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| 1 | Ni/Al_2O_3 catalysts for CO methanation: Effect of Al_2O_3 supports calcined at different temperatures显示文摘The correlation between phase structures and surface acidity of Al2O3 supports calcined at different temperatures and the catalytic performance of Ni/Al2O3 catalysts in the production of synthetic natural gas(SNG) via CO methanation was systematically investigated. A series of 10 wt% NiO/Al2O3 catalysts were prepared by the conventional impregnation method, and the phase structures and surface acidity of Al2O3 supports were adjusted by calcining the commercial γ-Al2O3 at different temperatures(600–1200 C). CO methanation reaction was carried out in the temperature range of 300–600 C at different weight hourly space velocities(WHSV = 30000 and 120000 mL·g-1h-1) and pressures(0.1 and 3.0 MPa). It was found that high calcination temperature not only led to the growth in Ni particle size, but also weakened the interaction between Ni nanoparticles and Al2O3 supports due to the rapid decrease of the specific surface area and acidity of Al2O3 supports. Interestingly, Ni catalysts supported on Al2O3 calcined at 1200 C(Ni/Al2O3-1200) exhibited the best catalytic activity for CO methanation under different reaction conditions. Lifetime reaction tests also indicated that Ni/Al2O3-1200 was the most active and stable catalyst compared with the other three catalysts, whose supports were calcined at lower temperatures(600, 800 and 1000 C). These findings would therefore be helpful to develop Ni/Al2O3 methanation catalyst for SNG production. | Jiajian Gao Chunmiao Jia Jing Li Meiju Zhang Fangna Gu Guangwen Xu Ziyi Zhong Fabing Su | 2013 | Journal of Energy Chemistry2013，22，6： | 16 |
| 2 | Piglets cloned from induced pluripotent stem cells显示文摘 | Nana Fan Jijun Chen Zhouchun Shang Hongwei Dou Guangzhen Ji Qingjian Zou Lu Wu Lixiazi He Fang Wang Kai Liu Na Liu Jianyong Han Qi Zhou Dengke Pan Dongshan Yang Bentian Zhao Zhen Ouyang Zhaoming Liu Yu Zhao Lin Lin Chongming Zhong Quanlei Wang Shouqi Wang Ying Xu Jing Luan Yu Liang Zhenzhen Yang Jing Li Chunxia Lu Gabor Vajta Ziyi Li Hongsheng Ouyang Huayan Wang Yong Wang Yang Yang Zhonghua Liu Hong Wei Zhidong Luan Miguel A Esteban Hongkui Deng Huanming Yang Duanqing Pei Ning Li Gang Pei Lin Liu Yutao Du Lei Xiao Liangxue Lai | 2013 | Cell Research2013，23，1： | 12 |
| 3 | Controllable Synthesis of Co304 from Nanosize to Microsize with Large-Scale Exposure of Active Crystal Planes and Their Excellent Rate Capability in Supercapacitors Based on the Crystal Plane Effect显示文摘 | Yu Wang Ziyi Zhong Yang Chen Cheng Theng Ng Jianyi Lin | 2011 | Nano Research2011，4，7： | 8 |
| 4 | 各向异性金纳米粒子的制备及其在催化中的应用(英文)显示文摘尽管有关金纳米粒子催化的研究工作很多,但其中大多数都是采用传统的浸渍法将金盐负载到载体上、共沉淀或沉积-沉淀法制得负载的纳米粒子,但这些方法并未吸收最新的纳米技术.最近,金催化剂的研究者开发了在胶态悬浮液中制取金属纳米粒子,然后进行固载,从而使得单金属和双金属催化剂的催化活性和形貌控制取得较大进展.另一方面,最近十年出现了金纳米粒子合成的高级控制技术,得到了许多各向异性的金纳米粒子,且很容易制得新的形貌,可以控制纳米粒子的表面原子配位数和光学特性(可调的等离子体带),这些都与催化密切相关.这些形貌包括纳米棒、纳米星、纳米花、树枝状纳米结构或多面体纳米粒子等.除了高度关注各向异性金纳米粒子的最新开发的制备方法和性质,本综述也清楚地总结了这些纳米粒子独特的催化性能,以及通过提供更高催化性能的金催化剂、控制暴露的活性位,以及热、电和光催化的鲁棒性和可调性,从而给多相催化领域带来令人惊奇的潜在变革. | Peter Priecel Hammed Adekunle Salami Romen Herrera Padilla Ziyi Zhong Jose Antonio Lopez-Sanchez | 2016 | Chinese Journal of Catalysis2016，37，10： | 5 |
| 5 | Rambutan-like hierarchically heterostructured CeO2-CuO hollow microspheres: Facile hydrothermal synthesis and applications显示文摘层次地空范围具有为由于他们的唯一的结构的特征和性质的大量应用的大兴趣的 heterostructured。然而,有为大规模上的混合转变金属氧化物的高度特定的形态学的明确的空范围的制造仍然保持挑战性。在这个工作,一致像红毛丹的 heterostructured CeO 2-CuO 有积木经由一个灵巧的热水的方法被准备的界面的地点和 nanorods 和 nanoparticles 由锻烧跟随了的众多的 copper-ceria 的空 microspheres。重要地,这条途径能乐意地被扩大规模并且对各种各样的基于 CuO 的混合金属氧化物的合成适用复杂空范围。同样准备的 CeO 2-CuO 当主要由于小主要 nanoparticle 成分,为 supercapacitors 并且作为为 Rochow 反应的基于 Cu 的催化剂的电极材料高出现,空红毛丹两个都展出优异性能众多的内部 heterostructures 的区域,和形成。 | Yongjun Ji Zheying Jin Jing Li Yu Zhang Hezhi Liu Laishun Shi Ziyi Zhong Fabing Su | 2017 | Nano Research2017，10，2： | 4 |
