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    题名 作者 年代 出处 被引量
1Defect Formation Mechanisms in Selective Laser Melting:A Review显示文摘Defect formation is a common problem in selective laser melting(SLM). This paper provides a review of defect formation mechanisms in SLM. It summarizes the recent research outcomes on defect findings and classification, analyzes formation mechanisms of the common defects, such as porosities, incomplete fusion holes, and cracks. The paper discusses the effect of the process parameters on defect formation and the impact of defect formation on the mechanical properties of a fabricated part. Based on the discussion, the paper proposes strategies for defect suppression and control in SLM.Bi Zhang Yongtao Li Qian Bai 2017Chinese Journal of Mechanical Engineering2017,30,3:50
2OsRFPH2-10, a RING-H2 Finger E3 Ubiquitin Ligase, Is Involved in Rice Antiviral Defense in the Early Stages of Rice dwarf virus Infection显示文摘Lifang Liu Lian Jin Xiahe Huang Yongtao Geng Feng Li Qingqing Qin Rui Wang Shaoyi Ji Shanshan Zhao Qi Xie Chunhong Wei Can Xie Biao Ding Yi Li 2014Molecular Plant2014,7,6:11
3Interactively interfacial reaction of iron-reducing bacterium and goethite for reductive dechlorination of chlorinated organic compounds显示文摘The interactively interfacial reactions between the iron-reducing bacterium (Shewanella decolorationis, S12) and iron oxide (α-FeOOH) were investigated to determine reductive dechlorination transformation of chlorinated organic compounds (chloroform and pentachlorophenol). The results showed that the interactive system of S12+ α-FeOOH exhibited relatively high dechlorination rate. By comparison, the S12 biotic system alone had no obvious dechlorination, and the α-FeOOH abiotic system showed low dechlorination rate. The enhanced dechlorination of chloroform and pentachlorophenol in the interactive system of S12+α-FeOOH was derived from the promoted generation of adsorbed Fe(Ⅱ) by S12. A decrease in redox potential of the Fe(Ⅲ)/Fe(Ⅱ) couple in the interactive reaction system was determined by cyclic voltammetry. Our results will give new insight into interactively interfacial reaction between iron-reducing bacterium and iron oxides for degradation of chlorinated organic compounds under anaerobic condition.LI XiaoMin LI YongTao LI FangBai ZHOU ShunGui FENG ChunHua LIU TongXu 2009Chinese Science Bulletin2009,54,16:11
4In-situ fabrication of PtSe2/GaN heterojunction for self-powered deep ultraviolet photodetector with ultrahigh current on/off ratio and detectivity显示文摘The research of ultraviolet photodetectors(UV PDs)have been attracting extensive attention,due to their important applications in many areas.In this study,PtSe2/GaN heterojunction is in-situ fabricated by synthesis of large-area vertically standing two-dimensional(2D)PtSe2 film on n-GaN substrate.The PtSe2/GaN heterojunction device demonstrates excellent photoresponse properties under illumination by deep UV light of 265 nm at zero bias voltage.Further analysis reveals that a high responsivity of 193 mA·W^-1,an ultrahigh specific detectivity of 3.8 × 10^14 Jones,linear dynamic range of 155d B and current on/off ratio of^10^8,as well as fast response speeds of 45/102μs were obtained at zero bias voltage.Moreover,this device response quickly to the pulse laser of 266 nm with a rise time of 172 ns.Such high-performanee PtSe2/GaN heteroj u nction UV PD demonstrated in this work is far superior to previously reported results,suggesting that it has great potential for deep UV detection.Ranran Zhuo Longhui Zeng Huiyu Yuan Di Wu Yuange Wang Zhifeng Shi Tingting Xu Yongtao Tian Xinjian Li Yuen Hong Tsang 2019Nano Research2019,12,1:11
