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1Recent progress of surface coating on cathode materials for high-performance lithium-ion batteries显示文摘Lithium-ion batteries (LIB) have received substantial attention in the last 10 years,as they offer great promise as power sources that can lead to the electric vehicle (EV) revolution in the next 5 years.Since the cathode serves as a key component in LIB,its properties significantly affect the performance of the whole system.Recently,the cathode surface modification based on coating technique has been widely employed to enhance the electrochemical performances by improving the material conductivity,stabilising the physical structure of materials,as well as preventing the reactions between the electrode and electrolyte.In this work,we reviewed the present of a number of promising cathode materials for Li-ion batteries.After that,we summarized the very recent research progress focusing on the surface coating strategies,mainly including the coating materials,the coating technologies,as well as the corresponding working mechanisms for cathodes.At last,the challenges faced and future guidelines for optimizing cathode materials are discussed.In this study,we propose that the structure of cathode is a crucial factor during the selection of coating materials and technologies.Peiyuan Guan Lu Zhou Zhenlu Yu Yuandong Sun Yunjian Liu Feixiang Wu Yifeng Jiang Dewei Chu 2020Journal of Energy Chemistry2020,29,4:28
2Temperature variation of a thermionic cathode during electron emission显示文摘It is necessary to know the actual temperature of a thermionic cathode that works as the electron source in a microwave tube. It has been found that the temperature of the cathode drops markedly during the thermionic emission. For example, the temperature could fall by about 30oC under a current density of 2.92 A/cm2. Using the molecular thermodynamics, the dependence of the cathode temperature on the emission current density has been obtained. It has been theoretically pointed out that several factors, such as heating model and temperature coefficient of resis-tance of heater, can influence the cathode temperature. These theoretical conclu-sions were supported by the experimental results.LIU YanWen TIAN Hong HAN Yong XU ZhenYing MENG MingFeng ZHANG HongLai 2008Science China(Technological Sciences)2008,51,9:22
3ASTUDY OF VALENCE OF YTTRIUM IN Y_2O_3 Mo CATHODE显示文摘The valenceofelementyttrium of Y2 O3 Mocathode materialhasbeenstudied by usingther mal weight analysis, X ray diffraction analysis, Scanning electron microscopy and X rayphotoelectronspectrum . It hasbeen provedthatyttrium oxidecan bereduced by molybdenum carbide. Thereaction between powdered Y2 O3 and Mo2 Ccan happen at 1173 , and Y2 O3may bereduced to metallicyttrium . Afterthepowder mixtureof Y2 O3 and Mo2 Cwasheat treated at1873 K, Yttrium existsin two kinds of chemicalstate- yttrium of zero valence and yttrium ofthreevalences.J.S.Wang1,2) ,M.L.Zhou2) ,J.X.Zhang2) ,Z.R.Nie2) T.Y.Zuo2) and G.J.Zhang2) 1) State Key Laboratory of Materials Chemistry and Applications,Peking University ,Beijing 100871 ,China2) Schoolof Materials Science and Engineering ,Beijing Polytechnic Univers 1999Acta Metallurgica Sinica(English Letters)1999,12,4:16
4Recent progress on lithium-ion batteries with high electrochemical performance显示文摘Lithium-ion batteries(LIBs) have been widely used in many fields such as portable electronics and electric vehicles since their successful commercialization in the 1990 s. However, the electrochemical performance of current commercial LIBs still needs to be further improved to meet the continuously increasing demands for energy storage applications. Recently, tremendous research efforts have been made in developing next-generation LIBs with enhanced electrochemical performance. In this review, we mainly focus on the recent progress of LIBs with high electrochemical performance from four aspects, including cathode materials, anode materials, electrolyte, and separators. We discuss not only the commercial electrode materials(LiCoO_2,LiFePO_4, LiMn_2O_4, LiNi_xMn_yCo_zO_2, LiNi_xCo_yAl_zO_2, and graphite) but also other promising next-generation materials such as Li-, Mn-rich layered oxides, organic cathode materials, Si, and Li metal. For each type of materials, we highlight their problems and corresponding strategies to enhance their electrochemical performance. Nowadays, one of the key challenges to construct high-performance LIBs is how to develop cathode materials with high capacity and working voltage. This review provides an overview and future perspectives to develop next-generation LIBs with high electrochemical performance.Yong Lu Qiu Zhang Jun Chen 2019Science China Chemistry2019,62,5:16
