 M537400 encodes a PINOID kinase protein involved in auxin transport. Expression of Csa1 M537400 was significantly lower in the rl mutant than in wild type, and it displayed higher levels of IAA(indole-3-acetic acid) in several tissues. Treatment of wild-type plants with an auxin transport inhibitor induced the formation of round leaves,similar to those in the rl mutant. Altered expression patterns of several auxin-related genes in the rl mutant suggest that rl plays a key role in auxin biosynthesis,transport, and response in cucumber. These findings provide insight into the molecular mechanism underlying the regulation of auxin signaling pathways in cucumber,and will be valuable in the development of an ideal plant type. | Mengfei Song Feng Cheng Jing Wang Qingzhen Wei Wenyuan Fu Xiaqing Yu Ji Li Jinfeng Chen Qunfeng Lou | 2019 | Journal of Integrative Plant Biology2019，61，9： | 3 |
| 5 | Progress in researching into the transition of the Mesozoic tectonic systems in southeast China显示文摘这篇论文论述在东南中国用进 NE- NNE 西方的和平的领域构造的 E-W paleo-Tethyan 在中生代构造系统转变的研究上做的最近的进步。西方太平洋领域的 Tectonism 在中间的侏罗记开始了(J 2) 并且形成了一套趋势 NE 结构, non-coaxially 早并且同时代地在可以是的电子 trending 构造的带上套印由 paleo- Tethyan 领域生产了。因此从电子 trending paleo- Tethyan 开始了构造领域转变到在早白垩纪和平、充分完成的趋势 NE。东方 Nanling 区域是在中间的侏罗记的转变的一个连接地区(J 2), 并且此后,连接地区可能倾斜地移居到沿海的区域,在此是这个学习区域的东方部分。到 Nanling 区域的北方, Ganjiang 差错地区是在二个构造领域之间的边界。相应于构造系统的转变,中国从一个有压缩性的系统改变了到前的 SE 的地球动力学紧张的系统,继续直到中生代的结束,第三级。 | YU Xinqi WU Ganguo ZHANG Da ZHANG Xiangxin DI yongjun ZANG Wenshuan WANG Qunfeng HUANG Huojian | 2006 | Progress in Natural Science:Materials International2006，16，6： | 3 |
| 6 | Probing deactivation by coking in catalyst pellets for dry reforming of methane using a pore network model显示文摘Dry reforming of methane(DRM) is an attractive technology for utilizing the greenhouse gases(CO_(2) and CH_(4)) to produce syngas. However, the catalyst pellets for DRM are heavily plagued by deactivation by coking, which prevents this technology from commercialization. In this work, a pore network model is developed to probe the catalyst deactivation by coking in a Ni/Al_(2)O_(3) catalyst pellet for DRM. The reaction conditions can significantly change the coking rate and then affect the catalyst deactivation. The catalyst lifetime is higher under lower temperature, pressure, and CH_(4)/CO_(2) molar ratio, but the maximum coke content in a catalyst pellet is independent of these reaction conditions. The catalyst pellet with larger pore diameter, narrower pore size distribution and higher pore connectivity is more robust against catalyst deactivation by coking, as the pores in this pellet are more difficult to be plugged or inaccessible.The maximum coke content is also higher for narrower pore size distribution and higher pore connectivity, as the number of inaccessible pores is lower. Besides, the catalyst pellet radius only slightly affects the coke content, although the diffusion limitation increases with the pellet radius. These results should serve to guide the rational design of robust DRM catalyst pellets against deactivation by coking. | Yu Wang Qunfeng Zhang Xinlei Liu Junqi Weng Guanghua Ye Xinggui Zhou | 2023 | Chinese Journal of Chemical Engineering2023，55，3： | 2 |
| 7 | Discovery and biosynthesis of thioviridamide-like compounds显示文摘Thioviridamide-like compounds are a unique subfamily of ribosomally synthesized and post-translationally modified peptides and contain characteristic thioamide bonds and S-[(Z)-2-aminovinyI]-Dcysteine(AviCys). Members of this family are active against a number of cancer cell lines. The distribution, biosynthetic machinery and the mode of action of thioviridamide-like compounds remain largely unknown. In this review, we outlined recent advances in the discovery of thioviridamide-like peptide natural products and the effort in the elucidation of their biosynthetic origin. | Jian Tang Jingxia Lu Qunfeng Luo Huan Wang | 2018 | Chinese Chemical Letters2018，29，7： | 1 |
| 8 | Analytical Calculation of Air-Gap Magnetic Field Distribution and Instantaneous Characteristics of Brushless DC Motors 显示文摘 | Xinghua Wang Qingfu Li Qunfeng Li | 2003 | IEEE TRANSACTIONS ON ENERGY CONVERSION2003，18，3： | 1 |
