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| 1 | Heavy metal concentrations in edible bivalves and gastropods available in major markets of the Pearl River Delta显示文摘Molluscs are able to accumulate heavy metals and impose health hazard to consumers. The main objective of the present study is to investigate the heavy metal concentrations in edible bivalves and gastropods available in major markets of the Pearl River Delta. Fourteen species of edible molluscs were purchased from six markets in Hong Kong and Guangdong Province. The fresh of these biota were tested for their cadmium (Cd), copper (Cu), zinc (Zn), lead (Pb), nickel (Ni), chromium (Cr), antimony (Sb) and tin (Sn) concentrations (based on wet weight). The results indicated that amongst the 14 edible molluscs, only Cd, Pb, Ni, Cr, Sb and Sn concentrations in three species ( Ruditapes philippinarum, Perna viridis and Hemifusus tuba ) were within the local regulatory limits. Over 60% of bivalve species exceeded maximum permitted levels of Cd (2 μg/g) and Cr (1 μg/g), while over 40% of gastropod species exceeded the maximum levels of Sb (1 μg/g) and Cr (1 μg/g). Most of the samples collected from Hong Kong had significantly higher contents of Pb and Sb, but similar levels of Cd, Cu and Zn when compared with samples collected across the border ( p <0 05; p <0 01; p <0 001 respectively). In general, the molluscs purchased in Guangdong markets had higher metal contents than those purchased from the Hong Kong markets. When compared with the Provisional Tolerable Weekly Intake or Maximum Acceptable Daily Load recommended by FAO/WHO Expert Committee on Food Additives, Cd levels of five species ( Anadara ferruginea, Pinna pectinata, Chlamys nobilis, Babylonia lutosa and Hemifusus terntanus ) and Cr levels of seven species ( Anadara ferruginea, Paphia undulata, Pinna pectinata, Babylonia lutosa, Hemifusus terntanus, Cymbium melo and Cipangopaludina chinensis ) were higher than both the human daily acceptable limits (for Cd and Cr respectively) and the local regulatory levels (for Cd and Cr respectively). | FANG Zhan-qiang CHEUNG R.Y.H. WONG M.H. | 2001 | Journal of Environmental Sciences2001，13，2： | 20 |
| 2 | Role of soil rhizobacteria in phytoremediation of heavy metal contaminated soils显示文摘Heavy metal pollution of soil is a significant environmental problem and has its negative impact on human health and agriculture. Rhizosphere, as an important interface of soil and plant, plays a significant role in phytoremediation of contaminated soil by heavy metals, in which, microbial populations are known to affect heavy metal mobility and availability to the plant through release of chelating agents, acidification, phosphate solubilization and redox changes, and therefore, have potential to enhance phytoremediation processes. Phytoremediation strategies with appropriate heavy metal-adapted rhizobacteria have re-ceived more and more attention. This article paper reviews some recent advances in effect and significance of rhizobacteria in phytoremediation of heavy metal contaminated soils. There is also a need to improve our understanding of the mechanisms in-volved in the transfer and mobilization of heavy metals by rhizobacteria and to conduct research on the selection of microbial isolates from rhizosphere of plants growing on heavy metal contaminated soils for specific restoration programmes. | JING Yan-de1,2, HE Zhen-li1,3, YANG Xiao-e1 (1Ministry of Education Key Lab of Environment, Remediation and Ecosystem Health, School of Natural Resource and Environment Science, Zhejiang University, Hangzhou 310029, China) (2Department of Resources and Planning, Qufu Normal University, Jining 273165, China) (3University of Florida Institute of Food and Agricultural Sciences, Indian River Research and Education Center, Fort Pierce, Florida 34945, USA) | 2007 | Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)2007，8，3： | 18 |