5γ-MnO2 nanorods/graphene composite as efficient cathode for advanced rechargeable aqueous zinc-ion battery显示文摘Aqueous Zn//MnO2 batteries are emerging as promising large-scale energy storage devices owing to their cost-effectiveness,high safety,high output voltage,and energy density.However,the MnO2 cathode suffers from intrinsically poor rate performance and rapid capacity deterioration.Here,we remove the roadblock by compositing MnO2 nanorods with highly conductive graphene,which remarkably enhances the electrochemical properties of the MnO2 cathode.Benefiting from the boosted electric conductivity and ion diffusion rate as well as the structural protection of graphene,the Zn//MnO2-graphene battery presents an admirable capacity of 301 mAh g^-1 at 0.5 A g^-1,corresponding to a high energy density of 411.6 Wh kg^-1.Even at a high current density of 10 A g^-1,a decent capacity of 95.8 mAh g^-1 is still obtained,manifesting its excellent rate property.Furthermore,an impressive power density of 15 kW kg^-1 is achieved by the Zn//MnO2-graphene battery.Chao Wang Yinxiang Zeng Xiang Xiao Shijia Wu Guobin Zhong Kaiqi Xu Zengfu Wei Wei Su Xihong Lu 2020Journal of Energy Chemistry2020,29,4:13
6A novel synthesis strategy to improve cycle stability of LiNio.8Mno.1Co0.1O2 at high cut-off voltages through core-shell structuring显示文摘Nickel-rich cathode materials have attracted considerable interest because of their high specific capacities,voltage ranges,and low cost.However,serious capacity attenuation and poor rate performance limit their application.This study proposes a novel strategy to improve the cycle stability of the nickel-rich LiNi0.sCo0.1Mn0.1O2(NCM811)layer material by designing core-shell LiNio.sCoo.1 Mno.102(CS-NCM811).CS-NCM811 is designed by the characteristic reaction between dimethylglyoxime(C4H8N2O2)and nickel ion to form Ni(C4H7N2O2)2-The CS-NCM811 is characterized with high nickel content in its core and high manganese content on its surface,leading to a high capacity and excellent cycle stability.The capacity retention of CS-NCM811 was 72.8%,much higher than that of NCM811(47.1%)after 500 cycles at a rate of 5 C.Not only is this method a no vel strategy to desig n high capacity cathode materials but also provides some new in sights into the cycle stability of nickel-rich layered cathode materials.Kang Wu Qi Li Rongbin Dang Xin Deng Minmin Chen Yu Lin Lee Xiaoling Xiao Zhongbo Hu 2019Nano Research2019,12,10:12
7LiMn_(2)O_(4) Microspheres:Synthesis,Characterization and Use As a Cathode in Lithium Ion Batteries显示文摘Solid and hollow microspheres of LiMn_(2)O_(4) have been synthesized by lithiating MnCO_(3) solid microspheres and MnO_(2) hollow microspheres,respectively.The LiMn_(2)O_(4) solid microspheres and hollow microspheres had a similar size of about 1.5μm,and the shell thickness of the hollow microspheres was only 100 nm.When used as a cathode material in lithium ion batteries,the hollow microspheres exhibited better rate capability than the solid microspheres.However,the tap density of the LiMn_(2)O_(4) solid microspheres(1.0 g/cm^(3))was about four times that of the hollow microspheres(0.27 g/cm^(3)).The results show that controlling the particle size of LiMn_(2)O_(4) is very important in terms of its practical application as a cathode material,and LiMn_(2)O_(4) with moderate particle size may afford acceptable values of both rate capability and tap density.Xiaoling Xiao Jun Lu Yadong Li 2010Nano Research2010,3,10:12