5Watering techniques and zero-valent iron biochar pH effects on As and Cd concentrations in rice rhizosphere soils,tissues and yield显示文摘Zero-valent iron amended biochar(ZVIB)has been proposed as a promising material in immobilizing heavy metals in paddy fields.In this study,the impacts of p H of ZVIB(p H 6.3 and p H 9.7)and watering management techniques(watering amount in the order of CON(control,5/72)>3/72>1-3/72>3/100>1/72,with 5/72,for example,representing irrigation given to 5 cm above soil surface in 72 hr regular interval)on As and Cd bioavailability for rice and its grain yield(Yield BR)were investigated in a pot experiment.Brown rice As(As BR)content was irrelative to the watering treatments,while significantly decreased(>50%)with the addition of both ZVIB materials.The diminutions of brown rice Cd(Cd BR)content as well as the Yield BR were highly dependent on both the soil amendment materials’p H and watering amount.Among all the watering treatments,3/72 treatment(15%less irrigation water than the CON)with ZVIB 6.3 amendment was the optimum fit for simultaneous reduction of As BR(50%)and Cd BR contents(19%)as well as for significant increment(12%)of the Yield BR.Although high pH(9.7)ZVIB application could also efficiently decrease As and Cd contents in brown rice,it might risk grain yield lost if appropriate(e.g.3/72 in our study)watering management technique was not chosen.Therefore,ZVIB would be an environmentally friendly option as an amendment material with proper selection of watering management technique to utilize As and Cd co-contaminated arable soils safely for paddy cultivation.Md Shafiqul Islam Yali Chen Liping Weng Jie Ma Zulqarnain Haider Khan Zhongbin Liao Abdoul Salam Issiaka Abdoul Magid Yongtao Li 2021Journal of Environmental Sciences2021,33,2:9
6Genome-wide association study of vitamin E in sweet corn kernels显示文摘Vitamin E,consisting of tocopherols and tocotrienols,serves as a lipid-soluble antioxidant in sweet corn kernels,providing nutrients to both plants and humans.Though the key genes involved in the vitamin E biosynthesis pathway have been identified in plants,the genetic architecture of vitamin E content in sweet corn kernels remains largely unclear.In the present study,an association panel of 204 inbred lines of sweet corn was constructed.Seven compounds of vitamin E were quantified in sweet corn kernels at 28 days after pollination.A total of 119 loci for vitamin E were identified using a genome-wide association study based on genotyping by sequencing,and a genetic network of vitamin E was constructed.Candidate genes identified were involved mainly in RNA regulation and protein metabolism.The known gene ZmVTE4,encodingγ-tocopherol methyltransferase,was significantly associated with four traits(α-tocopherol,α-tocotrienol,theα/γ-tocopherol ratio,and theα/γ-tocotrienol ratio).The effects of two causative markers on ZmVTE4 were validated by haplotype analysis.Finally,two elite cultivars(Yuetian 9 and Yuetian 22)with a 4.5-fold increase in the sum ofα-andγ-tocopherols were developed by marker-assisted selection,demonstrating the successful biofortification of sweet corn.Three genes(DAHPS,ADT2,and cmu2)involved in chorismate and tyrosine synthesis were significantly associated with theα/γ-tocotrienol ratio.These results shed light on the genetic architecture of vitamin E and may accelerate the nutritional improvement of sweet corn.Yingni Xiao Yongtao Yu Gaoke Li Lihua Xie Xinbo Guo Jiansheng Li Yuliang Li Jianguang Hu 2020The Crop Journal2020,8,2:7