| 3 | Effect of manganese oxide-modified biochar addition on methane production and heavy metal speciation during the anaerobic digestion of sewage sludge显示文摘Low organic matter content and high heavy metal levels severely inhibit the anaerobic digestion(AD) of sewage sludge. In this study, the effect of added manganese oxidemodified biochar composite(MBC) on methane production and heavy metal fractionation during sewage sludge AD was examined. The MBC could increase the buffering capacity,enhance the methane production and degradation of intermediate acids, buffer the pH of the culture, and stabilize the sewage sludge AD process. The application of MBC positively impacted methane production and the cumulative methane yield increased up to 121.97%,as compared with the control. The MBC addition can improve metal stabilization in the digestate. An optimum MBC dose of 2.36 g was recommended, which would produce up to 121.1 L/kg volatile solids of methane. After the AD process, even though most of the metals accumulated in the residual solids, they could be transformation from the bio-available fractions to a more stable fraction. The total organic-and sulfide-bound and residual fraction content at a 3 g dose of MBC that is 0.12 g/g dry matter were 51.06% and 35.11% higher than the control, respectively. The results indicated that the application of MBC could improve the performance of AD and promote stabilization of heavy metals in sewage sludge post the AD process. | Jianhua Li Min Zhang Zhiyin Ye Changming Yang | 2019 | Journal of Environmental Sciences2019，31，2： | 17 |
| 4 | Amino-functionalized core-shell magnetic mesoporous composite microspheres for Pb(Ⅱ) and Cd(Ⅱ) removal显示文摘Amino-functionalized Fe3O4 @mesoporous SiO2 core-shell composite microspheres NH2-MS in created in multiple synthesis steps have been investigated for Pb(Ⅱ) and Cd(Ⅱ) adsorption.The microspheres were characterized by transmission electron microscope(TEM),scanning electron microscope(SEM),N2 adsorption-desorption,zeta potential measurements and vibrating sample magnetometer.Batch adsorption tests indicated that NH2-MS exhibited higher adsorption affinity toward Pb(Ⅱ) and Cd(Ⅱ) than MS did.The Langmuir model could fit the adsorption isotherm very well with maximum adsorption capacity of 128.21 and 51.81mg/g for Pb(Ⅱ) and Cd(Ⅱ),respectively,implying that adsorption processes involved monolayer adsorption.Pb(Ⅱ) and Cd(Ⅱ) adsorption could be well described by the pseudo second-order kinetics model,and was found to be strongly dependent on pH and humic acid.The Pb(Ⅱ)and Cd(Ⅱ)-loaded microspheres were effectively desorbed using 0.01mol/L HCl or EDTA solution.NH2-MS have promise for use as adsorbents in the removal of Pb(Ⅱ) and Cd(Ⅱ) in wastewater treatment processes. | Yulin Tang Song Liang Juntao Wang Shuili Yu Yilong Wang | 2013 | Journal of Environmental Sciences2013，25，4： | 14 |
| 5 | Overview on current criteria for heavy metals and its hint for the revision of soil environmental quality standards in China显示文摘Following rapid social and economic development over the past several decades, soil pollution by heavy metals(HMs) has been both serious and widespread in China. The Soil Environmental Quality Standards(SEQSs) in China(GB 15618-1995) have been introduced to encourage and enforce sustainable soil HM management. However, in recent years, HM contents in soils have frequently been found to exceed their associated standard values, while the crops growing on them might still meet regulatory standards, and vice versa. There is thus growing awareness that GB 15618-1995 does not effectively regulate current soil HM pollution, as it has encountered bottlenecks, and disappointing outcomes caused by poor execution along with deficiencies and gaps in the policies. However, due to the deficiency of scientific research about relationships between soil HM concentrations and their ecological or human health effects, the development of SEQSs in China is still greatly restricted. This paper discusses international SEQSs of HMs as well their development in China over time, then examines current Chinese SEQSs to demonstrate their potential regulatory deficiencies by referring to international SEQSs. The corresponding legislative policies are described, and scientific information or responses are outlined for maintaining soil environmental quality. China's experience has shown that policy and science can be linked to work in tandem to better understand and manage soil quality issues. | CHEN Shi-bao WANG Meng LI Shan-shan ZHAO Zhong-qiu E Wen-di | 2018 | Journal of Integrative Agriculture2018，17，4： | 14 |
