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| 1 | Understanding the adsorption mechanism of Ni(II) on graphene oxides by batch experiments and density functional theory studies显示文摘The graphene oxides(GOs) have attracted multidisciplinary study because of their special physicochemical properties. The high surface area and large amounts of oxygen-containing functional groups make GOs suitable materials for the efficient elimination of heavy metal ions from aqueous solutions. Herein the sorption of Ni(II) on GOs was studied using batch experiments, and the results showed that the sorption of Ni(II) is strongly dependent on p H and ionic strength at pH<8, and independent of ionic strength at pH>8. The sorption of Ni(II) is mainly dominated by outer-sphere surface complexation and ion exchange at low p H, and by inner-sphere surface complexation at high p H. The interaction of Ni(II) with GOs was also investigated by theoretical density functional theory(DFT) calculations, and the results show that the sorption of Ni(II) on GOs is mainly attributed to the –COH and –COC groups and the DFT calculations show that Ni(II) forms stable GO_Ni_triplet structure with the binding energy of -39.44 kcal/mol, which is in good agreement with the batch sorption experimental results. The results are important for the application of GOs as adsorbents in the efficient removal of Ni(II) from wastewater in environmental pollution cleanup. | Yuantao Chen WeiZhang Shubin Yang Aatef Hobiny Ahmed Alsaedi Xiangke Wang | 2016 | Science China Chemistry2016，59，4： | 6 |
| 2 | MOF-derived ZnCo_2O_4/C wrapped on carbon fiber as anode materials for structural lithium-ion batteries显示文摘To meet the requirements for the mechanical and electrochemical performance for carbon fiber-based (CF-based) composites in the structural lithium ion batteries (SLIBs) application, better CF-Based composites are urgently needed. Herein, we report a novel composite metal organic framework (MOF)-derived ZnCo_2 O_4/C@carbon fiber via a facile method and subsequent annealing treatment. In this anode,the nano ZnCo_2 O_4/C coatings wrapped on the surface of CF provide more active sites for electrode reactions and the thin carbon layers give the additional protection. For this material, after 100 cycles, it exhibits excellent cycling stability including high reversible capacity of 463 mAh/g at 50 mA/g, which increases 201% than that of the CF. Thus, this structural anode material exhibits enhanced capacity, high initial columbic efficiency. | Huagen Li Shubin Wang Mengjie Feng Jiping Yang Boming Zhang | 2019 | Chinese Chemical Letters2019，30，2： | 4 |
| 3 | Congenital bifurcation of tympanic segment of facial nerve显示文摘Congenital aural atresia is usually associated with facial nerve (the seventh cranial nerve,CN7) anomalies with an incidence rate of 60%-75%.These anomalies include facial nerve displacement,facial nerve component overlying the oval window,bony canal dehiscence,and bifurcation,which increase the risk of surgical facial nerve injuries.Among all these anomalies,congenital bifurcation of the tympanic segment of facial nerve is the most confusing situation that significantly increases the surgical risk during hearing reconstruction. | Wang Danni Zhao Shouqin Zhao Yanling Chen Shubin Yang Lin | 2014 | Chinese Medical Journal2014，，9： | 3 |
| 4 | Trimming of N-Glycans by the Golgi-Localized α-1,2-Mannosidases, MNS1 and MNS2, Is Crucial for Maintaining RSW2 Protein Abundance during Salt Stress in Arabidopsis显示文摘天门冬素(Asn/N ) 连接了 glycans 为蛋白质合拢, trafficking,和 endoplasmic 是重要的在优核质的联系蜂窝胃的降级。glycoproteins 的成熟包含在 Golgi 由另外的糖分子的 mannosidases 和三分支的 N-glycans 的增加整修 mannosyl 残余。然而,调停 Golgi 的甘露糖整修的生物重要性充分没被理解。这里,我们显示出二机能上地冗余的 mannosidases, MNS1 和 MNS2 的那废除,为在 A 和工厂 N-glycans 的 C 分支上整修的 -1,2-mannose 负责在 Arabidopsis 在盐压力条件下面导致严重的根生长抑制。相反,有在 oligosaccharide 先锋的生合成的缺点的异种当甘露糖整修不在时显示了提高的盐忍耐。然而,在 EBS3 的变化,为分叉的 N-glycan 先锋的形成被要求,压制了 mns1 mns2 的盐敏感的显型两倍异种。有趣地,我们观察了那 ? 纤维素生合成在高咸度下面在 mns1 mns2 根被损害。一致地, ? 许多膜抛锚了 endo -- 在纤维素生合成起一个关键作用的 1,4-endoglucanase (RSW2/KOR ) 和它的变异的变体 rsw2-1 ? 被调制由 ? 在盐应力下面整修的 -1,2-mannose。RSW2 的 Overexpression 能部分救 mns1 mns2 的盐敏感的显型。一起拿,这些结果建议 N-glycans 整修的那 MNS1/2-mediated 甘露糖在 modulating glycoprotein 丰富是关键的在植物承受盐应力。 | Chuanfa Liu Guanting Niu Huchen Zhang Yafei Sun Shubin Sun Fugen Yu Shan Lu Yonghua Yang Jianming Li Zhi Hong | 2018 | Molecular Plant2018，11，5： | 3 |