| 9 | Thermal conductivity of MWCNT/epoxy composites: The effects of length, alignment and functionalization显示文摘 | Jin Gyu Park Qunfeng Cheng Jun Lu Jianwen Bao Shu Li Ying Tian Zhiyong Liang Chuck Zhang Ben Wang | 2012 | Carbon2012，，6： | 1 |
| 10 | Hg 0 oxidative absorption by K 2 S 2 O 8 solution catalyzed by Ag + and Cu 2+显示文摘 | Xinhua Xu Qunfeng Ye Tingmei Tang Dahui Wang | 2008 | Journal of Hazardous Materials2008，，2： | 1 |
| 11 | Mapping of fruit apex shape related QTLs across multi-genetic backgrounds in cucumber(Cucumis sativus L.)显示文摘The shape of fruit apex is critical to appearance quality in cucumber(Cucumis sativus L.),of which the genetic basis was poorly understood,and the use of marker-assisted breeding for fruit apex improvement is not available yet.In this study,the variation of fruit apex in different cucumber ecotypes was evaluated by fruit apex angle(variation coefficient from 7.1%to 15.7%)and fruit apex index(variation coefficient from 8.8%to 22.6%).Fruit apex associated QTLs were mapped by using 145 F_(2:3) families and 155 F_(2:6) population that were derived from the cross of different ecotype cucumbers.Phenotyping of the mapping populations were conducted in four experiments in 2 years.Four majoreffect QTLs,Bfal4.1,Bfai4.1,Bfad6.1 and Bfai6.1 were consistently and reliably detected across two environments which could explain 11.6%-33.6%phenotypic variations(R^(2))in the F_(2:3) families.Three major-effect QTLs,Ofai4.1(R^(2)=13.4%-15.5%),Ofal4.1(R^(2)=10.7%-12.8%),and Ofad6.1(R^(2)=11.6%-12.4%)were stably detected in the F_(2:6) population in two experiments.Bfai4.1,Bfal4.1,Ofai4.1 and Ofal4.1 were integrated to be consensus QTL fa4.1,within which 11 candidate genes were predicted.Bfai6.1 and Bfad6.1 were integrated to be consensus QTL fa6.1.QTL interaction analysis showed that Bfai6.1 has epistatic effect with Bfai4.1.This study revealed two reliable major-effect fruit apex related QTLs across multi-genetic backgrounds and environments in cucumber.The possible candidate genes regulating the shape of fruit apex,and the relationship between cell division and fruit apex morphogenesis were discussed. | Pinyu Zhu Yongjiao Meng Kaijing Zhang Xueyan Wang Kun Liang Tuantuan Wang Jian Xu Xiaodong Qin Zhe Wu Chunyan Cheng Xiaqing Yu Chuntao Qian Qunfeng Lou Jinfeng Chen Ji Li | 2022 | Horticultural Plant Journal2022，8，3： | 1 |
| 12 | Strong,tough,and thermally conductive nacre-inspired boron nitride nanosheet/epoxy layered nanocomposites显示文摘Thermally conductive polymer nanocomposites integrated with lightweight,excellent flexural strength,and high fracture toughness(KIc)would be of great use in many fields.However,achieving all of these properties simultaneously remains a great challenge.Inspired by natural nacre,here we demonstrate a lightweight,strong,tough,and thermally conductive boron nitride nanosheet/epoxy layered(BNNEL)nanocomposite.Because of the layered structure and enhancing the interfacial interactions through hydrogen bonding and Si–O–B covalent bonding,the resulting nacre-inspired BNNEL nanocomposites show high fracture toughness of~4.22 MPa·m^(1/2),which is 7 folds as high as pure epoxy.Moreover,the BNNEL nanocomposites demonstrate sufficient flexural strength(~168.90 MPa,comparable to epoxy resin),while also being lightweight(~1.23 g/cm^(3)).Additionally,the BNNEL nanocomposites display a thermal conductivity(κ)of~0.47 W/(m·K)at low boron nitride nanosheet loading of 2.08 vol.%,which is 2.7 times higher than that of pure epoxy resin.The developed nacre-inspired strategy of layered structure design and interfacial enhancement provides an avenue for fabricating high mechanical properties and thermally conductive polymer nanocomposites. | Huagao Wang Rongjian Lu Lei Li Cheng Liang Jia Yan Rui Liang Guoxing Sun Lei Jiang Qunfeng Cheng | 2024 | Nano Research2024，17，2： | 1 |
| 13 | Syn-ergistic toughening of bio-inspired poly (vinyl alcohol)-claynanofibrillar cellulose artificial nacre 显示文摘 | WANG Jianfeng CHENG Qunfeng LIN Ling | 2014 | ACS Nano2014，83，： | 1 |