| 6 | One-dimensional Cu-based catalysts with layered Cu-Cu20-CuO walls for the Rochow reaction显示文摘 | Jing Li Zailei Zhang Yongjun Ji Zheying Jin Shanying Zou Ziyi Zhong Fabing Su | 2016 | Nano Research2016，9，5： | 4 |
| 7 | Recent progress in perovskite solar cells:material science显示文摘Perovskite solar cells represent a promising third-generation photovoltaic technology with low fabrication cost and high power conversion efficiency.In light of the rapid development of perovskite materials and devices,a systematic survey on the latest advancements covering a broad range of related work is urgently needed.This review summarizes the recent major advances in the research of perovskite solar cells from a material science perspective.The discussed topics include the devices based on different type of perovskites(organic-inorganic hybrid,all-inorganic,and lead-free perovskite and perovskite quantum dots),the properties of perovskite defects,different type of charge transport materials(organic,polymeric,and inorganic hole transport materials and inorganic and organic electron transport materials),counter electrodes,and interfacial materials used to improve the efficiency and stability of devices.Most discussions focus on the key progresses reported within the recent five years.Meanwhile,the major issues limiting the production of perovskite solar cells and the prospects for the future development of related materials are discussed. | Jiang-Yang Shao Dongmei Li Jiangjian Shi Chuang Ma Yousheng Wang Xiaomin Liu Xianyuan Jiang Mengmeng Hao Luozheng Zhang Chang Liu Yiting Jiang Zhenhan Wang Yu-Wu Zhong Shengzhong(Frank)Liu Yaohua Mai Yongsheng Liu Yixin Zhao Zhijun Ning Lianzhou Wang Baomin Xu Lei Meng Zuqiang Bian Ziyi Ge Xiaowei Zhan Jingbi You Yongfang Li Qingbo Meng | 2023 | Science China Chemistry2023，66，1： | 3 |
| 8 | Converting industrial waste contact masses into effective multicomponent copper-based catalysts for the Rochow process显示文摘 | Hezhi Liu Yongjun Ji Yongxia Zhu Guangna Wang Xueguang Wang Ziyi Zhong Fabing Su | 2018 | Particuology2018，16，2： | 2 |
| 9 | Single-atom Sn-Zn pairs in CuO catalyst promote dimethyldichlorosilane synthesis显示文摘Single-atom catalysts are of great interest because they can maximize the atom-utilization efficiency and generate unique catalytic properties;however,much attention has been paid to single-site active components,rarely to catalyst promoters.Promoters can significantly affect the activity and selectivity of a catalyst,even at their low concentrations in catalysts.In this work,we designed and synthesized CuO catalysts with atomically dispersed co-promoters of Sn and Zn.When used as the catalyst in the Rochow reaction for the synthesis of dimethyldichlorosilane,this catalyst exhibited much-enhanced activity,selectivity and stability compared with the conventional CuO catalysts with promoters in the form of nanoparticles.Density functional theory calculations demonstrate that single-atomic Sn substitution in the CuO surface can enrich surface Cu vacancies and promote dispersion of Zn to its atomic levels.Sn and Zn single sites as the co-promoters cooperatively generate electronic interaction with the CuO support,which further facilitates the adsorption of the reactant molecules on the surface,thereby leading to the superior catalytic performance. | Qi Shi Yongjun Ji Wenxin Chen Yongxia Zhu Jing Li Hezhi Liu Zhi Li Shubo Tian Ligen Wang Ziyi Zhong Limin Wang Jianmin Ma Yadong Li Fabing Su | 2020 | National Science Review2020，7，3： | 2 |
