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| 1 | Mechanism of chain propagation for the synthesis of polyoxymethylene dimethyl ethers显示文摘Polyoxymethylene dimethyl ethers(PODE)were synthesized from the reaction of paraformaldehyde with dimethoxymethane(DMM)over different acid catalysts at different conditions.Products were found to follow the Schulz-Flory distribution law.The chain propagation proceeds through the insertion of an individual segment of CH2O one by one,while the simultaneous insertion of a few CH2O segments or their assembly is unlikely.Due to the restriction of this law,it is difficult to increase the selectivity to the desired products(e.g.,PODE3 4). | Yupei Zhao Zheng Xu Hui Chen Yuchuan Fu Jianyi Shen | 2013 | Journal of Energy Chemistry2013，22，6： | 36 |
| 2 | Controllable Synthesis of Co304 from Nanosize to Microsize with Large-Scale Exposure of Active Crystal Planes and Their Excellent Rate Capability in Supercapacitors Based on the Crystal Plane Effect显示文摘 | Yu Wang Ziyi Zhong Yang Chen Cheng Theng Ng Jianyi Lin | 2011 | Nano Research2011，4，7： | 8 |
| 3 | Synthesis of Large-Area, Few-Layer Graphene on Iron Foil by Chemical Vapor Deposition显示文摘我们表明一个简单、可控制的方法综合大区域,由优化化学蒸汽免职(CVD ) 的铁底层上的很少层 graphene 用甲烷和氢的混合物的方法。基于 Fe-C 阶段图的分析,为 Fe 表面上的 graphene 的成功的合成的一个合适的过程被设计。适当温度和冷却过程被发现在高度水晶的很少层 graphene 的合成很重要。基于 Graphene 的地效果晶体管(联邦货物税) 设备用产生很少层 graphene 被制作,并且与 3001150 cm2/ 的提取活动性显示出好质量(V 敢椠 ?? 敤瑢吗? | Yunzhou Xue Bin Wu Yunlong Guo Liping Huang Lang Jiang Jianyi Chen Dechao Geng Yunqi Liu Wenping Hu Gui Yu | 2011 | Nano Research2011，4，12： | 7 |
| 4 | An imine-linked covalent organic framework as the host material for sulfur loading in lithium–sulfur batteries显示文摘Lithium–sulfur(Li–S) batteries have high theoretical specific capacity, providing new opportunities for the next generation of secondary battery. Covalent organic framework(COF) as a new porous crystalline material has been used as the host material in Li–S battery to improve the cell's cycling stability. In this paper, an imine-linked TAPB-PDA-COF was applied as the host material for sulfur loading(60%) in Li–S battery. The TAPB-PDA-COF has a beehive-like morphology with high thermal stability(up to 500 ℃).In the electrochemical experiment, the performance of the composite cathode with acetylene black(AB) and super-P(S-P) as the conductive additives was studied individually. The initial discharge capacity under 0.2 A/g current density was 991 mAh/g and 1357 mAh/g for TAPB-PDA-COF/S@A-B and TAPB-PDACOF/S@S-P, respectively. The better result of S-P based cathode than A-B could be due to the better conductivity of the S-P, as proved by the EIS results. When further increased the current density to 2 A/g,the S-P based composite cathode can still deliver a comparable initial discharge capacity of 630 and 274 mAh/g capacity remained after 940 cycles. This results will inspire researchers develop more suitable conductive additives together with the host materials for high performance Li–S battery. | Jianyi Wang Liping Si Qin Wei Xujia Hong Ligui Lin Xin Li Jingyi Chen Peibiao Wen Yuepeng Cai | 2019 | Journal of Energy Chemistry2019，28，1： | 7 |
| 5 | Dendrite‐free lithium and sodium metal anodes with deep plating/stripping properties for lithium and sodium batteries显示文摘Although lithium(Li)and sodium(Na)metals can be selected as the promising anode materials for next‐generation rechargeable batteries of high energy density,their practical applications are greatly restricted by the uncontrollable dendrite growth.Herein,a platinum(Pt)–copper(Cu)alloycoated Cu foam(Pt–Cu foam)is prepared and then used as the substrate for Li and Na metal anodes.Owing to the ultrarough morphology with a threedimensional porous structure and the quite large surface area as well as lithiophilicity and sodiophilicity,both