7Use of SAR interferometry for monitoring illegal mining activities: A case study at Xishimen Iron Ore Mine显示文摘The development and application of the ''digital mine'' concept in China depends heavily upon the use of remote sensing data as well as domestic expertise and awareness. Illegal mining of mineral resources has been a serious long term problem frustrating the Xishimen Iron Ore Mine management. This mine is located in Wu'an county in Hebei province, China. Illegal activities have led to enormous economic losses by interfering with the normal operation of the Xishimen mine and have ruined the surrounding environ- ment and the stability of the Mahe riverbed the crosses the mined area. This paper is based on field recon- naissance taken over many years around the mine area. The ground survey data are integrated with Differential Synthetic Aperture Radar Interferometry (D-InSAR) results from ALOS/PALSAR data to pin- point mining locations. By investigating the relationship between the resulting interferometric deforma- tion pattern and the mining schedule, which is known a priori, areas affected by illegal mining activities are identified. To some extent these areas indicate the location of the illegal site. The results clearly dem- onstrate D-InSAR's ability to cost-effectively monitor illegal mining activities.Ji Maowei Li Xiaojing Wu Shunchuan Gao Yongtao Ge Linlin 2011Mining Science and Technology2011,21,6:7
8An antiretroviral regimen containing 6 months of stavudine followed by long-term zidovudine for first-fine HIV therapy is optimal in resource-limited settings: a prospective, multicenter study in China显示文摘Li Taisheng Guo Fuping Li Yijia Zhang Chengda Han Yang Lye Wei He Yun Lu Hongzhou Xie Jing Huang Aiqiong Li Yanling Tang Xiaoping Wang Hui Zhang Tong Gao Guiju Lei Junkang Zhang Xiaoying Wu Xinhua Sun Yongtao Bai Jinsong Luo Ling Wang Huanlmg 2014Chinese Medical Journal2014,,1:6
9Macroscale and microscale analysis of Anammox in anaerobic rotating biological contactor显示文摘Inoculated with conventional anaerobic activated sludge,the Anammox process was successfully developed in an anaerobic rotating biological contactor (AnRBC) fed with a low ratio of C/N synthetic wastewater.Operated in a single point feed mode,the AnRBC removed 92.1% (n=126) of the influent N at the highest surface load of 12 g/(m2·day).The biomass increased by 25% and 17.1 g/(m2·day) of maximum N removal surface load was achieved by elevating flow rate with another feed point.Fluorescence in situ hybridization and polymerase chain reaction analysis indicated that the Anammox genus Candidatus Kuenenia stuttgartiensis dominated the community.Both Anammox and denitrifying activity were detected in biofilm by the application of microelectrodes.In the outer layer of the biofilm (0-2500 μm),nitrite and ammonium consumed simultaneously in a ratio of 1.12/1,revealing the occurrence of Anammox.In the inner layer (> 2500 μm),a decrease of nitrate was caused by denitrification in the absence of nitrite and ammonium.Yongtao Lv Lei Wang Xudong Wang Yongzhe Yang Zhiying Wang Jie Li 2011Journal of Environmental Sciences2011,23,10:6
10Numerical study of soil-rock mixture:Generation of random aggregate structure显示文摘The soil-rock mixture(SRM) is highly heterogeneous. Before carrying out numerical analysis,a structure model should be generated. A reliable way to obtain such structure is by generating random aggregate structure based on random sequential addition(RSA). The classical RSA is neither efficient nor robust since valid positions to place new inclusions are formulated by trial, which involves repetitive overlapping tests. In this paper, the algorithm of Entrance block between block A and B(EAB)is synergized with background mesh to redesign RSA so that permissible positions to place new inclusions can be predicted,resulting in dramatic improvement in efficiency and robustness.CHEN Li YANG YongTao ZHENG Hong 2018Science China(Technological Sciences)2018,61,3:6
