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| 1 | Effects of selenium on peripheral blood mononuclear cell membrane fluidity,interleukin-2 production and interleukin-2 receptor expression in patients with chronic hepatitis显示文摘AIM To study the effect of selenium on peripheral blood mononuclear cell (PBMC) membrane fluidity and immune function in patients with chronic hepatitis.METHODS: PBMCs were pretreated with selenium (1.156x 10.7 mol/L) for 6 h in vitro or extracted directly from patients after administration of selenium-yeast continuously for 8-12 wk (200 pg/d), and then exposed to Con-A for 48 h. The membrane fluidity, interleukin-2 (IL-2) production and interleukin-2 receptor (IL-2R) expression in PBMCs and malondialdehyde (MDA) concentration in medium and lipid peroxide (LPO) in plasma were determined.RESULTS: The PBMC membrane fluidity, IL-2 production and IL-2R expression in patients with chronic hepatitis were significantly lower than those in healthy blood donators (particle adhesive degree R, 0.17±0.01 vs 0.14±0.01,P<0.01; IL-2, 40.26±9.55 vs72.96±11.36, P<0.01, IL-2R,31.05±5.09 vs 60.58±10.56, P<0.01), and the MDA concentration in medium in patients with chronic hepatitis was significantly higher than that in healthy blood donators (1.44±0.08 vs0.93±0.08, P<0.01). Both in vitro and in vivo administration of selenium could reverse the above parameters.CONCLUSION: Supplement of selenium can suppress lipid peroxidation, and improve PBMC membrane fluidity and immune function in patients with chronic hepatitis. | Shui-XiangHe BingWu Xin-MingChang Hong-XiaLi WenQiao | 2004 | World Journal of Gastroenterology2004，10，23： | 9 |
| 2 | Aurora A orchestrates entosis by regulating a dynamic MCAK-TIP150 interaction显示文摘 | PengXia JinhuaZhou Xiaoyu Song BingWu XingLiu Di Li Shuyuan Zhang Zhikai Wang H uijuan Yu Tarsha Ward Jiancun Zhang Yinmei Li Xiaoning Wang YongChen Zhen Guo Xuebiao Yao | 2014 | Journal of Molecular Cell Biology2014，8，3： | 9 |
| 3 | Magnetic molecular materials with paramagnetic lanthanide ions显示文摘The diverse magnetic properties of lanthanide-based magnetic molecular materials are introduced in the following organization.First,the general aspects of magnetic molecular materials and electronic states of lanthanide ions are introduced.Then the structures and magnetic properties are described and analyzed for molecules with one lanthanide ion,4f-4f,4f-3d and 4f-p magnetic coupling interactions.In each section,magnetic coupling,magnetic ordering and magnetic relaxation phenomenon are briefly reviewed using some examples.Finally,some possibilities of developing magnetic molecular materials containing lanthanide ions are discussed in the outlook part. | WANG BingWu JIANG ShangDa WANG XiuTeng GAO Song | 2009 | Science China Chemistry2009，52，11： | 8 |
| 4 | Room temperature ferromagnetism in ultra-thin van der Waals crystals of 1T-CrTe2显示文摘Although many emerging new phenomena have been unraveled in two dimensional(2D)materials with long-range spin orderings,the usually low critical temperature in van der Waals(vdW)magnetic material has thus far hindered the related practical applications.Here,we show that ferromagnetism can hold above 300 K in a metallic phase of 1T-CrTe2 down to the ultra-thin limit.It thus makes CrTe2 so far the only known exfoliated ultra-thin vdW magnets with intrinsic long-range magnetic ordering above room temperature.An in-plane room-temperature negative anisotropic magnetoresistance(AMR)was obtained in ultra-thin CrTe2 devices,with a sign change in the AMR at lower temperature,with−0.6%and+5%at 300 and 10 K,respectively.Our findings provide insights into magnetism in ultra-thin CrTe2,expanding the vdW crystals toolbox for future room-temperature spintronic applications. | Xingdan Sun Wanying Li Xiao Wang Qi Sui Tongyao Zhang Zhi Wang Long Liu Da Li Shun Feng Siyu Zhong Hanwen Wang Vincent Bouchiat Manuel Nunez Regueiro Nicolas Rougemaille Johann Coraux Anike Purbawati Abdellali Hadj-Azzem Zhenhua Wang Baojuan Dong Xing Wu Teng Yang Guoqiang Yu Bingwu Wang Zheng Han Xiufeng Han Zhidong Zhang | 2020 | Nano Research2020，13，12： | 6 |