Li and Na dendrite growths are significantly suppressed on the substrate.Moreover,during Li plating,the lithiated Pt atoms can dissolve into Li phase,leaving a lot of microsized holes on the substrate.During Na plating,although the sodiated Pt atoms cannot dissolve into Na phase,the sodiation of Pt atoms elevates many microsized blocks above the current collector.Either the holes or the voids on the surface of Pt–Cu foam what can be extra place for deposited alkali metal,what effectively relaxes the internal stress caused by the volume exchange during Li and Na plating/stripping.Therefore,the symmetric batteries of Li@Pt–Cu foam and Na@Pt–Cu foam have both achieved long‐term cycling stability even at ultrahigh areal capacity at 20 mAh cm−2. | Jianyi Wang Qi Kang Jingchao Yuan Qianru Fu Chunhua Chen Zibo Zhai Yang Liu Wei Yan Aijun Li Jiujun Zhang | 2021 | Carbon Energy2021，3，1： | 6 |
| 6 | Sensitivity of green and blue-green algae to methyl tert-butyl ether显示文摘The toxicity of methyl tert-butyl ether (MTBE) to Chlorella ellipsoidea and Aphanizomenon flos-aquae was tested and assessed for a 15-d incubation with concentrations of MTBE from high (2.00×104 mg/L) to low (2 mg/L). The results showed that the toxicity was low when the concentration of MTBE was in the range 1.00×104-2.00×104 mg/L (the greatest inhibition of growth-rate was 70%-71%, occurred during the day 1-5). Low concentrations (2-500 mg/L) stimulated algal growth up to the greatest effect of 85%-200% when the concentration of MTBE was 50-100 mg/L during day 3-5. The toxicity of MTBE (72-120 h EC50) was 6.65×103-9.58×103 mg/L for C. ellipsoidea and that is 1.14×104-2.00×104 mg/L for A. floc-aquae. We found that the toxicity and ecological risk of MTBE for the algal community structure were low and the toxicity was influenced by the duration time of the test. | CHEN Jianmeng MA Jianyi CAO Wei WANG Pinwei TONG Senmiao SUN Yizhao | 2009 | Journal of Environmental Sciences2009，21，4： | 5 |
| 7 | Effect of loading on the Ni_2P/Al_2O_3 catalysts for the hydrotreating reactions显示文摘The 80%Ni2P/Al2O3 catalysts were prepared by the phosphidation of corresponding 80%Ni/Al2O3 with triphenylphosphine in liquid phase and compared with the 60%Ni2P/Al2O3 for hydrotreating reactions. Both the60%Ni2P/Al2O3 and 80%Ni2P/Al2O3 in comparison exhibited the small and uniform Ni2 P particles(6.3 and8.4 nm,respectively),high CO uptakes(305 and 345 μmol/g,respectively) and thus high activities for the hydrotreating reactions. After the hydrotreating reactions,the small and uniform Ni2 P particles were remained,although the CO uptakes on the used 60%Ni2P/Al2O3 and 80%Ni2P/Al2O3 were greatly decreased(to 68 and95 μmol/g,respectively) due to the incorporation of S into the Ni2 P surfaces. The 80%Ni2P/Al2O3 was found to be significantly more active than the 60%Ni2P/Al2O3 due to that the 80%Ni2P/Al2O3 possessed more,and more active Ni2 P sites than the 60%Ni2P/Al2O3,probably due to the less S incorporated in the 80%Ni2P/Al2O3 than in the 60%Ni2P/Al2O3 during the hydrotreating reactions. | Junen Wang Shaozhong Li Jun Xu Hui Chen Jiangyu Yuan Jianyi Shen | 2015 | Journal of Energy Chemistry2015，24，4： | 4 |
| 8 | Identifying human body states by using a flexible integrated sensor显示文摘Flexible sensors are required to be lightweight,compatible with the skin,sufficiently sensitive,and easily integrated to extract various kinds of body vital signs during continuous healthcare monitoring in daily life.For this,a simple and low-cost flexible temperature and force sensor that uses only two carbon fiber beams as the sensing layer is reported in this work.This simple,flexible sensor can not only monitor skin temperature changes in real time but can also extract most pulse waves,including venous waves,from most parts of the human body.A pulse