| 5 | The geometric simulation and analysis of the blind growth fold in the overthrust belt of the southern section of the frontier Longmen Mt.during Late Triassic显示文摘The seismic profiles processed by high-resolution display that a blind growth fault-bend fold emerges in depth of seismic exploration area in Dayi in the southern section of the frontier Longmen Mt.This paper presents a detailed structural interpretation to seismic section,then describes the deformed geometry related to the pre-growth strata,the growth strata and the post-growth strata on both limbs of the fold.The computer geometric simulation,based on the model of fault-bend fold,is utilized to stimulate the geometry of the blind growth fold at different sedimentation rates in Dayi.These structural features are subsequently extracted and compared with the actual seismic reflection section.Our research suggests that a low angle overthrust formed during Late Triassic also appears in the southern section of the frontier Longmen Mt.The event of structure took place at the depositional stage of a portion of the middle and upper fourth member of Xujiahe Formation(T3x4),which corresponds to thrusting in the northern section of the frontier Longmen Mt.However,the thrusting displacement here is smaller than one of the northern section. | CHEN Wei YANG KeMing LI ShuBin JIAN GaoMing TANG Jin ZHAO Yiao SU Qian | 2009 | Chinese Science Bulletin2009，54，8： | 3 |
| 6 | Preparation and properties of ^(117m)Sn(Ⅳ)-TTHMP in in-vitro and in small animals显示文摘In this work,TTHMP was synthesized and labelled with ^(117m)Sn.The preparation conditions,stability and lipophilicity of ^(117m)Sn(Ⅳ)-TTHMP were investigated.Biodistribution of the complex in rabbits and mice was studied. It was found that the quantity of TTHMP and pH value of the preparation solution had vital effects on the labeling yield of ^(117m)Sn(Ⅳ)-TTHMP.It was also found that ^(117)Sn(Ⅳ)-TTHMP was hydrophilic and stable at room tempera- ture and 37℃in open air.^(117m)Sn(Ⅳ)-TTHMP showed unexpectedly high bone uptake and bone-to-blood ratio in the animals.This made it potentially useful as an reagent for skeletal scintigraphy and radiotherapy of bone tumors. | HE Jiaheng LUO Shunzhong JIANG Shubin YANG Yuqing WANG Guanquan | 2007 | Nuclear Science and Techniques2007，18，6： | 3 |
| 7 | Identification of long non-coding RNA p34822 as a potential plasma biomarker for the diagnosis of hepatocellular carcinoma显示文摘Dear Editor,Hepatocellular carcinoma(HCC)is the third leading cause of cancer-related deaths worldwide(Li and Satomura,2015).Early diagnosis and treatment are vital for reducing mortality.Currently,biomarkers such as serum alpha fetoprotein(AFP),AFP-L2,and carcinoembryonic antigen are widely used tumor markers for managing HCC in patients(Shi et al.,2016).However,because of their low diagnostic sensitivity and specificity,novel biomarkers with high sensitivity and specificity for early HCC diagnosis are needed. | Cheng Wang Tianyu Ren Keyu Wang Shaogeng Zhang Shubin Liu Hu Chen Penghui Yang | 2017 | Science China(Life Sciences)2017，60，9： | 2 |
