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| 1 | Enhanced stability of Pt nanoparticle electrocatalysts for fuel cells显示文摘尽管聚合物电解质膜燃料房间(PEMFC ) 由于他们的几乎零排出物,高力量密度,和高效率收到了宽广注意,目前, electrocatalysts 的有限稳定性在 PEMFC 使用了是到他们的大规模商品化的批评限制。作为流行地使用的 electrocatalyst 材料的一种类型,尽管高度碳,磅溶解,成熟的 Ostwald,和在严厉化学、电气化学的氧化下面的磅 nanoparticles (NP ) 的聚集的 efficientundergoes 腐蚀调节,碳黑色支持了铂(Pt/C ) ,它导致 electrocatalysts 的表演降级。以便克服这些劣势,许多组试着改进磅在上被装载的碳支持材料。它在强烈氧化下面与高表面区域,足够的抛锚地点,高电的传导性,和高氧化抵抗被发现了那一些小说碳 nanomaterials 和 noncarbon 材料在 PEMFC 的状况是理想的其他的支持。这评论加亮下列方面:(i) 在使用新奇的碳 nanomaterials 和 noncarbon 的最近的进展支持材料提高 electrocatalysts 的长期的耐久性;(ii ) 改进电的传导性,表面区域,和在金属和支持之间的强壮的相互作用的答案;并且(iii ) 在帮助的混合支持的 synergistic 效果改进 electrocatalysts 的稳定性。 | Li Li Linping Hu Jin Li Zidong Wei | 2015 | Nano Research2015，8，2： | 13 |
| 2 | Controlled synthesis of single cobalt atom catalysts via a facile one-pot pyrolysis for efficient oxygen reduction and hydrogen evolution reactions显示文摘Metal-nitrogen doped carbon catalysts(M-N/C) with abundantly accessible M-Nxsites, particularly single metal atom M-N/C(SAM-N/C), have been developed as a substitute for expensive Pt-based catalysts.These catalysts are used to increase the efficiency of otherwise sluggish oxygen reduction reactions(ORR) and hydrogen evolution reactions(HER). However, although the agglomerated metal nanoparticles are usually easy to form, they are very difficult to remove due to the protective surface-coating carbon layers, a factor that significantly hampers SAM-N/C fabrication. Herein, we report a one-step pyrolysis approach to successfully fabricate single cobalt atom Co-N/C(SACo-N/C) by using a Co2+-SCN-coordination compound as the metal precursor. Thanks to the decomposition of Co2+-SCN-compound at lower temperature than that of carbon layer deposition, Co-rich particles grow up to larger ones before carbon layers formation. Even though encapsulated by the carbon layers, it is difficult for the large Co-rich particle to be completely sealed. And thus, it makes the Co atoms possible to escape from incomplete carbon layer, to coordinate with nitrogen atoms, and to form SACo-N/C catalysts. This SACo-N/C exhibits excellent performances for both ORR(half-wave potential of 0.878 V) and HER(overpotential at 10 mA/cm2 of178 m V), and is thus a potential replacement for Pt-based catalysts. When SACo-N/C is integrated into a Zn-O2 battery, battery with high open-circuit voltage(1.536 V) has high peak power density(266 mW/cm2)and large gravimetric energy density(755 mA h/gZn) at current densities of 100 mA/cm2. Thus, we believe that this strategy may offer a new direction for the effective generation of SAM-N/C catalysts. | Yao Wang Linhui Chen Zhanxin Mao Lishan Peng Rui Xiang Xianyi Tang Jianghai Deng Zidong Wei Qiang Liao | 2019 | Science Bulletin2019，64，15： | 10 |
| 3 | Hierarchically porous nitrogen-doped carbon as cathode for lithium–sulfur batteries显示文摘Porous nitrogen-doped carbon is an especially promising material energy storage due to its excellent conductivity, stable physicochemical properties, easy processability, controllable porosity and low price.Herein, we reported a novel well-designed hierarchically porous nitrogen-doped carbon(HPNC) via a combination of salt template(ZnCl_2) and hard template(SiO_2) as sulfur host for lithium–sulfur batteries. The low-melting ZnCl_2 is boiled off and leaves behind micropores and small size mesopores during pyrolysis process, while the silica spheres are removed by acid leaching to generate interconnected 3D network of macropores. The HPNC-S electrode exhibits an initial specific capacity of 1355 mAh g^(–1) at 0.1 C(1 C = 1675 m Ah g^(–1)), a high-rate capability of 623 m Ah g^(–1) at 2 C, and a small decay of 0.13% per cycle over 300 cycles at 0.2 C. This excellent rate capability and remarkable long-term cyclability of the HPNC-S electrode are attributed to its hierarchical porous structures for confining the soluble lithium polysulfide as well as the nitrogen doping for high absorbability of lithium polysulfide. | Rui Wu Siguo Chen Jianghai Deng Xun Huang Yujie Song Ruiyi Gan Xiaoju Wan Zidong Wei | 2018 | Journal of Energy Chemistry2018，27，6： | 8 |