diagnostic glove containing three such flexible sensors was designed to simulate pulse diagnostic methods used in traditional Chinese medicine.Wearable equipment was also designed in which four flexible sensors were fixed onto different body parts(neck,chest,armpit,and fingertip)to simultaneously monitor body temperature,carotid pulse,fingertip artery pulse,and respiratory rate.Four important physiological indicators—body temperature(BT),blood pressure(BP),heart rate(HR),and respiratory rate(RR)—were extracted by the wearable equipment and analyzed to identify exercise,excited,tired,angry,and frightened body states. | Ying Jin Guoning Chen Kete Lao Songhui Li Yong Lu Yufeng Gan Zhundong Li Jiajia Hu Jingcheng Huang Jinxiu Wen Honggui Deng Min Yang Zhiming Chen Xiaoyan Hu Baowen Liang Jianyi Luo | 2020 | npj Flexible Electronics2020，4，1： | 2 |
| 9 | Preparation of Fe_2P/Al_2O_3 and FeP/Al_2O_3 catalysts for the hydrotreating reactions显示文摘A 60%Fe/Al_2O_3 catalyst was prepared by the co-precipitation method.It was reduced by H_2 to produce metallic Fe,which was then sulfided by CS_2 to Fe_(0.96) S and Fe_3S_4 or phosphided by triphenylphosphine(PPh3) in liquid phases to Fe2 P and Fe P.It was found that the iron sulfides(Fe0.96 S and Fe_3S_4) exhibited the low activity for the hydrodesulfurization(HDS) reactions.The HDS activity was also low on the Fe(metal)/Al_2O_3 and Fe_2 P/Al_2O_3 catalysts since they were converted into Fe0.96 S and Fe_3S_4 during the HDS reactions.In contrast,the FeP/Al_2O_3 was found to be stable and active for the HDS reactions.In particular,Fe P/Al_2O_3 possessed significantly smaller Fe P particles than Fe P/C,leading to the significant higher HDS activity of FeP/Al_2O_3 than Fe P/C. | Yamei Yuan Jiayou Zhang Hui Chen Qiumei Hou Jianyi Shen | 2019 | Journal of Energy Chemistry2019，28，2： | 2 |
| 10 | Review of surface transient charge measurement on solid insulating materials via the Pockels technique显示文摘Surface charges accumulated on solid insulating materials in electrical apparatuses and electronic devices could distort the initial electric field and severely damage the insulation performance.Accurate transient surface charge measurement is critical to determine the mechanisms of charge transport and flashover occurrence,and estimate surface insulation strength under high voltage.The measurement technique based on the Pockels electro-optic effect is considered as the only approach for 2-D dynamic charge distribution behaviour so far,and it has good capability to avoid original electric field distortion caused by conven-tional methods featured by metal probes.This paper reviews recent progress of the non-invasive dynamic surface charge measurement systems on the Pockels technique.We focus especially on typical systems with transmitting and reflecting configurations and the frequently used fast inversion algorithms.It can be inferred that higher spatial-temporal resolution,higher signal-to-noise ratio,and better compatibility for both transparent and opaque materials are the future development trends,which greatly depend on multiple technological breakthroughs at impact-resistant electro-optic crystals,advanced high-speed photography and high-performance inversion algorithms.In addition,the recent studies on transient behaviour of surface discharge,together with the present limitation and future prospects are discussed.It is expected that more ideas will be inspired in transient surface charge measurement by the Pockels technique and other relevant electro-optic methods. | Bo Zhang Jianyi Xue Xingyu Chen Sile Chen Haibao Mu Yang Xu Guanjun Zhang | 2021 | High Voltage2021，6，4： | 2 |