| 10 | Morphology-dependent catalytic properties of nano- cupric oxides in the Rochow reaction显示文摘四种 CuO 催化剂与控制得好像叶子(L-CuO ) ,象花(F-CuO ) , sea-urchin-like (U-CuO ) ,并且像燕麦片(O-CuO ) 形态学被各种各样的 chelating ligands 帮助的一个灵巧的降水方法综合。高分辨率的传播电子显微镜学和快 Fourier 转变显示的红外线的光谱学 L-CuO, F-CuO, U-CuO,和 O-CuO 的主导的水晶方面是 { 001 } , { 110 } , { 001 } ,并且 { 110 } ,以及 { 001 } 并且 { 110 } 分别地。当为 Rochow 反应测试了时,他们的催化表演依赖于他们的结构,这被发现。在四 CuO 催化剂之中, L-CuO 展出了最好的催化性质,与为氧和最高的 reducibility 的最强壮的吸附能力一起,它主要因为它的大部分暴露了 { 001 } 方面和大特定的表面区域。另外, Cu 3 Si 合金阶段,是在 Si 表面的反应区域产生了的最重要的反应中介,为不同催化剂被测量。基于调查结果,详细反应机制被建议。这个工作证明氧化物催化剂的那控制形状的合成能是有效策略设计并且发展有效催化剂。 | Yu Zhang Yongjun Ji Jing Li Hezhi Liu Xiao Hu Ziyi Zhong Fabing Su | 2018 | Nano Research2018，11，2： | 2 |
| 11 | Ordered mesoporous Cu-Ca-Zr:A superior catalyst for direct synthesis of methyl formate from syngas显示文摘It is still a big challenge to obtain both highly active and stable Cu-based catalysts for direct synthesis of methyl formate(MF)from syngas.To address the issue,we have designed and synthesized a series of ternary Cu-Ca-Zr catalysts,namely,the ordered mesoporous Cu-Ca-Zr catalyst prepared by one-pot evaporation-induced self-assembly(EISA)method,and the supported CuO/CaO-ZrO_(2)catalysts by impregnating with copper precursor or by immobilizing copper nanoparticles.In the latter two catalysts,the ordered mesoporous CaO-ZrO_(2)support was also prepared by the EISA method.The catalysts were characterized by techniques such as ICP,XRD,TEM,N2 isotherm adsorption-desorption,XPS and H2-TPR,and used for direct synthesis of MF.The results indicated that the catalyst prepared by onepot EISA method,in which the CuO species are highly dispersed in frame of CaO-ZrO_(2),exhibits much better activity and stability as compared with the other two catalysts with most of CuO located on the outer surface of the CaO-ZrO_(2)support,because the former has a higher specific surface area,enhanced synergistic effect and stronger interaction between the CaO-ZrO_(2)support and CuO active constituent. | Jiahao Zhuang Bin Lu Fangna Gu Ziyi Zhong Fabing Su | 2018 | Carbon Resources Conversion2018，1，2： | 2 |
| 12 | Molecular catalysis for the steam reforming of ethanol显示文摘In this paper,the application of molecular catalysis for steam reforming of ethanol(SRE)is reviewed.Eight metals(Ni,Co,Cu,Pt,Rh,Pd,Ir and Ru)have shown high catalytic activity for SRE.Among them Ni and Rh are very promising because of high d character in the metal bond and low metal-oxygen bonding(vs.metal-carbon).They can effectively promote C–C bond cleavage in the rate-determining process during SRE.However,Rh is weak in water-gas-shift so that CH4 and CO become the main by-products at low reaction temperatures,while Ni catalysts suffer from rapid deactivation due to coking and sintering.Two low-temperature CO-free catalysts have been developed in our lab,namely Rh-Fe/Ca-Al2O3 and carbonyl-derived Rh-Co/Ce O2,in which the presence of iron oxide or Co can promote water-gas-shift reaction and significantly improve the SRE performance.On the other hand,adding 3 wt%Ca O to Ni/Al2O3 can greatly improve the catalyst stability because the Ca modification not only increases Ni concentration on the Ni/Ca-Al2O3 surface and 3d valence electron density,but also facilitates the water adsorption and coke gasification via water-gas-shift.The availability of abundant surface OH groups helps the formation and conversion of adsorbed formate intermediate.Hence,ethanol reaction on Ca-Al2O3-supported Ni,Pt,Pd and Rh catalysts are found to follow the formate-intermediated pathway,a new reaction pathway alternative to the traditional acetate-intermediated pathway. | Jianyi Lin Luwei Chen Catherine Kai Shin Choong Ziyi Zhong Lin Huang | 2015 | Science China Chemistry2015，58，1： | 1 |