| 4 | DFT study of difference caused by catalyst supports in Pt and Pd catalysis of oxygen reduction reaction显示文摘Based on an experimental phenomenon that catalytic activity of Pt and Pd for oxygen reduction reaction (ORR) changes with catalyst supports from C to TiO2, density function theory (DFT) was used to elucidate the cause behind the difference in catalysis caused by catalyst supports. First, factors closely associated with the first electron transfer of the ORR were assessed in the light of quantum chemistry. Then intermediate (atomic oxygen, O) adsorption strength on the catalyst surface was calculated. The results show that, in terms of minimum energy difference, the best orbital symmetry match, and the maximum orbital overlap, TiO2 does bring about a very positive effect on catalysts Pd/TiO2 for the first electron transfer of the ORR. Especially, TiO2 remarkably expands the space size of Pd/TiO2 HOMO orbital and improves orbital overlap of Pd/TiO2 HOMO and O2 LUMO. The analysis of deformation density and partial density of state shows that the strong interaction between Pt and Ti leads to a strong adsorption of intermediate O on Pt/TiO2, but the strong interaction between Pd and surface O causes positive net charge of Pd and a weak adsorption of intermediate O on Pd/TiO2. Thus, the ORR can proceed more smoothly on Pd/TiO2 than Pt/TiO2 in every respect of maximum orbital overlap and rate delay by intermediate O. The research also discloses that several factors lead to less activity of TiO2-supported Pt and Pd catalysts than the C-supported ones for the ORR. These factors include the poor dispersion of Pt and Pd particles on TiO2, poor electric conduction of TiO2 carrier itself, and bigger energy difference between HOMO of TiO2-carried metallic catalysts and LUMO of O2 molecule due to electrons deeply embedded in the semiconductor TiO2 carrier. | LI Li WEI ZiDong ZHANG Yi QI XueQiang XIA MeiRong ZHANG Jie SHAO ZhiGang SUN CaiXin | 2009 | Science China Chemistry2009，52，5： | 6 |
| 5 | Enhancing the stability and activity by anchoring Pt nanoparticles between the layers of etched montmorillonite for oxygen reduction reaction显示文摘Proton exchange membrane fuel cells(PEMFCs)are recognized as potential environmentally friendly power sources owing to their high energy conversion efficiency and low pollutant emissions[1–4].However,the insufficient electrocatalytic durability of Pt cathode catalysts remains one of the major obstacles for their wide applications[5–8].The Pt cathode catalyst is predominantly | Wei Li Wei Ding Yao Nie Xueqiang Qi Guangping Wu Li Li Jianhua Liao Siguo Chen Zidong Wei | 2016 | Science Bulletin2016，61，18： | 5 |
| 6 | Enhanced Photocatalytic Activity of Nanoparticle-Aggregated Ag–AgX(X=Cl, Br)@TiO_2 Microspheres Under Visible Light显示文摘Ag–AgX(X = Cl, Br)@TiO_2 nanoparticle-aggregated spheres with different mass ratio of R = TiO2/Ag(X) from 35:1 to 5:1 were synthesized by a facile sol–gel technique with post-photoreduction. The photocatalytic activities of both Ag–Ag Cl@TiO_2 and Ag–Ag Br@TiO_2 under visible light are effectively improved by ~3 times relative to TiO_2 NPAS under the simulated sunlight for the decomposition of methyl orange(MO). Ag–AgBr@TiO_2 showed 30% improvement and less stable in photocatalytic activity than that of AgCl@TiO_2. The role of Ag and Ag X nanoparticles on the surface of Ag–Ag X(X = Cl,Br)@TiO_2 was discussed. Ag