11A New Method of Wind Turbine Bearing Fault Diagnosis Based on Multi-Masking Empirical Mode Decomposition and Fuzzy C-Means Clustering显示文摘Based on Multi-Masking Empirical Mode Decomposition (MMEMD) and fuzzy c-means (FCM) clustering, a new method of wind turbine bearing fault diagnosis FCM-MMEMD is proposed, which can determine the fault accurately and timely. First, FCM clustering is employed to classify the data into different clusters, which helps to estimate whether there is a fault and how many fault types there are. If fault signals exist, the fault vibration signals are then demodulated and decomposed into different frequency bands by MMEMD in order to be analyzed further. In order to overcome the mode mixing defect of empirical mode decomposition (EMD), a novel method called MMEMD is proposed. It is an improvement to masking empirical mode decomposition (MEMD). By adding multi-masking signals to the signals to be decomposed in different levels, it can restrain low-frequency components from mixing in highfrequency components effectively in the sifting process and then suppress the mode mixing. It has the advantages of easy implementation and strong ability of suppressing modal mixing. The fault type is determined by Hilbert envelope finally. The results of simulation signal decomposition showed the high performance of MMEMD. Experiments of bearing fault diagnosis in wind turbine bearing fault diagnosis proved the validity and high accuracy of the new method.Yongtao Hu Shuqing Zhang Anqi Jiang Liguo Zhang Wanlu Jiang Junfeng Li 2019Chinese Journal of Mechanical Engineering2019,32,3:6
12Emplacement Mechanism of the Akebasitao Pluton:Implications for Regional Tectonic Evolution of West Junggar,NW China显示文摘Late Carboniferous to Early Permian A-type granites are extensively distributed throughout the West Junggar region,NW China,and the Akebasitao pluton is extremely distinguished among these plutons.In this paper,we reported new anisotropy of magnetic susceptible(AMS) data combine with detailed field study and audio magnetotelluric(AMT) sounding to assess the three-dimensional shape and magmatic emplacement mechanism of the Akebasitao pluton.The geological features and the AMT sounding indicate that the pluton had a slightly oblique movement of magma from northwest to southeast,which was most likely to correspond to an asymmetrical torch with a laccolith-shaped upper part,and a lower part formed by sub-vertical 'root' that was located within its northwestern part,probably controlled by the NE-trending Anqi fault.The AMS fabrics of aU the specimens reveal a low P_j value(mean of 1.02) and a low T value(mean of-0.024),suggesting that the deformation of the AMS ellipsoid is relatively weak.The specimens exhibit both oblate and prolate shapes of the AMS ellipsoid.Magnetic lineations and foliations are randomly distributed throughout the pluton without any preferred orientation.These AMS patterns indicate that the pluton formed in a relatively stable structural environment with no regional extrusion.Therefore,we propose a complex emplacement process in which the magmas reached the shallower crust levels via deep-faults and subsequently occupied the room created by doming,accompanied by sloping near the pluton roof.Additionally,the regional tectonic setting was relatively stable during the emplacement of the Akebasitao pluton,indicating the termination of compressional orogeny during the late Late Carboniferous in the West Junggar region.This conclusion perfectly coincides with the regional tectonic paleogeography,magmatic system,and paleostress field.ZHANG Pan WANG Guocan LI Yongtao ZHANG Shengye PENG Chao ZHAO Hongwei ZHA Yanhong 2017Acta Geologica Sinica(English Edition)2017,91,3:5
13Effect of water-driven changes in rice rhizosphere on Cd lability in three soils with different pH显示文摘Pot experiments were conducted to evaluate the effect of water management,namely continuous flooding(CF),intermittent flooding(IF)and non-flooding(NF),on Cd phytoavailaility in three paddy soils that differed in p H and in Cd concentrations.Diffusive gradients in thin films(DGT)technique was employed to monitor soil labile Cd and Fe concentrations simultaneously at three growth stages(tillering,heading and mature stage)of rice.The Cd phytoavailability were generally in the order of NF>IF>CF,and higher rice Cd(over permitted