| 6 | Environmental application of three-dimensional graphene materials as adsorbents for dyes and heavy metals: Review on ice-templating method and adsorption mechanisms显示文摘The remediation of wastewater requires treatment technologies which are robust, efficient,simple to operate and affordable such as adsorption. Lately, three-dimensional(3D)graphene based materials have attracted significant attention as effective adsorbents for wastewater treatment. The intrinsic properties of 3D graphene structure such as large surface area and interconnected porous structure can facilitate the transport of pollutants into the 3D network and provide abundant active sites for trapping the pollutants. For the synthesis of 3D graphene structure, ice-templating is commonly practiced due to its facile steps, cost effectiveness and high scalability potential. This review covers the icetemplating fabrication technique for 3D graphene based materials and their application as adsorbents in eliminating dyes and heavy metals from aqueous media. The assembly mechanisms of the ice-templating fsynthesis are comprehensively discussed. Further discussion on the fundamental principles, critical process parameters and characteristics of ice-templated 3D graphene structures is also included. A thorough review on the mechanisms for batch adsorption of dyes and heavy metals is presented based on the structures and properties of the 3D graphene materials. The review further evaluates the dynamic adsorption in packed columns and the regeneration of 3D graphene based materials. | Kar Chiew Lai Lai Yee Lee Billie Yan Zhang Hiew Suchithra Thangalazhy-Gopakumar Suyin Gan | 2019 | Journal of Environmental Sciences2019，31，5： | 13 |
| 7 | Development and Prospect of Rare Earth Functional Biomaterials for Agriculture in China显示文摘The development and prospect of rare earth functional biomaterials (REFB) was discussed. From 1979 to 1985, the simple REFB (salts) has been developed, and the fundamental research including forms, effects, toxicity, conversion in soil, and analysis methods had been finished. Then, the RE feed additive materials had been developed, and the fundamental research had also been finished. In 1990s, new REFB including RE phosphate fertilizer additive, RE conversional agricultural film additive, RE water-retraining reagent and RE seed coating reagent had been developed out rapidly. They were extended to 1.36 million hectares and big benefit had been got during the last three years. Recently, it was found that RE has some function of antagonizing heavy metals and degradating organophosphors pesticide, so the REFB will be studied as a focus once more, and will become one of the important methods of guaranteeing food security in the future. | 王甲辰 刘向生 杨军 张赫 刘营 樊玉斌 伍艳平 韩学伟 | 2006 | Journal of Rare Earths2006，24，z2： | 12 |
| 8 | Heavy metals contents in soil profiles of typical agricultural lands in Yixing,Jiangsu Province,China显示文摘The effect of land use pattern on the heavy metals(HMs)distribution in soil profiles was investigated in Yixing City,China,for the four typical types of land utilization,i.e.vegetable fields on the plain,paddy fields,tea gardens on hilly lands and bamboo groves.The variance of HMs concentration in the depth of 0-15 cm,15-30 cm,30-60 cm of soil profiles was compared among the different tillage ages. Results showed there was a notable accumulation of Cd,Hg,Cu,Pb,Zn and Cr in the soil profiles of vegetable fields and paddy fields causing a pollution of Cu,Hg and Cd in some profiles,while no remarkable accumulation of HMs in the soil profiles of the tea gardens and bamboo groves was found. The accumulation extent of HMs in the soil profiles of the four kinds of land use followed a sequence of vegetable fields>paddy fields>tea gardens>bamboo groves.The accumulation of HMs was mainly due to the industry,transportation,other urban human activities,and intensive use of fertilizers and pesticides.The downward leaching of HMs was relatively remarkable in the soil profiles of vegetable fields. There was an accumulation in surface and subsurface layers for Cd,Hg,Pb,Zn in the soil profiles of paddy fields and tea gardens,and for Cd,Hg in those of bamboo groves.Serious pollution effects of Hg, Pb,and Zn have been shown in the soil of vegetable fields.All the four kinds of agricultural land are basically free from the pollution of the external sources of As and Ni.With the increase of tillage time, the soil of vegetable and paddy fields will face the potential risk of HMs pollution,which mainly comes from Hg,Cd and Cu,whereas that of tea gardens and bamboo groves faces a relatively small risk. | Zhou ShengLu Liao FuQiang Wu ShaoHua Zhang HongFu Ren Kui | 2008 | Chinese Science Bulletin2008，53，S1： | 11 |