| 13 | 显示文摘 | Zhong Ziyi Chen Kaidong Ji Yong | 1997 | Applied Catalysis A: General1997，156，： | 1 |
| 14 | Sonochemieally prepared high dispersed Ru/TiOz mesoporous catalyst for partial oxidation of methane to syngas 显示文摘 | Nina Perkas Zhong Ziyi Chen Luwei | 2005 | Catalysis Letters2005，103，12： | 1 |
| 15 | Sonochemically prepared high dispersed Ru/TiO2 mesoporous catalyst for partial oxidation of methane to syngas显示文摘 | Perkas N Zhong Ziyi Chen Luwei | 2005 | Catalysis Letters2005，103，2： | 1 |
| 16 | Nickel catalysts supported on barium hexaaluminate for enhanced CO methanation显示文摘 | Gao Jiajian Jia Chunmiao Li Jing Gu Fangna Xu Guangwen Zhong Ziyi Su Fabing | 2012 | Industrial & Engineering Chemistry Research2012，51，10： | 1 |
| 17 | CO2 Capture by Solid Adsorbents and Their Applications:Current Status and New Trends显示文摘 | Wang Qiang Luo Jizhong Zhong Ziyi | | 0，，4： | 1 |
| 18 | Efficacy and safety of Sancai powder in patients with type 2 diabetes mellitus: a randomized controlled trial显示文摘OBJECTIVE: To assess the efficacy and safety of Sancai powder in patients with type 2 diabetes mellitus(T2DM) inadequately controlled with single oral metformin in a randomized controlled trial(RCT).METHODS: A total of 132 patients with T2 DM were enrolled in the study, who only took metformin(500-1000 mg/day) for at least three months and with inadequate glycemic control(7.0% ≤ hemoglobin A1 c ≤ 9.0%) in the past three months.The patients stopped taking metformin with lifestyle interventions for three weeks, and 105 patients qualified for the program. They were randomly divided into the Sancai powder group and the metformin group(1500 mg/day). The follow-up period was for 12 weeks. Comparisons of several variables were analyzed.RESULTS: No significant differences were found between the two groups in hemoglobin A1c(Hb A1c),fasting plasma glucose(FPG) and 2 h post-meal glucose(2h PG), although they had decreased significantly(P < 0.01). Homeostasis model assessment of beta cell function index was significantly improved in Sancai powder group(P < 0.01), and there were significant differences in the changes of homeostasis model assessment of insulin resistance and insulin sensitivity index in the two groups(P < 0.05). Sancai powder significantly reduced triglyceride level(P < 0.05), although there was no significant difference in the body weight and body mass index in the two groups.CONCLUSION: In this 12-week study, Sancai powder could significantly reduce hemoglobin A1 c,FPG and 2h PG levels, improved beta-cell function and insulin resistance of the T2 DM inadequately controlled with metformin. | Guo Qiang Zhang Hengyao Li Mindian Zhao Ziyi Luo Yunlin Luo Yulei Cao Wenzhai Zhao Huan Zhu Ranran Lei Xingxing Chen Huizhen Gan Huakui Zuo Zhihuang Chen Qi Shi Cuimei Zhang Xinli Guo Jian Zhong Sen Chen Qiu | 2016 | Journal of Traditional Chinese Medicine2016，36，5： | 1 |
| 19 | Preparation of mesoscale hollow spheres of TiO2 and SnO2 by templating against crystalline arrays ofpolystryrene beads显示文摘 | ZHONG Ziyi YIN Yadong GATES Byron | 2000 | Advanced Materials2000，12，： | 1 |
| 20 | Hydrogenolysis of cellulose to C4–C7 alcohols over bi-functional CuO–MO/Al 2 O 3 (M=Ce, Mg, Mn, Ni, Zn) catalysts coupled with methanol reforming reaction显示文摘 | Yanhua Wu Fangna Gu Guangwen Xu Ziyi Zhong Fabing Su | 2013 | Bioresource Technology2013，，： | 1 |
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