on these samples not onlycan efficiently harvest visible light especially for Ag Cl, but also efficiently separate excited electrons and holes via the fast electron transfer from Ag X(X = Cl, Br) to metal Ag nanoparticles and then to TiO_2-aggregated spheres on the surface of heterostructure. On the basis of their efficient and stable photocatalytic activities under visible-light irradiation, these photocatalysts could be widely used for degradation of organic pollutants in aqueous solution. | Cuiling Zhang Hao Hua Jianlin Liu Xiangyu Han Qipeng Liu Zidong Wei Chengbin Shao Chenguo Hu | 2017 | Nano-Micro Letters2017，9，4： | 5 |
| 7 | A DFT study on PtMo resistance to SO_2 poisoning显示文摘Pt is a catalyst in proton exchange membrane fuel cell (PEMFC), and its activity will be degraded in the air due to the existence of SOx impurities. On strategy is introducing of Mo into the Pt catalyst because it can improve the SOx -tolerance capacity. Based on the aforementioned phenomenon, a density function theory (DFT) study on SO x adsorbed on Pt(111) and PtMo(111) was performed to enhance Pt catalytic activity. The adsorption energy of adsorbed species, the net change, partial density of state (PDOS), and d-band center were calculated and analyzed comparatively. The results show that the presence of Mo-atom weakens the S-Pt bond strength and reduces the adsorption energies for SO2 , S and SO3 on PtMo(111). Moreover, the Mo atom weakens the effects of SO2 on the PtMo(111) electronic structure and makes the catalyst maintains its original electronic structure after SO2 adsorption as compared with Pt(111). | XIA MeiRong LIU Ying LI Li XIONG Kun QI XueQiang YANG LinJiang HU BaoShan XUE Yun WEI ZiDong | 2013 | Science China Chemistry2013，56，7： | 4 |
| 8 | Wavy PtCu alloy nanowire networks with abundant surface defects enhanced oxygen reduction reaction显示文摘Bimetalic platinum-copper(Pt-Cu)alloy nanowires have emerged as a novel class of fuel cell electrocatalysts for oxygen reduction reaction(ORR)due to their intrinsic high catalytic activity and durability,but preparing such electrocatalysts with clean surface via facile method is still a challenge.Herein,PtCu alloy with nanowire networks(NWNs)structure is obtained by a simple modified polyol method accompanied with a salt-mediated self-assembly process in a water/ethylene glycol(EG)mixing media.The formation mechanism of PtCu NWNs including the morphological evolution and the relevant experimental parameters has been investigated systematically.We propose that a micro-interface in H2O-EG media formed with the assistance of disodium dihydrogen pyrophosphate(Na2H2P2O7)and its unique nature of coordinating with Pt^2+ or Cu^2+ play critical roles in the formation of NWNs.When tested as ORR catalyst,the PtCuNWNs/C exhibits much higher activity and durability than that of PtNWNs/C and commercial PtC,even exceeding the target of DOE in 2020.The excellent performance of PtCuNWNs/C could be attributed to the unique structure of NWNs with 2.4 nm ultrathin wavy nanowires and plentiful surface defects and the modified electronic effect caused by alloying with Cu atoms. | Dahui Fang Lei Wan Qike Jiang Hongjie Zhang Xuejun Tang Xiaoping Qin Zhigang Shao Zidong Wei | 2019 | Nano Research2019，12，11： | 4 |