| 14 | High halogenated nitrobenzene hydrogenation selectivity over nano Ir particles显示文摘The selective hydrogenation of halogenated nitrobenzene over noble metal catalysts(Pd, Pt, and Ir) has attracted much attention owing to its high efficiency and environmental friendliness. However, the effect of size on the catalytic performance varies among different metal catalysts. In this study, sub-nano(<3 nm) Ir and Pd particles were prepared, and their catalytic properties for hydrogenation of halogenated nitrobenzene were evaluated.Results show that high selectivity(N 99%) was achieved over small Ir nanoparticles, in which the selectivity over the Pd with same size was much lower than that on Ir nanoparticles. Meanwhile, Ir and Pd have different hydrogen consumption rates and reaction rates. Density functional theory calculations showed that p-chloronitrobenzene(CNB) has different adsorption properties on Ir and Pd. The distance between oxygen(cholorine) and Ir is much shorter(longer) than that between oxygen and Pd. The reaction barriers of dechlorination of p-CNB and p-chloroaniline over different Ir models are much larger than those on Pd. Especially,lower coordination of Ir leads to larger barriers of dechlorination reaction. These theoretical results explain the difference between Ir and Pd on hydrogenation of halogenated nitrobenzene. | Lei Ma Jianguo Wang Hanbing Wang Qunfeng Zhang Chunshan Lu Xiaobo He Xiaonian Li | 2017 | Chinese Journal of Chemical Engineering2017，25，3： | 0 |
| 15 | Tribological properties of low-temperature time-dependent pretreated graphite for mechanical seal pairs in high-speed turbopump显示文摘The friction coefficient and wear rate of pretreated graphite with liquid nitrogen were obtained by using a ball-on-disk tester,and the wear of GCr15–graphite seal pairs with the low-temperature time-dependent pretreatment was discussed by comparing the wear morphology.The results show that liquid nitrogen pretreatment can affect the hardness and interlayer spacing of graphite.The range of the friction coefficients of pretreated graphite changes from 0.17 to 0.22.With the increase of liquid nitrogen pretreatment time,the wear mechanism of graphite would change from dominated three-body wear to adhesion wear.The experimental results of the mechanical seal with liquid nitrogen pretreatment show that the wear rate of stator is less than 0.00165 mm^(3)·N^(−1)·m^(−1),and the graphite shows a good low-temperature compatibility. | Yangyang ZHAO Guoyuan ZHANG Junqian WANG He WANG Weigang ZHAO Qunfeng ZENG | 2024 | Friction2024，12，2： | 0 |
| 16 | Shear response of β-SiC bulk dependent on temperature and strain rate显示文摘The shear responses of β-SiC are investigated using molecular dynamics simulation with the Tersoff interatomic potential. Results show a clear decreasing trend in critical stress,fracture strain and shear modulus as temperature increases. Above a critical temperature, β-SiC bulk just fractures after the elastic deformation. However, below the critical temperature, an interesting pattern in β-SiC bulk emerges due to the elongation of Si-C bonds before fracture. Additionally, the shear deformation of β-SiC at room temperature is found to be dependent on the strain rate. This study may shed light on the deformation mechanism dependent on temperature and strain rate. | Liang Wang Qunfeng Liu Wenshan Yu Shengping Shen | 2017 | Acta Mechanica Solida Sinica2017，30，2： | 0 |
| 17 | Pt-Ni core-shell structure with Pt-skin and electronic effect on catalytic performance显示文摘In order to improve the catalytic performance of the nitrobenzene hydrogenation rearrangement to prepare p-aminophenol,a bimetallic Pt-Ni/C(PNC)catalyst was synthesized.Taking advantage of the synergistic effect of Ni and Pt to enhance product selectivity and catalytic performance stability,the electrons in Ni are moved to Pt by the electron effect,which affects the catalyst’s ability to activate H_(2)as well as the amount of hydrogen activated.Furthermore,due to the strong Pt(5d)-Ni(3d)coupling effect,Ni can effectively maintain Pt stability in the acidic system and reduce Pt dissolution.The stability of the PNC can be found to be greatly enhanced compared to the Pt/C(PC)catalyst,and p-aminophenol selectivity is greatly enhanced,showing excellent catalytic performance. | Chong Yao Dandan Ma Jie Luo Yixin Chen Min Tian Haoxuan Xie Chunshan Lu Feng Feng Xiaoliang Xu Qingtao Wang Qunfeng Zhang Xiaonian Li | 2023 | Chinese Journal of Chemical Engineering2023，63，11： | 0 |