level,0.2 mg/kg)were only found in neutral and acidic soils under NF conditions.DGT measured soil labile Cd rather than total Cd was the most reliable predictor for Cd accumulation in rice.CF enhanced the formation of root plaques,which related to oxidation of large quantities of available Fe on root surfaces due to the O2 secretion of rice root.The Cd concentration in root plaques shared the same trend with DGT-Cd.Generally,root plaques would inhibit Cd uptake by rice under CF conditions,while under IF and NF conditions,root plaques act as a temporarily store of Cd,and soil labile Cd is the key factor that controls the transfer of Cd from soil to rice.The results of principle component analysis revealed that water management had the greatest effect on soil Cd lability and rice Cd in acidic soil.Thus,it is important to consider the availability of Cd and soil p H when assessing current agricultural practices of contaminated soil in China.Jinjin Wang Dongqin Li Qin Lu Yulong Zhang Huijuan Xu Xueli Wang Yongtao Li 2020Journal of Environmental Sciences2020,32,1:5
14PARAMETERS DETERMINATION METHOD OF PHASE-SPACE RECONSTRUCTION BASED ON DIFFERENTIAL ENTROPY RATIO AND RBF NEURAL NETWORK显示文摘Phase space reconstruction is the first step of recognizing the chaotic time series.On the basis of differential entropy ratio method,the embedding dimension opt m and time delay t are optimal for the state space reconstruction could be determined.But they are not the optimal parameters accepted for prediction.This study proposes an improved method based on the differential entropy ratio and Radial Basis Function(RBF)neural network to estimate the embedding dimension m and the time delay t,which have both optimal characteristics of the state space reconstruction and the prediction.Simulating experiments of Lorenz system and Doffing system show that the original phase space could be reconstructed from the time series effectively,and both the prediction accuracy and prediction length are improved greatly.Zhang Shuqing Hu Yongtao Bao Hongyan Li Xinxin 2014Journal of Electronics(China)2014,31,1:4
15Highly sensitive solar-blind deep ultraviolet photodetector based on graphene/PtSe_(2)/β-Ga_(2)O_(3)2D/3D Schottky junction with ultrafast speed显示文摘There is an emerging need for high-sensitivity solar-blind deep ultraviolet(DUV)photodetectors with an ultra-fast response speed.Although nanoscale devices based on Ga_(2)O_(3)nanostructures have been developed,their practical applications are greatly limited by their slow response speed as well as low specific detectivity.Here,the successful fabrication of two-/three-dimensional(2D/3D)graphene(Gr)/PtSe2/β-Ga_(2)O_(3)Schottky junction devices for high-sensitivity solar-blind DUV photodetectors is demonstrated.Benefitting from the high-quality 2D/3D Schottky junction,the vertically stacked structure,and the superior-quality transparent graphene electrode for effective carrier collection,the photodetector is highly sensitive to DUV light illumination and achieves a high responsivity of 76.2 mA/W,a large on/off current ratio of~105,along with an ultra-high ultraviolet(UV)/visible rejection ratio of 1.8×104.More importantly,it has an ultra-fast response time of 12µs and a remarkable specific detectivity of~1013 Jones.Finally,an excellent DUV imaging capability has been identified based on the Gr/PtSe2/β-Ga_(2)O_(3)Schottky junction photodetector,demonstrating its great potential application in DUV imaging systems.Di Wu Zhihui Zhao Wei Lu Lukas Rogée Longhui Zeng Pei Lin Zhifeng Shi Yongtao Tian Xinjian Li Yuen Hong Tsang 2021Nano Research2021,14,6:4