| 9 | Biomass-derived porous carbon highly efficient for removal of Pb(Ⅱ) and Cd(Ⅱ)显示文摘The utilization of abundant and renewable biomass to fabricate advanced functional materials is considered a promising route for environmental applications.Herein,Lignin-based porous carbon with layered graphene-like structure(LPC)is successfully synthesized and applied to efficiently remove Pb(Ⅱ)and Cd(Ⅱ).The as-synthesized LPC materials are systematically characterized and these results show that LPC has a porous graphene-like structure,facilitating the diffusion and immobilization of heavy metal ions.The influence of different reaction parameters(solution pH,initial concentration of metal ions,contact time and adsorbent amount)on the adsorption performance is investigated in details.The results demonstrate that LPC can achieve superior adsorption capacities of 250.5 mg·g^-1 for Pb(Ⅱ)and 126.4 mg·g^-1 for Cd(Ⅱ),which are far superior to the previously reported adsorbents.Pseudo-second order kinetics model and Freundlich isotherm model describe the adsorption process well.Furthermore,the exhausted LPC can be regenerated easily and exhibits the removal efficiency of 96%and 92%for Pb(Ⅱ)and Cd(Ⅱ)after five continuous runs,respectively.This study shows a sustainable strategy for the design of porous carbon material from na?ve biomass and highlights the great potential in wastewater treatment. | Anqi Wang Zhikeng Zheng Ruiqi Li Di Hu Yiran Lu Huixia Luo Kai Yan | 2019 | Green Energy & Environment2019，4，4： | 10 |
| 10 | Use of polymeric sub-micron ion-exchange resins for removal of lead,copper,zinc,and nickel from natural waters显示文摘This research investigated the removal capacity of polymeric sub-micron ion-exchange resins(SMR) for removal of lead, copper, zinc, and nickel from natural waters in competition with natural organic matter(NOM). Polymeric SMR particles were created and tested to ensure that they were adequately dispersed in the solution. They removed little NOM(10%or less) from river water and wastewater, indicating that competition from NOM was not a major concern. SMR were able to remove 82% ± 0.2% of lead, 46% ± 0.6% of copper, 55% ±20% of zinc, and 17% ± 2% of nickel from river water spiked with 500 μg/L of each. Similarly,in wastewater, they were able to remove 86% ± 0.1% of lead, 38% ± 0.8% of copper, 28% ± 1%of zinc, and 11% ± 1% of nickel. | Audrey Murray Banu ?rmeci | 2019 | Journal of Environmental Sciences2019，31，1： | 9 |
| 11 | 黄土高原丘陵沟壑区新造耕地质量评价(英文)显示文摘In order to better understand the quality of newly created farmland(NF) as well as slope and check-dam farmland(CF) soil quality, two typical traditional farmland areas within the hilly and gully region of Chinese Loess Plateau were selected as controls in this analysis.The results of this study initially reveal that pH values for slope farmland(SF) and CF were significantly lower(P < 0.05) than those for NF and that SF values were always greater than those of their CF counterparts. At the same time, cation exchange capacity(CEC) and soil organic matter(SOM) occurred in the following size-decreasing sequence, i.e., CF, SF, and NF. Data also show that long-term planting has resulted in increases in total nitrogen(N),available N, total phosphorus(P), available P, total potassium(K) and available K and has also enhanced concentrations of soil copper(Cu), zinc(Zn), iron(Fe), and manganese(Mg)as well as soil cadmium(Ca), lead(Pb), chromium(Cr), and mercury(Hg). These latter elements occur in the concentration sequence of SF > CF > NF. Overall, results indicate that long-term planting negatively impacts soil health because of the accumulation of toxic heavy metals. This means that farmland planted over longer timescales needs to lie fallow to enable it to rehabilitate while NF requires the addition of organic matter as well as rotational utilization in order to facilitate the development of green agriculture. | 陈怡平 毋俊华 王洪 马吉福 苏翠翠 王凯博 王益 | 2019 | Journal of Geographical Sciences2019，0，5： | 9 |