| 18 | A mutation in CsKTN1 for the Katanin p60 protein results in miniature plant in cucumber,Cucumis sativus L.显示文摘Katanin,a microtubule shearing protein,plays an important role in plant architecture formation.However,little is known about its mechanisms in regulating plant architecture in cucumber.In the present study,through EMS mutagenesis,we identified a novel micro-plant(mp)mutant in the North China type inbred line CCMC that may be of value for cucumber breeding.The size and number of stem cells were altered in the mp mutant.Through bulked segregant analysis(BSA)sequencing approach combined with genetic mapping,the mp locus was delimited to an interval of 130.9-kb.Multiple lines of evidence suggested that the mp mutation is due to a single nucleotide polymorphism in Csa7G435510 that is predicted to encode the Katanin p60 subunit protein(CsKTN1).The expression levels of CsKTN1 decreased significantly in all tissues except the tendril of mp mutant.Subcellular localization showed that both wild-type and mutant CsKTN1 proteins were located in cell membrane,cytoplasm and nucleus of tobacco leaf cells.The mutant protein lost part of its ability to bind and shear microtubule in vitro.These findings provide new insight into the regulatory function of microtubule-shearing protein,Katanin p60,in plant architecture of cucumber. | MengFei Song WenYuan Fu YuHui Wang Feng Cheng MengRu Zhang JinFeng Chen QunFeng Lou | 2022 | Vegetable Research2022，2，1： | 0 |
| 19 | Characterization of grain cadmium concentration in indica hybrid rice显示文摘As a consequence of contamination of soil with heavy metals,cadmium accumulation in grain is of great concern worldwide,but especially in southern China.It is important to evaluate the Cd accumulation potential of grain before or when examining and approving new cultivars.An evaluation method and criteria for verifying Cd accumulation potential in rice are proposed,and the Cd accumulation potential of 56 mid-season indica hybrids collected from the provincial cultivar trials in 2016 were investigated.Genotype,environment and their interactions strongly affected the variation in grain Cd accumulation.Two hybrids were identified as slightly Cd accumulating.Hybrids with slight Cd accumulation potential would be suitable for safe grain production on polluted land(total Cd under 2.0 mg$kg–1)in Hunan Province(China)and should be considered for new cultivar evaluation and approval.This evaluation method and criterion could be applied for certifying Cd accumulation potential of rice cultivars. | Kai WANG Qunfeng ZHOU Tianze YAN Shilong XU Longyi ZHAO Weicheng WANG Zhigang JIN Peng QIN Chenjian FU Liangbi CHEN Yuanzhu YANG | 2020 | Frontiers of Agricultural Science and Engineering2020，7，4： | 0 |
| 20 | Regulation of the selective hydrogenation performance of sulfur-doped carbon-supported palladium on chloronitrobenzene显示文摘The overall performance of metal catalysts can be efficiently adjusted by modifying carbon carriers with different valence sulfur precursors.The wet impregnation technique successfully prepared carbon material carriers doped with varying sources of sulfur(Na_(2)SO_(4),NaHSO_(3),Na_(2)S·9H_(2)O).Palladium carbon catalysts doped with different sulfur precursors had been prepared with the aid of the liquid-phase reduction method of the selective hydrogenation of o-chloronitrobenzene(o-CNB)to o-chloroaniline(o-CAN).The catalyst prepared for Na_(2)S·9H_(2)O as a precursor has excellent performance,and the selectivity for o-CAN is more than 99.9%at 100%conversion.In addition,the characterization results show that with the decrease of S valence,the electronic effect between S and Pd increases,and the outer electron shift of Pd increases,which reduces the adsorption and dissociation ability of Pd to hydrogen,resulting in excellent selectivity.The effects provided a good idea for the hydrogenation of o-CNB and a different point of view on sulfur doping in a variety of hydrogenation reactions. | Qunfeng Zhang Bingcheng Li Yuan Zhou Deshuo Zhang Chunshan Lu Feng Feng Jinghui Lv Qingtao Wang Xiaonian Li | 2023 | Chinese Journal of Chemical Engineering2023，58，6： | 0 |
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