16Synthesis, insecticidal activities and SAR studies of novel anthranilic diamides containing trifluoroethoxyl substituent and chiral amino acid moieties显示文摘Ryanodine receptors(RyRs) activator has become one class of popular insecticide because of its unique mode of action. In order to find more new RyRs activators as insecticidal agents, a series of 18 novel chiral anthranilic diamides were designed by introducing the D-alanine acid and D-serine acid esters as well as trifluoroethoxyl group into the anthranilic diamide skeleton and synthesized successfully based on anthranilic diamide and FKI-1033 structures. The structures of the title compounds Ia–i and IIa–i were confirmed by melting points,~1H NMR,^(13)C NMR, elemental analysis and specific optical rotation analysis.The preliminary bioassay results indicated that most of the title compounds exhibited considerable larvicidal activities against oriental armyworm at 10 mg/L, especially Ib, Ie and IIh showed remarkable insecticidal activities at 0.5 mg/L. The larvicidal activity against diamondback moth of Ia and IId were 80%and 90% respectively at 0.0001 mg/L, which was similar to that of chlorantraniliprole. The relationship between structure and insecticidal activity was analyzed to reveal a possible co-regulated effect of the chiral amino acid ester, halogen atom or cyano group, and trifluoroethyloxyl group of the skeleton structures of the title compounds, which will provide useful information for guiding the design and discovery of new RyRs activators and insecticidal agrochemicals.Shaa Zhou Sha Zhou Yongtao Xie Xiangde Meng Baolei Wang Lixia Xiong Na Yang Zhengming Li 2018Chinese Chemical Letters2018,29,8:3
17A bone-targeted engineered exosome platform delivering siRNA to treat osteoporosis显示文摘The complex pathogenesis of osteoporosis includes excessive bone resorption,insufficient bone formation and inadequate vascularization,a combination which is difficult to completely address with conventional therapies.Engineered exosomes carrying curative molecules show promise as alternative osteoporosis therapies,but depend on specifically-functionalized vesicles and appropriate engineering strategies.Here,we developed an exosome delivery system based on exosomes secreted by mesenchymal stem cells(MSCs)derived from human induced pluripotent stem cells(iPSCs).The engineered exosomes BT-Exo-siShn3,took advantage of the intrinsic anti-osteoporosis function of these special MSC-derived exosomes and collaborated with the loaded siRNA of the Shn3 gene to enhance the therapeutic effects.Modification of a bone-targeting peptide endowed the BT-Exo-siShn3 an ability to deliver siRNA to osteoblasts specifically.Silencing of the osteoblastic Shn3 gene enhanced osteogenic differentiation,decreased autologous RANKL expression and thereby inhibited osteoclast formation.Furthermore,Shn3 gene silencing increased production of SLIT3 and consequently facilitated vascularization,especially formation of type H vessels.Our study demonstrated that BT-Exo-siShn3 could serve as a promising therapy to kill three birds with one stone and implement comprehensive anti-osteoporosis effects.Yongzhi Cui Yuanyuan Guo Li Kong Jingyu Shi Ping Liu Rui Li Yongtao Geng Weihang Gao Zhiping Zhang Dehao Fu 2022Bioactive Materials2022,7,4:3
18Prognostic and incremental value of computed tomography-based radiomics from tumor and nodal regions in esophageal squamous cell carcinoma显示文摘Objective:This study aimed to evaluate the prognostic value of preoperative radiomics and establish an integrated model for esophageal squamous cell cancer(ESCC).Methods:A total of 931 patients were retrospectively enrolled in this study(training cohort,n=624;validation cohort,n=307).Radiomics features were obtained by contrast-enhanced computed tomography(CT)before esophagectomy.A radiomics index was set based on features of tumor and reginal lymph nodes by using the least absolute shrinkage and selection operator(LASSO)Cox regression.Prognostic nomogram was built based on radiomics index and other independent risk factors.The prognostic value was assessed by using Harrell’s concordance index,time-dependent receiver operating