8Novel Insights into Energy Storage Mechanism of Aqueous Rechargeable Zn/MnO2 Batteries with Participation of Mn2+显示文摘Aqueous rechargeable Zn/MnO2 zinc-ion batteries(ZIBs)are reviving recently due to their low cost,non-toxicity,and natural abundance.However,their energy storage mechanism remains controversial due to their complicated electrochemical reactions.Meanwhile,to achieve satisfactory cyclic stability and rate performance of the Zn/MnO2 ZIBs,Mn2+ is introduced in the electrolyte(e.g.,ZnSO4 solution),which leads to more complicated reactions inside the ZIBs systems.Herein,based on comprehensive analysis methods including electrochemical analysis and Pourbaix diagram,we provide novel insights into the energy storage mechanism of Zn/MnO2 batteries in the presence of Mn2+.A complex series of electrochemical reactions with the coparticipation of Zn2+,H+,Mn2+,SO42-,and OH-were revealed.During the first discharge process,co-insertion of Zn2+ and H+ promotes the transformation of MnO2 into ZnxMnO4,MnOOH,and Mn2O3,accompanying with increased electrolyte pH and the formation of ZnSO4·3 Zn(OH)2-5 H2O.During the subsequent charge process,ZnxMnO4,MnOOH,and Mn2O3 revert to a-MnO2 with the extraction of Zn2+ and H+,while ZnSO4·3Zn(OH)2·5H2O reacts with Mn2+ to form ZnMn3O7·3 H2O.In the following charge/discharge processes,besides aforementioned electrochemical reactions,Zn2+ reversibly insert into/extract from α-MnO2,ZnxMnO4,and ZnMn3O7·3H2O hosts;ZnSO4·3Zn(OH)2·5 H2O,Zn2Mn3O8,and ZnMn2O4 convert mutually with the participation of Mn2+.This work is believed to provide theoretical guidance for further research on high-performance ZIBs.Yongfeng Huang Jian Mou Wenbao Liu Xianli Wang Liubing Dong Feiyu Kang Chengjun Xu 2019Nano-Micro Letters2019,11,3:11
9Electrochemical performance of Li-rich cathode material,0.3Li_2MnO_3-0.7LiMn_(1/3)Ni_(1/3)Co_(1/3)O_2 microspheres with F-doping显示文摘Layered F-doped cathode materials 0.3 Li_2 MnO_3-0.7 LiMn_(1/3)Ni_(1/3)CO_(1/3))O_(2-x)F_x(x = 0, 0.01, 0.02, 0.03, 0.04,0.05) microspheres made up of nanosized primary grains were prepared through co-precipitation method. The sample of x = 0.02 demonstrates a large discharge capacity of226 mAh g^(-1) over 100 cycles at 0.1 C and excellent rate performance with discharge capacity of 96 mAh g-1 at 5.0 C and room temperature. Particularly, this material shows much enhanced electrochemical performances even at high temperature of 55 ℃. It delivers a quite high discharge capacity of 233.7 mAh·g^(-1) at 1.0 C with capacity retention as high as 97.9% after 100 cycles. The results demonstrate that the fluorine incorporation stabilizes the cathode structure and maintains stable interfacial resistances.Ting Liu Shi-Xi Zhao Lu-Lu Gou Xia Wu Ce-Wen Nan 2019Rare Metals2019,38,3:11
10Recent progress on the recycling technology of Li-ion batteries显示文摘Lithium-ion batteries(LIBs)have been widely applied in portable electronic devices and electric vehicles.With the booming of the respective markets,a huge quantity of spent LIBs that typically use either LiFePO_(4) or Li N_(x)Co_(y)Mn_(z)O_(2) cathode materials will be produced in the very near future,imposing significant pressure for the development of suitable disposal/recycling technologies,in terms of both environmental protection and resource reclaiming.In this review,we firstly do a comprehensive summary of the-state-of-art technologies to recycle Li N_(x)Co_(y)Mn_(z)O_(2) and LiFePO_(4)-based LIBs,in the aspects of pretreatment,hydrometallurgical recycling,and direct regeneration of the cathode materials.This closed-loop strategy for cycling cathode materials has been regarded as an ideal approach considering its economic benefit and environmental friendliness.Afterward,as for the exhausted anode materials,we focus on the utilization of exhausted anode materials to obtain other functional materials,such as graphene.Finally,the existing challenges in recycling the LiFePO_(4) and Li N_(x)Co_(y)Mn_(z)O_(2) cathodes and graphite anodes for industrial-scale application are discussed in detail;and the possible strategies for these issues are proposed.We expect this review can provide a roadmap towards better technologies for recycling LIBs,shed light on the future development of novel battery recycling technologies to promote the environmental benignity and economic viability of the battery industry and pave way for the large-scale application of LIBs in industrial fields in the near future.Yuqing Wang Ning An Lei Wen Lei Wang Xiaotong Jiang Feng Hou Yuxin Yin Ji Liang 2021Journal of Energy Chemistry2021,30,4:10