| 9 | Effects of substrate and transfer on CVD-grown graphene over sapphire-induced Cu films显示文摘We differentiated the effects of Cu films deposited on single crystalline a-,r-,and c-plane sapphire substrates upon graphene films synthesized with atmospheric pressure chemical vapor deposition(CVD).The data illustrate that the realization of high-crystalline Cu film is dependent not only on the crystallinity of underlying substrate,but also on the symmetric match of crystallographic geometry between metal film and substrate.We also systematically investigated the effects of PMMA removal on the Raman ID/IG and IG/I2D values of transferred graphene.The results reveal that different PMMA removal methods do not alter the ID/IG values;instead,the residue of PMMA increases the IG/I2D values and the thermal decomposition of PMMA leads to higher IG/I2D values than the removal of PMMA with acetone.The effects of PMMA removal on variations of the Raman spectra are also discussed. | HU BaoShan WEI ZiDong AGO Hiroki JIN Yan XIA MeiRong LUO ZhengTang PAN QingJiang LIU YunLing | 2014 | Science China Chemistry2014，57，6： | 4 |
| 10 | Chemical oscillation in electrochemical oxidation of methanol on Pt surface显示文摘Based on dual path reaction mechanism, a nonlinear dynamics model reflecting the potential oscilla- tion in electrooxidation of methanol on Pt surface was established. The model involves three variables, the electrode potential (e), the surface coverage of carbon monoxide (x), and adsorbed water (y). The chemical reactions and electrode potential were coupled together through the rate constant ki = exp(ai(e ? ei)). The analysis to the established model discloses the following: there are different kinetics be- haviors in different ranges of current densities. The chemical oscillation in methanol electrooxidation is assigned to two aspects, one from poison mediate CO of methanol electrooxidation, which is the in- duced factor of the chemical oscillation, and the other from the oxygen-containing species, such as H2Oa. The formation and disappearance of H2Oa deeply depend on the electrode potential, and directly cause the chemical oscillation. The established model makes clear that the potential oscillation in methanol electrooxidation is the result of the feedback of electrode potential e on the reactions in- volving poison mediates CO and oxygen-containing species H2Oa. The numerical analysis of the estab- lished model successfully explains why the potential oscillation in methanol galvanostatic oxidation on a Pt electrode only happens in a certain range of current densities but not at any current density. | LI LanLan WEI ZiDong QI XueQiang SUN CaiXin YIN GuangZhi | 2008 | Science China Chemistry2008，51，4： | 3 |
| 11 | Recent progress of mesoscience in design of electrocatalytic materials for hydrogen energy conversion显示文摘Electrocatalytic materials with different morphologies,sizes,and components show different catalytic behavior in various heterogeneous catalytic reactions.It has been proved that the catalytic properties of these materials are strongly influenced by several factors at different levels,including the electrode morphology,reaction channels,three-phase interface,and surface active sites.Recent developments of mesoscience allow one to study the relationship between the apparent catalytic performance of electro-catalytic materials with these factors from different levels.In this review,following a brief introduction of new mesoscience,we summarize the effect of mesoscience on electrocatalytic material design,including modulating the geometric and electronic structures of materials focusing on morphology(particulate,fiber,film,array,monolith,and superlattice),pore structure(microporous,mesoporous,and hierarchical),size(single atoms,nanoclusters,and nanoparticles),multiple components(alloys,heterostructures,and multiple ligands),and crystal structures(crystalline,amorphous,and multiple crystal phases).By evaluating the electrocatalytic performance of catalytic materials tuned at the mesoscale,we paint a picture of how these factors at different levels affect the final system performance and then provide a new direction to better understand and design catalytic materials from the viewpoint of mesoscience. | Lishan Peng Zidong Wei | 2020 | Particuology2020，18，1： | 2 |