| 8 | Dislocation glide and mechanical twinning in a ductile VNbTi medium entropy alloy显示文摘An equiatomic VNbTi medium-entropy alloy with outstanding tensile properties and unique deformation behavior is reported.The screw dislocation glide,deformation twinning,and dislocation accumulation induced kink bands are identified as three deformation mechanisms that contribute to a large elongation above 20%.The{112}<111>twins are activated at the beginning of the yield stage accompanied by sudden stress-drop and pronounced acoustic emission.Dislocations dominate subsequent tensile deformation,and the prevalent multiplanar dislocation slip promotes the formation of complex dislocation configurations(e.g.,debris,dipoles,and loops)and dense dislocation networks.The twin bands and kink bands can further impede the dislocation motion meanwhile effectively alleviate stress concentration.The synergistic activation of these deformation mechanisms provides new opportunities to design ductile refractory medium-and high-entropy alloys. | Mingxu Wu Shubin Wang Fei Xiao Guoliang Zhu Chao Yang Da Shu Baode Sun | 2022 | Journal of Materials Science & Technology2022，，15： | 2 |
| 9 | Boron-doping induced lithophilic transition of graphene for dendrite-free lithium growth显示文摘Li metal,possessing advantages of high theoretical specific capacity and low electrochemical potential,is regarded as the most promising anode material for next-generation batteries.However,despite decades of intensive research,its practical application is still hindered by safety hazard and low Coulombic efficiency,which is primarily caused by dendritic Li deposition.To address this issue,restraining dendrite growth at the nucleation stage is deemed as the most effective method.By utilizing the difference of electronegativity between boron atoms and carbon atoms,carbon atoms around boron atoms in boron-doped graphene(BG)turn into lithiophilic sites,which can enhance the adsorption capacity to Li^(+)at the nucleation stage.Consequently,an ultralow overpotential of 10 mV at a current density of 0.5 mA/cm^(2) and a high average Coulombic efficiency of 98.54%over more than 140 cycles with an areal capacity of 2 mAh/cm^(2) at a current density of 1 m A/cm^(2) were achieved.BG-Li|LiFePO_(4) full cells delivered a long lifespan of480 cycles at 0.5 C and excellent rate capability.This work provides a novel method for rational design of dendrite-free Li metal batteries by regulating nucleation process. | Wei Liu Pengbo Zhai Shengjian Qin Jing Xiao Yi Wei Weiwei Yang Shiqiang Cui Qian Chen Chunqiao Jin Shubin Yang Yongji Gong | 2021 | Journal of Energy Chemistry2021，30，5： | 2 |
| 10 | Fast Cryomediated Dynamic Equilibrium Hydrolysates towards Grain Boundary-Enriched Platinum Scaffolds for Efficient Methanol Oxidation显示文摘Although platinum nanocrystals have been considered as potential electrocatalysts for methanol oxidation reaction(MOR)in fuel cells,the large-scale practical implementation has been stagnated by their limited abundance,easy poisoning,and low durability.Here,grain boundary-enriched platinum(GB-Pt)scaffolds are produced in large scale via facilely reducing fast cryomediated dynamic equilibrium hydrolysates of platinum salts.Such plentiful platinum grain boundaries are originated from the fast fusion of short platinum nanowires during reduction of the individually and homogeneously dispersed platinum intermediates.These grain boundaries can provide abundant active sites to efficiently catalyze MOR and meanwhile enable to oxidize the adsorbed poisonous CO during the electrocatalytic process.As a consequence,the as-synthesized GB-Pt scaffolds exhibit an impressively high mass activity of 1027.1 mA mgPt^(−1) for MOR,much higher than that of commercial Pt/C(345.2 mA mgPt^(−1)),as well as good stability up to 5000 cycles.We are confident that this synthetic protocol can be further extended to synthesize various grain boundary-enriched metal scaffolds with broad applications in catalysis. | Chao Zhang Huajie Huang Jianan Gu Zhiguo Du Bin Li Songmei Li Shubin Yang | 2019 | Research2019，，1： | 2 |
| 11 | Preparation and Characterization of Ternary Europium Complex-Doped Thin Sol-Gel Hybrid Film by Fluorescence Spectroscopy显示文摘IntroductionThelow-temperatureprocessingofthesol-gelmaterialmakesitpossibletoentraporganicspecieseasilywithinarigidglassmatri... | FU Lianshe, ZHANG Hongjie**, WANG Shubin MENG Qingguo, YANG Kuiyue and NI Jiazuan (Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022) | 1999 | Chemical Research in Chinese Universities1999，15，2： | 1 |