11Choice for graphene as conductive additive for cathode of lithium-ion batteries显示文摘Graphene is a promising conductive additive for the lithium-ion batteries(LIBs) and shows great potential especially with its fast development of the large scale fabrication technology. This work has explored the influence of the incorporation of graphenes prepared by three typical methods on the electrochemical performance of the LiCoO_2-based cathode focusing on the choice for the effective graphene as conductive additive for the cathode of LIBs. Through the comparison of the intrinsic characteristics of graphenes and the electrochemical performance of electrodes with graphene, it is found that graphene with low disorder degree and large size is not suitable for LiCoO_2 cathodes as conductive additive. Conversely, the graphene with oxygen functional groups, relatively low surface area and proper size displays much better electrochemical performance when it is used as conductive additive. This work also demonstrates the transmission mechanism for different graphenes as conductive additives in the LiCoO_2 materials, and further reveals that the conductivity of graphene is not the only factor as conductive additives, surface chemistry and sheet size of the graphene are also essential factors which greatly influence the electrochemical performance of electrode. In addition, when combined with Super P, only 1% graphene is enough to construct an efficient conductive network in the electrode. This study also gives a new sight on the practical application of graphene as conductive additive for high performance LIBs.Ying Shi Lei Wen Songfeng Pei Minjie Wu Feng Li 2019Journal of Energy Chemistry2019,28,3:10
12High-temperature electrocatalysis and key materials in solid oxide electrolysis cells显示文摘Solid oxide electrolysis cells(SOECs)can convert electricity to chemicals with high efficiency at ~600-900℃,and have attracted widespread attention in renewable energy conversion and storage.SOECs operate in the inverse mode of solid oxide fuel cells(SOFCs)and therefore inherit most of the advantages of SOFC materials and energy conversion processes.However,the external bias that drives the electrochemical process will strongly change the chemical environments in both in the cathode and anode,therefore necessitating careful reconsideration of key materials and electrocatalysis processes.More importantly,SOECs provide a unique advantage of electrothermal catalysis,especially in converting stable low-carbon alkanes such as methane to ethylene with high selectivity.Here,we review the state-of-the-art of SOEC research progress in electrothermal catalysis and key materials and provide a future perspective.Lingting Ye Kui Xie 2021Journal of Energy Chemistry2021,30,3:9
13Understanding of performance degradation of LiNi0.80Co0.10Mn0.10O2 cathode material operating at high potentials显示文摘Inferior cycling stability, poor safety, and gas generation are long lasting problems of Ni-rich Li Ni0.80 Co0.10 Mn0.10 O2(NCM811) cathode material. Although much effort has been made, mechanisms for the above problems are poorly understood. Studying the cycling and float-charging characteristics of Li/NCM811 cells in high voltage conditions(4.5 V and 4.7 V, respectively), in this work we find that nearly all known problems with NCM811 material can be attributed to the oxidation of lattice oxygen occurring in the capacity region corresponding to H2 → H3 phase transition. While contributing to overall capacity,the oxidation of lattice oxygen results in a loss of oxygen through oxygen evolution and relative reactions between active oxygen evolution intermediates and electrolyte solvents. It is the loss of oxygen that results in irreversible layered-spinel-rocksalt phase transition, secondary particle cracking, and performance degradation. The conclusions of this work suggest that the priority for further research on NCM811 material should give to the suppression of oxygen evolution, followed by the use of the anti-oxygen electrolyte being chemically stable against the active oxygen evolution intermediates.Sheng SZhang 2020Journal of Energy Chemistry2020,29,2:9
14THERMODYNAMIC ANALYSIS OF Mo-La_2O_3 THERMIONIC CATHODE WIRE显示文摘THERMODYNAMICANALYSISOFMo-La_2O_3THERMIONICCATHODEWIRE¥ZhouMeiling;WangJinshu;ZhangJiuxing;NieZuoren;LiEr;ZuoTieyong(Departmen...Zhou Meiling Wang Jinshu Zhang Jiuxing Nie Zuoren Li Er Zuo Tieyong(Department of Materials Science and Engineering,Beijing Polytechnic University,Beijing 100022) 1996中国有色金属学会会刊:英文版1996,6,4:9