| 12 | Improved hydrogen oxidation reaction under alkaline conditions by Au–Pt alloy nanoparticles显示文摘This work demonstrates the outstanding performance of alloyed Au1 Pt1 nanoparticles on hydrogen oxidation reaction(HOR)in alkaline solution.Due to the weakened hydrogen binding energy caused by uniform incorporation of Au,the alloyed Au1Pt1/C nanoparticles exhibit superior HOR activity than commercial PtRu/C.On the contrary,the catalytic performance of the phase-segregated Au2Pt1/C and Au1Pt1/C bimetallic nanoparticles in HOR is significantly worse.Moreover,Au1Pt1/C shows a remarkable durability with activity dropping only 4% after 3000 CV cycles,while performance attenuation of commercial PtRu/C is high up to 15% under the same condition.Our results indicate that the alloyed Au1Pt1/C is a promising candidate to substitute commercial PtRu/C for hydrogen oxidation reaction in alkaline electrolyte. | Lijuan Lu Lishan Peng Li Li Jing Li Xun Huang Zidong Wei | 2020 | Journal of Energy Chemistry2020，29，1： | 2 |
| 13 | Anion Exchange Membrane Based on Interpenetrating Polymer Network with Ultrahigh Ion Conductivity and Excellent Stability for Alkaline Fuel Cell显示文摘A high-performance anion exchange membrane(AEM)is critical for the development of alkaline fuel cell.In this work,AEMs with an interpenetrating polymer network(IPN)are synthesized.An electron microscope clearly reveals a highly efficient“ion channel”network,which is constructed with a small amount of cation exchange groups.This specially designed ion channel leads to extraordinary hydroxide conductivity(e.g.,257.8 mS cm^(-1) at 80℃)of IPN AEMs at moderate ion exchange capacity(IEC=1:75 mmol g^(-1)),as well as excellent long-term alkaline stability at harsh condition which showed that 81%of original conductivity can be retained after a long time for 1248 hours.Moreover,a remarkable peak power density of 1.20 Wcm^(-2)(0.1 MPa backpressure)with nonprecious metal(FeNx-CNTs)as oxygen reduction reaction(ORR)catalyst in a fuel cell test was achieved.This work offers a general strategy to prepare high-performance AEMs based on IPN structure design. | Lingping Zeng Qian He Yunchuan Liao Shangyi Kuang Jianchuan Wang Wei Ding Qiang Liao Zidong Wei | 2020 | Research2020，，1： | 2 |
| 14 | Catalyst Engineering for Electrochemical Energy Conversion from Water to Water:Water Electrolysis and the Hydrogen Fuel Cell显示文摘In the context of the current serious problems related to energy demand and climate change,substantial progress has been made in developing a sustainable energy system.Electrochemical hydrogen-water conversion is an ideal energy system that can produce fuels via sustainable,fossil-free pathways.However,the energy conversion efficiency of two functioning technologies in this energy system—namely,water electrolysis and the fuel cell—still has great scope for improvement.This review analyzes the energy dissipation of water electrolysis and the fuel cell in the hydrogen-water energy system and discusses the key barriers in the hydrogen-and oxygen-involving reactions that occur on the catalyst surface.By means of the scaling relations between reactive intermediates and their apparent catalytic performance,this article summarizes the frameworks of the catalytic activity trends,providing insights into the design of highly active electrocatalysts for the involved reactions.A series of structural engineering methodologies(including nano architecture,facet engineering,polymorph engineering,amorphization,defect engineering,element doping,interface engineering,and alloying)and their applications based on catalytic performance are then introduced,w让h an emphasis on the rational guidance from previous theoretical and experimental studies.The key scientific problems in the electrochemical hydrogen-water conversion system are outlined,and future directions are proposed for developing advanced catalysts for technologies with high energy-conversion efficiency. | Lishan Peng Zidong Wei | 2020 | Engineering2020，6，6： | 2 |