| 12 | The C_(6)D_(6)detector system on the Back-n beam line of CSNS显示文摘Introduction The neutron capture cross sections are very important in the field of nuclear device design and basic physics research.Hydrogen-free liquid scintillator such as C_(6)D_(6)detectors are widely used in the neutron capture cross-sectional measurements for the low neutron sensitivity and fast time response.The Back-n white neutron source at China Spallation Neutron Source is the first spallation white neutron source in China,and it is suitable for neutron capture cross-sectional measurement.Materials and methods A C_(6)D_(6)detector system was built in the Back-n experimental station.The pulse height weighting technique was used to determine the system’s detection efficiency.The response to gamma rays of the C_(6)D_(6)detector was measured,and the energy resolution function was determined.Monte Carlo simulation with Geant4 code was carried out to get the weighting function of this C_(6)D_(6)detector system.Additionally,the systematic uncertainty of the weighting function was also determined.Conclusion According to the experimental and simulation results,this C_(6)D_(6)detector system can be used to measure neutron capture cross section. | Jie Ren Xichao Ruan Jie Bao Guangyuan Luan Wei Jiang Qi An Huaiyong Bai Ping Cao Qiping Chen Yonghao Chen Pinjing Cheng Zengqi Cui Ruirui Fan Changqing Feng Minhao Gu Fengqin Guo Changcai Han Zijie Han Guozhu He Yongcheng He Yuefeng He Hanxiong Huang Weiling Huang Xiru Huang Xiaolu Ji Xuyang Ji Haoyu Jiang Hantao Jing Ling Kang Mingtao Kang Bo Li Lun Li Qiang Li Xiao Li Yang Li Yang Li Rong Liu Shubin Liu Xingyan Liu Yinglin Ma Changjun Ning Binbin Qi Zhaohui Song Hong Sun Xiaoyang Sun Zhijia Sun Zhixin Tan Hongqing Tang Jingyu Tang Pengcheng Wang Qi Wang Taofeng Wang Yanfeng Wang Zhaohui Wang Zheng Wang Jie Wen Zhongwei Wen Qingbiao Wu Xiaoguang Wu Xuan Wu Likun Xie Yiwei Yang Han Yi Li Yu Tao Yu Yongji Yu Guohui Zhang Jing Zhang Linhao Zhang Liying Zhang Qingmin Zhang Qiwei Zhang Xianpeng Zhang Yuliang Zhang Zhiyong Zhang Yingtan Zhao Liang Zhou Zuying Zhou Danyang Zhu Kejun Zhu Peng Zhu | 2019 | Radiation Detection Technology and Methods2019，3，3： | 1 |
| 13 | Hollow carbon spheres with encapsulation of Co 3 O 4 nanoparticles as anode material for lithium ion batteries显示文摘 | Liang Zhan Yanli Wang Wenming Qiao Licheng Ling Shubin Yang | 2012 | Electrochimica Acta2012，，： | 1 |
| 14 | Pt-decorated 3D architectures built from graphene and graphitic carbon nitride nanosheets as efficient methanol oxidation catalysts 显示文摘 | HUAGN Huajie YANG Shubin VAJTAI R | 2014 | Advanced Materials2014，26，30： | 1 |
| 15 | Expansion of mesocarbon microbeads显示文摘 | YANG Shubin SONG Huaihe CHEN Xiaohong | 2006 | Carbon2006，44，4： | 1 |
| 16 | Nanosized tin and tin oxidesloaded expanded mesocarbon microbeads as negative electrode material for lithium-ion batteries显示文摘 | Yang Shubin Song Huaihe | 2007 | J Power Sources2007，173，： | 1 |
| 17 | Comparative study of pyrolysis behaviors of com stalk and its three components显示文摘 | Lv Gaojin Wu Shubin Yang Guihua | 2013 | Journal of Analytical and Applied Pyrolysis2013，104，： | 1 |
| 18 | Nanographene-constructed hollow carbon spheres and their favorable electroactivity with respect to lithium storage显示文摘 | YANG Shubin FENG Xinliang ZHI Linjie | 2010 | Advanced Materials2010，22，7： | 1 |
| 19 | A Bottom‐Up Approach to Build 3D Architectures from Nanosheets for Superior Lithium Storage显示文摘 | Yongji Gong Shubin Yang Liang Zhan Lulu Ma Robert Vajtai Pulickel M. Ajayan | 2014 | Adv Funct Mater2014，，1： | 1 |
| 20 | Effect of pH, Ionic Strength and Humic Substances on the Adsorption of Uranium (VI) onto Na-rectorite显示文摘 | Zhao Donglin Yang Shubin Chen Shaohua Guo Zhiqiang Yang Xin | 2011 | Journal of RadioAnalytical and Nuclear Chemistry2011，287，2： | 1 |
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