| 11 | Silicon photonic network-on-chip and enabling components显示文摘As the transistor's feature scales down and the integration density of the monolithic circuit increases continuously,the traditional metal interconnects face significant performance limitation to meet the stringent demands of high-speed,low-power and low-latency data transmission for on-and off-chip communications.Optical technology is poised to resolve these problems.Due to the complementary metal-oxide-semiconductor(CMOS) compatible process,silicon photonics is the leading candidate technology.Silicon photonic devices and networks have been improved dramatically in recent years,with a notable increase in bandwidth from the megahertz to the multi-gigahertz regime in just over half a decade.This paper reviews the recent developments in silicon photonics for optical interconnects and summarizes the work of our laboratory in this research field. | HU Ting QIU Chen YU Ping YANG LongZhi WANG WanJun JIANG XiaoQing YANG Mei ZHANG Lei YANG JianYi | 2013 | Chinese Science Bulletin2013，58，7： | 2 |
| 12 | Ultrahigh Density Modulation of Aligned Single-Walled Carbon Nanotube Arrays显示文摘在圣切割石英上控制排列的围单人赛的碳 nanotube 数组(SWNT ) 的密度是在这些材料的各种各样的应用的关键步。然而为调节 SWNT 密度使用的生长机制化学蒸汽免职(CVD ) 方法仍然不好理解,阻止获得需要的结果的有效方法的发展。这里,我们报导完成的一条一般周期的途径超离频圣切割石英 substrateswith 密度上的 SWNT 数组的密度调整用改变 CH4 气体离开时间的一样的催化剂 densitiesby 与常规方法相比到多达 60 次增加了。这条途径对大量起始的催化剂密度,底层,催化剂类型和生长条件适用。我们为与不同的免费的碳集中联系的 SWNT 的催化剂尺寸依赖者成核建议一般机制,它解释所有观察。而且,模型的有效性被在周期的 CVD 途径包含关键参数的变化的系统的实验支持。 | Bin Wu Dechao Geng Yunlong Guo Liping Huang Jianyi Chen Yunzhou Xue Gui Yu Yunqi Liu Hisashi Kajiura Yongming Li | 2011 | Nano Research2011，4，10： | 1 |
| 13 | Thermally enhanced responsivity in an all-silicon optical power monitor based on defect-mediated absorption显示文摘We demonstrate a high responsivity all-silicon in-line optical power monitor by using the thermal effect to enhance the quantum efficiency of defect-mediated absorption at 1550 nm.The doping compensation technique is utilized to increase the density of lattice defects responsible for the sub-bandgap absorption and suppress the detrimental free carrier absorption.The 200-μm-long device presents a propagation loss as low as 2.9 d B/cm.Its responsivity is enhanced from 12.1 m A/W to 112 m A/W at-9 V bias by heating the optical absorption region.With this device,we build an optical power monitoring system that operates in the sampling mode.The minimal detectable optical power of the system is below-22.8 d Bm,while the average power consumption is less than1 m W at a sampling frequency of 10 Hz.Advantages of this scheme in terms of high responsivity,low insertion loss,and low power consumption lend itself to implement the feedback control of advanced large-scale silicon photonic integrated circuits. | QIKAI HUANG HUI YU QIANG ZHANG YAN LI WEIWEI CHEN YUEHAI WANG JIANYI YANG | 2021 | Photonics Research2021，9，11： | 1 |
| 14 | Optical Switch Based on Multimode Interference Coupler显示文摘 | Wang Fan Yang Jianyi Chen Limei Jiang Xiaoqing Wang Minghua | 2006 | IEEE Photonecs Technology Letters2006，18，2： | 1 |
| 15 | Molecular catalysis for the steam reforming of ethanol显示文摘In this paper,the application of molecular catalysis for steam reforming of ethanol(SRE)is reviewed.Eight metals(Ni,Co,Cu,Pt,Rh,Pd,Ir and Ru)have shown high catalytic activity for SRE.Among them Ni and Rh are very promising because of high d character in the metal bond and low metal-oxygen bonding(vs.metal-carbon).They can effectively promote C–C bond cleavage in the rate-determining process during SRE.However,Rh is weak in water-gas-shift so that CH4 and CO become the main by-products at low reaction temperatures,while Ni catalysts suffer from rapid deactivation due to coking and sintering.Two low-temperature CO-free catalysts have been developed in our lab,namely Rh-Fe/Ca-Al2O3 and carbonyl-derived Rh-Co/Ce O2,in which the presence of iron oxide or Co can promote water-gas-shift reaction and significantly improve the SRE