| 12 | Recent research progress in geochemical properties and restoration of heavy metals in contaminated soil by phytoremediation显示文摘Heavy metals are widely distributed contaminants in natural environments and their potential threats to human health have attracted worldwide concerns due to the food chain. Therefore, great efforts have been made to reduce them to a safe level in soil. Compared with the traditional methods, the method using plants to remove them has been accepted as a feasible and efficient way. Herein, the geochemical behavior of heavy metals and the restoration methods with phytoremediation were reviewed. In addition, issues on heavy metal speciation as well as its influencing factors, phytoremediation mechanism, phytoremediation effect and vegetation selection principle used for phytoremediation were discussed. | FU Jiang-tao YU Dong-mei CHEN Xi SU Ying LI Cai-hong WEI Yong-ping | 2019 | Journal of Mountain Science2019，16，9： | 8 |
| 13 | 山东省蔬菜产地灌溉水重金属环境质量分析与评价(摘要)(英文)显示文摘[目的]评价山东省蔬菜基地灌溉水重金属环境质量。[方法]对山东省主要蔬菜产地的灌溉水进行了重金属Hg、Cd、As、六价Cr、Pb、Cu和Zn含量的抽样调查分析,并采用单项质量指数与综合质量指数相结合的方法对重金属的环境质量状况进行了评价。[结果]寿光、莱阳、金乡和章丘4个蔬菜产地灌溉水中各重金属的平均含量均远低于《食用农产品产地环境质量评价标准》(HJ332-2006)规定的限值,未发现重金属含量超标现象;4地灌溉水重金属的单项质量指数均小于0.5,综合质量指数分别为0.3178、0.3204、0.2326和0.2607,灌溉水环境质量均为1级。[结论]4个蔬菜产地的灌溉水环境质量属于清洁水平,适宜作为无公害蔬菜的灌溉用水。 | 刘苹 魏建林 于淑芳 杨力 Jian-lin Shu-fang | 2010 | Agricultural Science & Technology2010，11，5： | 7 |
| 14 | Environmental risks for application of magnesium slag to soils in China显示文摘Magnesium slag(MS)is one of the main industrial solid wastes produced by the magnesium industry.Solving the problem of its disposal has attracted much attention with increasing amounts of solid wastes generated in the production of metallic magnesium.Because MS contains calcium(Ca),magnesium(Mg),and silicon(Si),some have tried to use MS as Si-Ca-Mg fertilizer or for soil amendment in agriculture.However,in the magnesium metallurgical process,some pollutant elements are introduced into MS,resulting in the enrichment of these pollutants in MS,such as arsenic(As),chromium(Cr),cadmium(Cd),mercury(Hg),copper(Cu),nickel(Ni),fluorine(F)and chlorine(CI).Research indicates that the enrichment of these pollutants can result in high levels,especially for Cd,Hg,Cu,Ni,F and CI(0-4,0-0.74,20-127,100-170,2277-14800 and 133-1000 mg kg1,respectively)in some MS in China.These levels are often far beyond the limits(S0.3,s0.5,≤50 and≤60 mg·kg-1 for Cd,Hg,Cu and Ni,respectively)of the Chinese Risk Screening Values for Soil Contamination of Agricultural Land based on the Soil Environmental Quality Risk Control Standard for Soil Contamination of Agricultural Land(GB 15618-2018)or the critical reference values(<800 and≤200 for F and CI,respectively).The elements Hg,Cu,Cr and F(detected in MS leachate at 0.00023--0.0052,0.043--3.89,0.026-0.171,and 1.43-8.52 mg·L-1,respectively)also exceed the limits(Class IV-V)of the Chinese Standard for Groundwater Quality(GB/T 14848-2017).Based on the above results,it is suggested that without any pretreatment for reducing harmful pollutants MS should not be allowed to be applied for soil remediation or conditioning directly into farmlands in order to ensure soil health,food safety and environmental quality. | WANG Xiao-bin YAN Xiang LI Xiu-ying | 2020 | Journal of Integrative Agriculture2020，19，7： | 7 |
| 15 | Spatial distribution and sources of soil heavy metals in the outskirts of Yixing City,Jiangsu Province,China显示文摘City outskirts serve as the concentration centers for the pollutants discharged from various sources such as industry,agriculture and transportation.With the acceleration of industrialization and urbanization,the eco-environment of the city outskirts has become a hot spot of public concern.An analysis was conducted in this paper on the soil in the outskirts of Yixing City using frequency distribution functions.The heavy metal sources in this region had been divided into two components,i.e.natural background component and strong human disturbance component.The corresponding interpretation of the distribution pattern and features of heavy metal elements was presented by spatial analysis.The results showed that the strong human disturbance components of Hg,Pb,and Cu accounted for 36.9%, 26.7%,and 23.3%in their contents respectively,which indicated directly the serious effect of human activities on heavy metal