| 5 | Luminescent single-molecule magnet of metallofullerene DyErScN@Ih-C80显示文摘Magneto-luminescent molecules have significant applications in data storage and quantum computing.However,design of these bi-functional molecules coupled with magnetic behavior and photoluminescence is still challenging.In this work,we report a metallofullerene DyErScN @In-C80 exhibiting single-molecule magnet (SMM) behavior and near-infrared emission.For DyErScN @Ih-C80,two functional lanthanide metal ions of Dy^3+(SMM function) and Er^3+(luminescent function) are integrated inside a fullerene cage using a trimetallic nitride template,and its structure has been unambiguously characterized by single-crystal X-ray diffraction.Magnetic measurements revealed that DyErScN @Ih-C80 behaves as a SMM with a blocking temperature up to 9 K resulting from the intramolecular magnetic interaction between Dy^3+ and Er^3+ ions.Moreover,DyErScN @In-C80 exhibits temperature-dependent near-infrared emission around 1.5 pm with multiple splitting peaks from Er^3+,which arises from the influence of Dy^3+ ion.This study provides a new strategy to synthesize new magneto-luminescent molecule materials. | Mingzhe Nie Jin Xiong Chong Zhao Haibing Meng Kun Zhang Yibo Han Jie Li Bingwu Wang Lai Feng Chunru Wang Taishan Wang | 2019 | Nano Research2019，12，7： | 2 |
| 6 | Static field induced magnetic relaxations in dinuclear lanthanide compounds of [phen_2Ln_2(HCOO)_4(HCOO)_(2-2x)(NO_3)_(2x)](1,Ln=Gd and x=0.52; 2, Ln=Er and x=0.90; phen=1,10-phenanthroline)显示文摘Two dinuclear lanthanide (Ln) complexes, formulated as [phen2Ln2(HCOO)4(HCOO)2-2x(NO3)2x](1, Ln=Gd and x=0.52; 2, Ln = Er and x = 0.90; phen = 1,10-phenanthroline), were synthesized and characterized. They are isostructural. The dinuclear molecule consists of two Ln 3+ bridged by four formate groups and chelated by phen and formate/nitrate ligands, and the Ln 3+ possesses a coordination environment of distorted tri-capped trigonal prism of LnO 7 N 2 . Both compounds behave as paramagnets between 2 and 300 K, but display two static field induced magnetic relaxation processes. One is slow and of spin-lattice type, and it results from the lifting of Kramer's degeneracy of the ground-states of both Gd 3+ and Er 3+ , and the other is fast, and it might be spin-spin type. | LIU Bin WANG BingWu WANG ZheMing GAO Song | 2012 | Science China Chemistry2012，55，6： | 2 |
| 7 | Lightweight fault localization combined with fault context to improve fault absolute rank显示文摘Lightweight fault localization(LFL), which outputs a list of suspicious program entities in descending order based on their likelihood to be a root fault, is a popular method used by programmers to assist them in debugging. However, owing to the nature of program structures, it is impossible for LFL to always rank the root faulty program entity at the top of a ranking list. Recently, Xia et al. noted in their study that programmers inspect the first top-K-ranked program entities outputted by an LFL tool in sequence. Therefore,it is of practical significance to further improve the absolute rank of those buggy programs by using LFL if the root fault is ranked higher. To solve this issue, we propose a new LFL combined with a fault context to improve the fault absolute rank. We conduct experiments in which we apply our proposed approach to seven Siemens benchmark programs. The results show that by combining the suspiciousness scores of program entities with their fault-context suspiciousness scores that are based on an LFL called Dstar, our approach can improve the fault absolute rank with an effectiveness rate of 35.7% for 129 faulty versions from the seven benchmark programs. It should be noted that our approach can obtain an average improvement of 65.18% for those improved programs to which LFL can be effectively applied, and that there were improvements to seven top-ranked root faults of buggy programs. | Yong WANG Zhiqiu HUANG Yong LI Bingwu FANG | 2017 | Science China(Information Sciences)2017，60，9： | 1 |