performance.On the other hand,adding 3 wt%Ca O to Ni/Al2O3 can greatly improve the catalyst stability because the Ca modification not only increases Ni concentration on the Ni/Ca-Al2O3 surface and 3d valence electron density,but also facilitates the water adsorption and coke gasification via water-gas-shift.The availability of abundant surface OH groups helps the formation and conversion of adsorbed formate intermediate.Hence,ethanol reaction on Ca-Al2O3-supported Ni,Pt,Pd and Rh catalysts are found to follow the formate-intermediated pathway,a new reaction pathway alternative to the traditional acetate-intermediated pathway. | Jianyi Lin Luwei Chen Catherine Kai Shin Choong Ziyi Zhong Lin Huang | 2015 | Science China Chemistry2015，58，1： | 1 |
| 16 | Design and finite-element analysis of an outer-rotor permanent-magnet generator for directly coupled wind turbines显示文摘 | Chen Jianyi Chemmangot V Nayar Xu Longya | 2000 | IEEE Transactions on Magnetics2000，36，5： | 1 |
| 17 | Combination of MALDI-TOF mass spectrometry with immobilized enzyme microreactor for peptide mapping显示文摘 | Honghai Jiang Hanfa Zou Hailin Wang Qiang Zhang Jianyi Ni Qingchun Zhang Zhong Guo Xiaoming Chen | 2000 | Science in China Series B: Chemistry2000，，6： | 1 |
| 18 | Grinding characteristics in high speed grinding of engineering ceramics with brazed diamond wheels显示文摘 | Jianyi Chen Jianyun Shen Hui Huang Xipeng Xu | 2011 | Journal of Materials Processing Technology2011，210，6： | 1 |
| 19 | Design and FE analysis of an outer-rotor PM generator for directly-coupled wind turbine applications显示文摘 | JianYi Chen ChemNayar Longya Xu | 1998 | IEEE Industry Applications Conference1998，1，1： | 1 |
| 20 | Polybenzimidazole functionalized electrolyte with Li-wetting and self-fluorination functionalities for practical Li metal batteries显示文摘Rough Li plating,low ionic conductivity,and low thermal stability of conventional electrolytes post-primary challenges for achieving reliable high-capacity rechargeable lithium batteries,for which lithiummetal is frequently proposed as themost promising anode material.Conventional low-polarity commercial polypropylene/polyethylene separators fail to support the application of high-energy-density Li anodes due to their rigid physicochemical properties and the high reactivity of Li metal,leading to fatal dendrite formation and vigorous exothermic reaction with electrolytes.Herein,we develop a Li-wetting,flame-retardant binary polymer electrolyte by functionalizing poly(vinylidene fluoride)(PVDF)separators with nonflammable polybenzimidazole(PBI)to build safe room-temperature solid-state electrolyte membranes.A dendrite-free LiFePO4 cell with the solid polymer electrolyte(SPE)delivers a discharge capacity of 127 mAh g^(-1) at 25℃ with a capacity retention of 87.5%after 500 cycles at 0.5℃(0.15 mA cm^(-2)).Phase-field simulations and density functional theory calculations demonstrate that the negatively charged benzimidazole chains of PBI own superior affinity to lithium bis(trifluoromethanesulfonyl)imide(LiTFSI),and shares overlapping electron density with Li anode,giving rise to accelerated Li^(+)conduction at room temperature and uniform Li electrodeposition at the electrolyte/Li metal interface.The SPE is also flame-retardant since heat-resistant polytetrafluoroethylene and a dense,heat-blocking graphitized carbon layer are formed in intense heat throughdehydrogenation/fluorination of PVDF under the catalysis of Lewis base imidazole rings and the decomposition of benzimidazole rings in PBI.No such fire-resistant mechanism is ever reported in conventional electrolytes. | Dongjiang Chen Yuanpeng Liu Chuan Xia Yupei Han Qingwei Sun Xuchang Wang Wei Chen Xian Jian Weiqiang Lv Jianyi Ma Weidong He | 2022 | InfoMat2022，4，5： | 1 |
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