contents.Hg and Pb,because of the human disturbance,showed the greatest spatial variability,and human activities intensified the heterogeneity of the spatial distribution.The anisotropic analysis showed the higher organisation of Hg and Zn in the direction of urban-rural transition,which indicated their spatial characteristics with urban-rural transition.Pb displayed distinctive structure in the vertical direction of urban-rural transition,which was largely controlled by highway distribution.Cu content in paddy fields was significantly higher than those of other land-use-types,and the agricultural non-point source pollution played an important role in the distribution pattern of Cu. | ShaoHua Wu ShengLu Zhou DeZhi Yang FuQiang Liao HongFu Zhang Kui Ren | 2008 | Chinese Science Bulletin2008，53，S1： | 7 |
| 16 | Spatial distribution and accumulation of heavy metals in tidal flat sediments of Shanghai coastal zone显示文摘Surface and core sediments from the high, middle and low tidal flats of Shanghai coastal zone were analyzed for heavy metal (e.g. Cu, Pb, Zn, Cr, Cd, Fe, Mn) concentrations. Besides Cd, the concentrations of Cu, Zn, Cr and Pb are 2-5 times higher than their background values and show serious pollution trend due to the direct discharge of industrial and municipal sewage along the Shanghai tidal flat, as well as the wet and dry depositions of industrial dusts. It seems that heavy metals prefer to accumulate and be enriched in the sediments near large sewage outlets, high flats, and the subsurface layer at the depth of 10-30 cm. Several main factors, which include the direct sewage discharge along the tidal flat, tidal hydrodynamic action, large engineering activity, early diagenesis and windstorm tide, are considered to be responsible for influencing spatial distribution patterns of heavy metals in the Shanghai tidal flat. | 陈振楼 刘培芳 许世远 柳林 余佳 俞立中 | 2001 | Science China Chemistry2001，44，S1： | 6 |
| 17 | An overview of carbon nanotubes role in heavy metals removal from wastewater显示文摘The scarcity of water, mainly in arid and semiarid areas of the world is exerting exceptional pressure on sources and necessitates offering satisfactory water for human and different uses. Water recycle/reuse has confirmed to be successful and promising in reliable water delivery. For that reason, attention is being paid to the effective treatment of alternative resources of water (other than fresh water) which includes seawater, storm water, wastewater (e.g., dealt with sewage water), and industrial wastewater. Carbon nanotubes (CNTs) are called the technology of 21st century. Nowadays CNTs have been widely used for adsorption of heavy metals from water/ wastewater due to their unique physical and chemical properties. This paper reviews some recent progress (from 2013 to 2018) in the application of CNTs for the adsorption of heavy metals in order to remove toxic pollutants from contaminated water. CNTs are expected to be a promising adsorbent in the future because of its high adsorption potential in comparison to many traditional adsorbents. | Leila Ouni Ali Ramazani Saeid Taghavi Fardood | 2019 | Frontiers of Chemical Science and Engineering2019，13，2： | 5 |
| 18 | Distribution and partitioning of heavy metals in large anthropogenically impacted river, the Pearl River, China显示文摘In order to evaluate the distribution and partitioning characteristics of heavy metals in the large anthropogenically impacted Pearl River Basin, the contents of ‘‘anthropophile'' elements(Cr, Ni, Cu, Zn, Cd and Pb,which are clearly influenced by human activities) were determined, and their partitioning coefficients(Kd) between water and sediments and enrichment factors(EF) were calculated for samples collected at different locations along the Pearl River main stream. The modified BCR sequential extraction procedure(proposed by the European Community Bureau of Reference in 1993), which involves the successive extraction of metals in a decreasing order of reactivity, was applied. Sediment samples from the upper,middle, and lower reaches were included in this study. The results showed that the content of most metals in water and sediment samples gradually increases from upstream to downstream, suggesting a possible input from human activities as shown by their increasing high EF, ranged from 1.4 to 3.9 for Cu, from 1.4 