15Interfacial adsorption-insertion mechanism induced by phase boundary toward better aqueous Zn-ion battery显示文摘Biphasic and multiphasic compounds have been well clarified to achieve extraordinary electrochemical properties as advanced energy storage materials.Yet the role of phase boundaries in improving the performance is remained to be illustrated.Herein,we reported the biphasic vanadate,that is,Na_(1.2)V_(3)O_(8)/K_(2)V_(6)O_(16)·1.5H_(2)O(designated as Na0.5K0.5VO),and detected the novel interfacial adsorption-insertion mechanism induced by phase boundaries.Firstprinciples calculations indicated that large amount of Zn^(2+)and H^(+)ions would be absorbed by the phase boundaries and most of them would insert into the host structure,which not only promote the specific capacity,but also effectively reduce diffusion energy barrier toward faster reaction kinetics.Driven by this advanced interfacial adsorption-insertion mechanism,the aqueous Zn/Na_(0.5)K_(0.5)VO is able to perform excellent rate capability as well as long-term cycling performance.A stable capacity of 267 mA h g^(-1)after 800 cycles at 5 A g^(-1)can be achieved.The discovery of this mechanism is beneficial to understand the performance enhancement mechanism of biphasic and multiphasic compounds as well as pave pathway for the strategic design of highperformance energy storage materials.Lutong Shan Yiren Wang Shuquan Liang Boya Tang Yongqiang Yang Ziqing Wang Bingan Lu Jiang Zhou 2021InfoMat2021,3,9:8
16Facilitating Lithium-Ion Diffusion in Layered Cathode Materials by Introducing Li^(+)/Ni^(2+) Antisite Defects for High-Rate Li-Ion Batteries显示文摘Li^(+)/Ni^(2+) antisite defects mainly resulting from their similar ionic radii in the layered nickel-rich cathode materials belong to one of cation disordering scenarios.They are commonly considered harmful to the electrochemical properties,so a minimum degree of cation disordering is usually desired.However,this study indicates that LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)as the key material for Tesla batteries possesses the highest rate capability when there is a minor degree(2.3%)of Li^(+)/Ni^(2+) antisite defects existing in its layered structure.By combining a theoretical calculation,the improvement mechanism is attributed to two effects to decrease the activation barrier for lithium migration:(1)the anchoring of a low fraction of high-valence Ni^(2+) ions in the Li slab pushes uphill the nearest Li^(+)ions and(2)the same fraction of low-valence Li^(+) ions in the Ni slab weakens the repulsive interaction to the Li^(+) ions at the saddle point.Zhongfeng Tang Sen Wang Jiaying Liao Shuo Wang Xiaodong He Bicai Pan Haiyan He Chunhua Chen 2019Research2019,,1:8
17High-ionicity fluorophosphate lattice via aliovalent substitution as advanced cathode materials in sodium-ion batteries显示文摘As a cathode for sodium-ion batteries(SIBs),Na3V2(PO4)2F3(NVPF)with 3D open framework is a promising candidate due to its high working voltage and large theoretical capacity.However,the severe capacity degradation and poor rate capability hinder its practical applications.The present study demonstrated the optimization of Na-storage performance of NVPF via delicate lattice modulation.Aliovalent substitution of V^(3^(+))at Na^(+)in NVPF induces the generation of electronic defects and expansion of Na^(+)-migration channels,resulting in the enhancement in electronic conductivity and acceleration of Na^(+)-migration kinetics.It is disclosed that the formed stronger Na O bonds with high ionicity than V O bonds lead to the significant increase in structural stability and ionicity in the Na^(+)-substituted NVPF(NVPF-Nax).The aforementioned effects of Na^(+)substitution achieve the unprecedented electrochemical performance in the optimized Na_(3.14)V1.93Na0.07(PO_(4))_(2)F_(3)(NVPF-Na_(0.07)).As a result,NVPF-Na0.07 delivers a high-rate capability(77.5 mAh g^(−1)at 20 C)and ultralong cycle life(only 0.027%capacity decay per cycle over 1000 cycles at 10 C).Sodium-ion full cells are designed using NVPF-Na0.07 as cathode and Se@reduced graphene oxide as anode.The full cells exhibit excellent wide-temperature electrochemical performance from−25 to 25C with an outstanding rate capability(96.3 mAh g^(−1)at 20 C).Furthermore,it delivered an excellent cycling performance over 300 cycles with a capacity retention exceeding 90%at 0.5 C under different temperatures.This study demonstrates a feasible strategy for the development of advanced cathode materials with excellent electrochemical properties to achieve high-efficiency energy storage.Zhen-Yi Gu Jin-Zhi Guo Xin-Xin Zhao Xiao-Tong Wang Dan Xie Zhong-Hui Sun Chen-De Zhao Hao-Jie Liang Wen-Hao Li Xing-Long Wu 2021InfoMat2021,3,6:8