| 8 | Calixarene-supported hexadysprosium cluster showing single molecule magnet behavior显示文摘The syntheses, crystal structures, magnetic and luminescent properties of three isomorphous compounds [Ln III 6 (μ 4-O) 2 (C4A) 2-(NO 3 ) 2 (HCOO) 2 (CH 3 O) 2 (DMF) 4 (CH 3 OH) 4 ] (Ln = Gd (1), Tb (2) and Dy (3); H 4 C4A = p-tert-butylcalix[4]arene) are reported. These three compounds are featured with the sandwich-like units constructed by two tail-to-tail calixarene molecules and an in-between Ln III 6 octahedron. The Dy III compound exhibits both single molecule magnet behavior and photoluminescence. | BI YanFeng XU GuanCheng LIAO WuPing DU ShangChao DENG RuiPing WANG BingWu | 2012 | Science China Chemistry2012，55，6： | 1 |
| 9 | A fungal protein elicitor PevD1 induces Verticillium wilt resistance in cotton显示文摘 | Bu Bingwu Qiu Dewen Zeng Hongmei | 2014 | Plant Cell Reports2014，33，3： | 1 |
| 10 | Theoretical study on potential energy curves and spectroscopy properties of ground and low-lying excited electronic states of BrCl^+显示文摘The calculations on the potential energy curves and spectroscopic constants of the ground and low-lying excited states of BrCl+,one of the important molecular ions in environment science,have been performed by using the multireference configuration interaction method at high level of theory in quantum chemistry.Through analyses of the effects of the spin-orbit coupling interaction on the elec-tronic structures and spectroscopic properties,the multiconfiguration characteristic of the X2Π ground state and low-lying excited states was established.The spin-orbit coupling splitting energy of the X2 Π ground state was calculated to be 1814 cm-1,close to the experimental value 2070 cm-1.The spin-orbit coupling splitting energy of the 2Π(Ⅱ) exited state was predicted to be 766 cm-1.The transition dipole moments and Frank-Condon factors of the 3/2(Ⅲ)-X3/2 and 1/2(Ⅲ)-1/2(I) transitions were estimated,and the radiative lifetimes of the two transitions were briefly discussed. | WANG MingWei WANG BingWu CHEN ZhiDa | 2008 | Science China Chemistry2008，51，6： | 1 |
| 11 | Effect of Naoling decoction on the expression of microglia and IL-6 in hippocampal CA3 region of rats with synthetic Alzheimer's disease显示文摘 | WANG Zhe WU Minghui ZHONG Bingwu | 2013 | Journal of Central South University(Medical Science)2013，2，： | 1 |
| 12 | Production of lipase by repeated batch fermentation with immobilized Rhizop us arrhizus显示文摘 | Yang Xuehao Wang Bingwu Cui Fengnan | 2005 | Process Biochemistry2005，40，： | 1 |
| 13 | A fungal protein elicitor PevD1 induces Verticillium wilt resistance in cotton显示文摘 | Bingwu Bu Dewen Qiu Hongmei Zeng Lihua Guo Jingjing Yuan Xiufen Yang | 2014 | Plant Cell Reports2014，，3： | 1 |
| 14 | Divalent Ytterbium Iodide Supported by β-Diketiminato Based Tridentate Ligand: Synthesis, Structure and Small Molecule Activation显示文摘Divalent ytterbium lodide[LYb(μ-I)(THF)]2(1;L=[MeC(NDIPP)CHC(Me)NCH2CH2NMe2]^-,DIPP=2,6-(iPr)2C6H3)was synthesized and its reactivity was studied.Complex 1 was synthesized by salt metathesis of Ybl2(THF)2 with the potassium salt of ligand(KL)in high yield.In the reactions with trimethylsil azide,azobenzene,sulfur and diphenyl disufide,complex 1 acts as a 2e reductant.In the reaction with CO2,the central carbon atom ofβ-diketiminato backbone in 1 nuclephilcally attacks the CO2 molecule to give a divalent ytterbium carboxylate. | Xiaojuan Liu Li Xiang Chen Wang Bingwu Wang Xuebing Leng Yaofeng Chen | 2020 | Chinese Journal of Chemistry2020，38，3： | 1 |
| 15 | Quasar candidate selection and photometric redshift estimation based on SDSS and UKIDSS data显示文摘 | Xue‐BingWu ZhendongJia | 2010 | Monthly Notices of the Royal Astronomical Society2010，，3： | 1 |
| 16 | Production of lipase by repeated batch fermentation with immobilized Rhizopus arrhizus显示文摘 | Yang Xuehao Wang Bingwu Cui Fengnan | 2005 | Process Biochemistry2005，40，： | 1 |