to 6.7 for Zn, from 2.5 to59.1 for Cd, and from 1.7 to 8.9 for Pb, respectively. Thehigher partition coefficients(Kd) for Cr, Zn, and Pb(10~5–10~6) indicated that they were mainly transported in solid phase, while parts of Ni, Cu, and Cd were transported in dissolved phase as they display relatively lower Kdin the range of 10~4–10~5. According to the results of the BCR leaching, the percentage of non-residual fraction of heavy metals in the sediments showed a decreasing order of Cd [ Pb [ Zn [ Cu [ Ni [ Cr, implying that Cd and Pb were more active and bioavailable compared to the other four metals, and thus would be potentially more harmful to the watershed ecosystem. | Silan Liu Zhongwei Wang Yuanyuan Zhang Yulong Liu Wei Yuan Ting Zhang Yujie Liu Ping Li Li He Jiubin Chen | 2019 | Acta Geochimica2019，38，2： | 5 |
| 19 | Superior adsorption performance of graphitic carbon nitride nanosheets for both cationic and anionic heavy metals from wastewater显示文摘Water pollution caused by highly toxic Cd(II), Pb(II), and Cr(VI) is a serious problem. In the present work,a green and low-cost adsorbent of g-C_3N_4 nanosheets was developed with superior capacity for both cationic and anionic heavy metals. The adsorbent was easily fabricated through one-step calcination of guanidine hydrochloride with thickness less than 1.6 nm and specific surface area of 111.2 m^2·g^(-1). Kinetic and isotherm studies suggest that the adsorption is an endothermic chemisorption process, occurring on the energetically heterogeneous surface based on a hybrid mechanism of multilayer and monolayer adsorption. The tri-s-triazine units and surface N-containing groups of g-C_3N_4 nanosheets are proposed to be responsible for the adsorption process.Further study on pH demonstrates that electrostatic interaction plays an important role. The maximum adsorption capacity of Cd(II), Pb(II), and Cr(VI) on g-C_3N_4 nanosheets is 123.205 mg·g^(-1), 136.571 mg·g^(-1),and 684.451 mg·g^(-1), respectively. The better adsorption performance of the adsorbent than that of the recently reported nanomaterials and low-cost adsorbents proves its great application potential in the removal of heavy metal contaminants from wastewater. The present paper developed a promising adsorbent which will certainly find applications in wastewater treatment and also provides guiding significance in designing adsorption processes. | Gang Xiao Yaoqiang Wang Shengnan Xu Peifeng Li Chen Yang Yu Jin Qiufeng Sun Haijia Su | 2019 | Chinese Journal of Chemical Engineering2019，27，2： | 5 |
| 20 | Distribution and relationship between antimicrobial resistance genes and heavy metals in surface sediments of Taihu Lake,China显示文摘Heavy metals, pharmaceuticals, and other wastes released into the environment can significantly influence environmental antibiotic resistance. We investigated the occurrence of 22 antimicrobial resistance genes(ARGs) and 10 heavy metal concentrations, and the relationship between ARGs and heavy metals in surface sediment from seven sites of Lake Taihu. The results showed significant correlations(p < 0.05) between sediment ARG levels,especially for tetracycline and sulfonamides(e.g., tet(A), tet(D), tet(E), tet(O), sul1, sul2 and int-1) and specific heavy metals(Fe, Mn, Cr, Cu, Zn, among others) in the Lake. In the surface sediments, heavy metals showed an interaction with resistance genes, but the strength of interaction was diminished with increasing depth. For most of the heavy metals, the concentration of elements in the top sediments was higher than that in other depths.Tetracycline resistance genes(tet(A), tet(B), tet(D), tet(E) and tet(O), β-lactam resistance genes(SHV, TEM, CTX, OXA and OXY) and sulfonamide resistance genes(sulA, sul1, sul2, sul3 and int-1) were detected. They showed a trend which inferred a statistically significant increase followed by decreases in the relative abundance of these ARGs(normalized to 16 S rRNA genes) with increasing depth. This study revealed that tet(A), tet(O), TEM, OXY, int-1, sul1 and sul3 were widespread in surface sediments with high abundance, indicating that these genes deserve more attention in future work. | Okugbe E.Ohore Felix Gyawu Addo Songhe Zhang Nini Han Kwaku Anim-Larbi | 2019 | Journal of Environmental Sciences2019，31，3： | 5 |
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