18Ni-based cathode materials for Na-ion batteries显示文摘Na-ion batteries(NIBs)have attracted significant attention owing to Na being an abundant resource that is uniformly distributed in the Earth's crust.Several 3d transition metal(TM)ions have been thoroughly investigated as charge compensators in single or multiple composition systems to enhance the electrochemical performance of cathodes for the practical applications.In this review,the composition-structure-property relationship of Ni-based cathodes has been reviewed as a design perspective for NIB'S cathodes.The typical Ni-based cathode materials have bee n systematically summarized and comparatively analyzed,and it is dem on strated that Ni io ns can be used to provide charge compensation.Moreover,Ni-based cathodes present high reversible capacity owing to the multi-electron redox reactions and suitable redox pote ntial of Ni-ions redox.However,con sidering the abundan ce,cost,and hygroscopic properties of Ni eleme nt,the content of 0.15-0.35 per formula can be optimal for enhancing the performance of cathodes.Lastly,further perspectives on designing Ni?containing cathodes,including Ni-rich layered cathodes,have been discussed,which could promote the practical applications of NIBs for grid-scale energy storage in future.Chenglong Zhao Yaxiang Lu Liquan Chen Yong-Sheng Hu 2019Nano Research2019,12,9:8
19Improving the stability of LiNi_(0.80)Co_(0.15)Al_(0.05)O_2 by AlPO_4 nanocoating for lithium-ion batteries显示文摘Nickel-rich layered materials,such as LiNi_(0.8)0Co_(0.15)Al_(0.05)O_2(NCA),have been considered as one alternative cathode materials for lithium-ion batteries(LIBs) due to their high capacity and low cost.However,their poor cycle life and low thermal stability,caused by the electrode/electrolyte side reaction,prohibit their prosperity in practical application.Herein,AlPO4 has been homogeneously coated on the surface of NCA via wet chemical method towards the target of protecting NCA from the attack of electrolyte.Compared with the bare NCA,NCA@AlPO_4 electrode delivers high capacity without sacrificing the discharge capacity and excellent cycling stability.After 150 cycles at 0.5 C between 3.0-4.3 V,the capacity retention of the coated material is 86.9%,much higher than that of bare NCA(66.8%).Furthermore,the thermal stability of cathode is much improved due to the protection of the uniform coating layer on the surface of NCA.These results suggest that AlPO4 coated NCA materials could act as one promising candidate for next-generation LIBs with high energy density in the near future.Ran Qi Ji-Lei Shi Xu-Dong Zhang Xian-Xiang Zeng Ya-Xia Yin Jian Xu Li Chen Wei-Gui Fu Yu-Guo Guo Li-Jun Wan 2017Science China Chemistry2017,60,9:8
20The development in aqueous lithium-ion batteries显示文摘To meet the growing energy demands, it is urgent for us to construct grid-scale energy storage system than can connect sustainable energy resources. Aqueous Li-ion batteries(ALIBs) have been widely investigated to become the most promising stationary power sources for sustainable energy such as wind and solar power. It is believed that advantages of ALIBs will overcome the limitations of the traditional organic lithium battery in virtue of the safety and environmentally friendly aqueous electrolyte. In the past decades, plentiful works have been devoted to enhance the performance of different types of ALIBs.In this review, we discuss the development of cathode, anode and electrolyte for acquiring the desired electrochemical performance of ALIBs. Also, the main challenges and outlook in this field are briefly discussed.Duan Bin Yunping Wen Yonggang Wan Yongyao Xia 2018Journal of Energy Chemistry2018,27,6:7
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