| 17 | Study on the covalence of Cu and chemical bonding in an inorganic fullerene-like molecule,[CuCl]_(20)[Cp^(*)FeP_(5)]_(12)[Cu-(CH_(3)CN)_(2)^(+)Cl^(-)]_(5),by a density functional approach显示文摘The electronic structure and chemical bonding in a recently synthesized inorganic fullerene-like molecule, {[CuCl]20[Cp*FeP5]12 [Cu(CH3CN)2+ Cl-]5}, has been studied by a density functional approach. Geometrical optimization of the three basic structural units of the molecule is performed with Amsterdam Density Functional Program. The results are in agreement with the experiment. Localized MO抯 obtained by Boys-Foster method give a clear picture of the chemical bonding in this molecule. The reason why CuCl can react with Cp*FeP5 in solvent CH3CN to form the fullerene-like molecule is explained in terms of the soft-hard Lewis acid base theory and a new concept of covalence. | WANG Bingwu XU Guangxian CHEN Zhida | 2004 | Science China Chemistry2004，47，2： | 0 |
| 18 | Bonding in [CuNRR′]4 type clusters显示文摘Many polynuclear Cu(I) compounds have been synthesized, but the problem whether there is direct or no direct Cu-Cu bonding in these compounds is not clear. The electronic structure of [CuNRR′]4 type clusters was investigated by using density functional methods. The results of geometrical optimization are in good agreement with experiment, and the localization of MO’s shows that there are four Cu-Cu s bonds to form the square Cu4 ring in addition to the four bridging Cu-N-Cu bonds. A concept of the covalence of molecular fragments is proposed to describe the bonding in these clusters. | WANG Bingwu XU Guangxian CHEN Zhida | 2004 | Science China Chemistry2004，47，3： | 0 |
| 19 | Iodine ion modification enables Ag nanowire film with improved carrier transport properties and stability as high-performance transparent conductor显示文摘Ag nanowire(NW)film is the promising next generation transparent conductor.However,the residual long-chain polyvinylpyrrolidone(PVP,introduced during the synthesis of Ag NWs)layer greatly deteriorates the carrier transport capability of the Ag NW film and as well its long-term stability.Here,we report a one-step I−ion modification strategy to completely replace the PVP layer with an ultrathin,dense layer of I^(−)ions,which not only greatly diminishes the resistance of the Ag NW film itself and that at interface of the Ag NW film and a functional layer(e.g.,a current collect electrode)but also effectively isolates the approaching of corrosive species.Consequently,this strategy can simultaneously improve the carrier transport properties of the Ag NW film and its long-term stability,making it an ideal electric component in diverse devices.For example,the transparent heater and pressure sensor made from the I^(−)-wrapped Ag NW film,relative to their counterparts made from the PVP-wrapped Ag NW film,deliver much improved heating performance and pressure sensing performance,respectively.These results suggest a facile post treatment approach for thin Ag NW film with improved carrier transport properties and long-term stability,thereby greatly facilitating its downstream applications. | Jianfang Liu Dongmei Deng Yongjie Ge Yaomengli Xu Moxia Li Bingwu Liu Xidong Duan Yongchun Fu Jiawen Hu | 2022 | Nano Research2022，15，6： | 0 |
| 20 | Static field induced magnetic relaxations in dinuclear lanthanide compounds of [phen_2Ln_2(HCOO)_4(HCOO)_(2-2x)(NO_(3))_(2x)] (1, Ln=Gd and x=0.52; 2, Ln=Er and x=0.90; phen=1,10-phenanthroline)显示文摘Two dinuclear lanthanide (Ln) complexes, formulated as [phen2Ln2(HCOO)4(HCOO)2-2x(NO3)2x] (1, Ln = Gd and x = 0.52; 2, Ln = Er and x = 0.90; phen = 1,10-phenanthroline), were synthesized and characterized. They are isostructural. The dinuclear molecule consists of two Ln3+ bridged by four formate groups and chelated by phen and formate/nitrate ligands, and the Ln3+ possesses a coordination environment of distorted tri-capped trigonal prism of LnO7N2. Both compounds behave as paramagnets between 2 and 300 K, but display two static field induced magnetic relaxation processes. One is slow and of spin-lattice type, and it results from the lifting of Kramer's degeneracy of the ground-states of both Gd3+ and Er3+, and the other is fast, and it might be spin-spin type. | LIU Bin WANG BingWu WANG ZheMing GAO Song | 2012 | 中国科学:化学2012，42，6： | 0 |
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