| 15 | Ro- bust filter with stochastic nonlinearities and multi- ple missing measurements显示文摘 | Wei Guoliang Wang Zidong Shu Huisheng | 2009 | Automatica2009，45，3： | 1 |
| 16 | High activityPtPd - WC/C electrocatalyst for hydrogen evolution reac- tion显示文摘 | Wu Mei Shen Peikang Wei Zidong | 2007 | Journal of Power Sources2007，166，2： | 1 |
| 17 | Electrocatalytic oxygen evolution activities of metal chalcogenides and phosphides:Fundamentals,origins,and future strategies显示文摘The development of inexpensive and efficient electrocatalysts is key to commercializing energy-related electrocatalytic techniques such as water electrolyzers and metal-air batteries.In particular,novel oxygen evolution reaction(OER)pre-catalysts,such as transition metal chalcogenides(TMCs)and phosphides(TMPs),have evolved in recent years from traditional stable OER electrocatalysts,which show superior OER electrocatalytic performance compared with transition metal oxides(TMOs)or(oxy)hydroxides(TMOHs).In this feature article,we summarize recent advances in the development of TMCand TMP-based OER electrocatalysts,as well as approaches to improve the OER performance in terms of morphology,structure,composition,surface engineering,lattice-strained and in-situ transformation in the electrolysis process.In particular,the electrochemical stability of TMCs and TMPs in alkaline electrolytes and the evolution of morphology,structure and composition under OER conditions are discussed.In the last section,we discuss the challenges that need to be addressed in this specific area of research and the implications for further research. | Xiaolin Hu Ronghua Wang Wenlin Feng Chaohe Xu Zidong Wei | 2023 | Journal of Energy Chemistry2023，，6： | 1 |
| 18 | Carbon-based air electrodes carrying MnO2 in zinc- air batteries 显示文摘 | WEI Zidong HUANG Wenzhang ZHANG Tao | 2000 | Journal of Power Sources2000，91，2： | 1 |
| 19 | Nanostructured polyaniline-decorated Pt/C @ PANI coreshell catalyst with enhanced durability and activity显示文摘 | Chen Siguo Wei Zidong Qi Xueqiang et a1 | 2012 | J Am Chern Soc2012，134，13： | 1 |
| 20 | High-loading Pt-alloy catalysts for boosted oxygen reduction reaction performance显示文摘To improve performance of membrane electrode assembly(MEA)at large current density region,efficient mass transfer at the cathode is desired,for which a feasible strategy is to lower catalyst layer thickness by constructing high loading Pt-alloy catalysts on carbon.But the high loading may induce unwanted par-ticle aggregation.In this work,H-PtNi/C with 33%(mass)Pt loading on carbon and monodisperse distri-bution of 3.55 nm PtNi nanoparticles,was prepared by a bimodal-pore route.In electrocatalytic oxygen reduction reaction(ORR),H-PtNi/C displays an activity inferior to the low Pt loading catalyst L-PtNi/C(13.3%(mass))in the half-cell.While in H_(2)-0_(2) MEA,H-PtNi/C delivers the peak power density of 1.51 W·cm^(-2) and the mass transfer limiting current density of 4.4 A·cm^(-2),being 21%and 16%higher than those of L-PtNi/C(1.25 W·cm^(-2),3.8 A·cm^(-2))respectively,which can be ascribed to enhanced mass trans-fer brought by the thinner catalyst layer in the former.In addition,the same method can be used to pre-pare PtFe alloy catalyst with a high-Pt loading of 36%(mass).This work may lead to a range of catalyst materials for the large current density applications,such as fuel cell vehicles. | Wei Hong Xinran Shen Jian Wang Xin Feng Wenjing Zhang Jing Li Zidong Wei | 2022 | Chinese Journal of Chemical Engineering2022，35，8： | 1 |
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