characteristics and Kaplan-Meier curves.Results:Twelve radiomic features from tumor and lymph node regions were identified to build a radiomics index,which was significantly associated with overall survival(OS)in both training cohort and validation cohort.The radiomics index was highly correlated with clinical tumor-node-metastasis(cTNM)and pathologic TNM(pTNM)stages,but it demonstrated a better prognostic value compared with cTNM stage and was almost comparable with pTNM stage.Multivariable Cox regression showed that the radiomics index was an independent prognostic factor.An integrated model was constructed based on gender,preoperative serum sodium concentration,pTNM and the radiomics index for clinical usefulness.The integrated model demonstrated discriminatory ability better compared with the traditional clinical-pathologic model and pTNM alone,indicating incremental value for prognosis.Conclusions:CT-based radiomics for primary tumor and reginal lymph nodes was sufficient in predicting OS for patients with ESCC.The integrated model demonstrated incremental value for prognosis and was robust for clinical applications.Bangrong Cao Kun Mi Wei Dai Tong Liu Tianpeng Xie Qiang Li Jinyi Lang Yongtao Han Lin Peng Qifeng Wang 2022Chinese Journal of Cancer Research2022,34,2:3
19Poly(amide-6-b-ethylene oxide)/[Bmim][Tf2N] blend membranes for carbon dioxide separation显示文摘Poly(amide-6-b-ethylene oxide)(Pebax1657)/1-butyl-3-methylimidazo-lium bis[trifluoromethyl)sulfonyl]-imide([Bmim][Tf_2N]) blend membranes with different [Bmim][Tf_2N] contents were prepared via solution casting and solvent evaporation method. The permeation properties of the blend membranes for CO_2, N_2,CH_4 and H_2 were studied, and the physical properties were characterized by differential scanning calorimeter(DSC) and X-ray diffraction(XRD). Results showed that [Bmim][Tf_2N] was dispersed as amorphous phase in the blend membranes, which caused the decrease of Tg(PE) and crystallinity(PA). With the addition of [Bmim][Tf_2N], the CO_2 permeability increased and reached up to approximately 286 Barrer at 40 wt%[Bmim][Tf_2N], which was nearly double that of pristine Pebax1657 membrane. The increase of CO_2 permeability may be attributed to high intrinsic permeability of [Bmim][Tf_2N], the increase of fractional free of volume(FFV) and plasticization effect. However, the CO_2 permeability reduced firstly when the [Bmim][Tf_2N]content was below 10 wt%, which may be due to that the small ions of [Bmim][Tf_2N] in the gap of polymer chain inhibited the flexibility of polymer chain; the interaction between Pebax1657 and [Bmim][Tf_2N]decreased the content of EO units available for CO_2 transport and led to a more compact structure. For Pebax1657/[Bmim][Tf_2N] blend membranes, the permeabilities of N_2, H2 and CH4decreased with the increase of feed pressure due to the hydrostatic pressure effect, while CO_2 permeability increased with the increase of feed pressure for that the CO_2-induced plasticization effect was stronger than hydrostatic pressure effect.Yongtao Qiu Jizhong Ren Dan Zhao Hui Li Maicun Deng 2016Journal of Energy Chemistry2016,25,1:3
20Design, Synthesis and Insecticidal Evaluation of Anthranilic Diamides Containing Optically Pure Amino Acid Moiety显示文摘N-pyridylpyrazolecarboxamide 衍生物的二个系列被介绍 D 丙氨酸酸酉旨和 D 丝氨酸酸酉旨进 chlorantraniliprole 的骨骼设计并且综合。获得的结构被 1 H NMR, 13 C NMR,元素的分析和特定的光旋转分析。初步的生物鉴定显示一些混合物与 chlorantraniliprole 比较对分开的 Mythimna 和 Plutella xylostella 显示了优秀杀虫的活动。特别地, IIq 在 0.01 mg·L −1 与 90% 的死亡率对 Plutella xylostella 显示出优秀杀虫的活动。A 3D-QSAR (CoMSIA ) 学习被执行以便揭示杀虫的结构活动关系并且显示未来工作。CoMSIA 学习证明在 pyrazole 的 3 位置的缺乏的组打电话找的大候补选手和电子是有利的,与氨基酸的酉旨组附近的一个小组一样。Shaa Zhou Sha Zhou Xuewen Hua Wei Wei Yongtao Xie Minggui Chen Xiangde Meng Ming Liu Lixia Xiong Na Yang Baolei Wang Zhengming Li 2016Chinese Journal of Chemistry2016,34,12:2
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