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1Recent advances in solid-state LED phosphors with thermally stable luminescence显示文摘Phosphor-converted white light-emitting diode(LED) lighting has gained tremendous achievements since the invention of the InGaN blue LED by Nakamura et al., who won the Nobel Physics Prize in 2014.By far, a significant challenge comes from the thermal quenching(TQ) behavior of the present LED phosphors during the high-power LED operation or the updated laser lighting. But systematic research or review on the luminescence quenching character and/or how to realize thermally stable luminescence are lacking. Since TQ is an inherent property of phosphors, it can be diminished by different approaches.This review proceeds from the mechanism of TQ, summarizes previous researches on improving the thermal stability of LED phosphors and also discusses future research opportunities in this field. The developments of the phosphors with properties of high luminance and thermal stability, as well as the improved strategies involved,will benefit the basic researches and applications in high power lighting or high-luminance laser lighting.Jianwei Qiao Jing Zhao Quanlin Liu Zhiguo Xia 2019Journal of Rare Earths2019,37,6:34
2Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition显示文摘Phosphor-converted white LEDs rely on combining a blue-emitting InGaN chip with yellow and red-emitting luminescent materials.The discovery of cyan-emitting(470-500 nm)phosphors is a challenge to compensate for the spectral gap and produce full-spectrum white light.Na_(0.5)K_(0.5)Li_(3)SiO_(4):Eu^(2+)(NKLSO:Eu^(2+))phosphor was developed with impressive properties,providing cyan emission at 486 nm with a narrow full width at half maximum(FWHM)of only 20.7 nm,and good thermal stability with an integrated emission loss of only 7% at 150℃.The ultra-narrow-band cyan emission results from the high-symmetry cation sites,leading to almost ideal cubic coordination for UCr_(4)C_(4)-type compounds.NKLSO:Eu^(2+) phosphor allows the valley between the blue and yellow emission peaks in the white LED device to be filled,and the color-rendering index can be enhanced from 86 to 95.2,suggesting great applications in full-spectrum white LEDs.Ming Zhao Hongxu Liao Maxim S.Molokeev Yayun Zhou Qinyuan Zhang Quanlin Liu Zhiguo Xia 2019Light(Science & Applications)2019,8,1:21
3Formation mechanisms of megadunes and lakes in the Badain Jaran Desert,Inner Mongolia显示文摘Field observations demonstrate that calc-sinters occurred in the lakes of Badain Jaran Desert. 87Sr/86Sr ratios,14C,δ 13C and mineral com-positions of calc-sinters,and 3He/4He,4He/20Ne,δ 18O,δ D,pH and TDS of water from springs and lakes are analyzed in detail. The results indicate that the lake water is supplied through deep fault zone. The “ker-nel” of stabilized dunes in the Badain Jaran Desert perhaps consists of calc-sinters and calcareous ce-mentation layers. Deep-seated groundwater effuses from this “kernel” and recharges to lakes in desert. Precipitation and snowmelt water from the Qing-hai-Tibet Plateau is fed into the Badain Jaran Desert,Gurinai,Wentougaole and Ejinqi areas through the Xigaze-Langshan Fault zone. The isotopic composi-tions of groundwater in the Alax Plateau are abnor-mal due to the strong evaporation of the Gyaring and Ngoring lake water in the headstream of the Yellow River. Groundwater dissolves dissoluble fractions of rocks during its transportation through the fault zone and flows out of the mouth of spring in the Badan Jaran Desert. The dissoluble fractions are finally de-veloped into calc-sinters and calcareous cementation layers around the spring. Calci-sinters are gradually largened and eventually emerge on the surface of lake water. Eolian sands accumulate on the surfaces of calc-sinters and calcareous cementation layers,and eventually develop into dunes. Invasion of magma causes an increase in the temperature of groundwater within the faults. Groundwater evapora-tion provides water vapor for the formation of humid stabilized dunes during its upwelling. Rhizoconcre-tions found in Yihejigede indicate that the dune was formed and remained immovable 4700 years ago. The height of the megadunes is proportional to thermal quantity carried by the groundwater.CHEN Jiansheng ZHAO Xia SHENG Xuefen DONG Haizhou RAO Wenbo SU Zhiguo 2006Chinese Science Bulletin2006,51,24:19
4Structural Engineering of Eu^2+-Doped Silicates Phosphors for LED Applications显示文摘CONSPECTUS:Phosphor-converted light-emitting diodes(pc-LEDs)are of great importance for their applications in solid-state lighting,backlit display,and near-infrared detection light source.Herein,the main challenges for these emergent pc-LEDs are to achieve full-spectrum lighting,wide color gamut display and broadband high efficiency near-infrared emission,respectively,which depends on the luminescence properties of phosphors used.Owing to the unique 4f-5d transition,Eu^2+is one of the most commonly used activators in luminescent materials for pc-LEDs,and Eu^2+-doped earth-abundant silicates phosphors exhibit outstanding luminescence properties,including multicolor emission,adjustable bandwidth,excellent thermal stability as well as high luminescence efficiency.These attributes motivate scientists to find Eu^2+-doped silicates phosphors that can practically meet the various LED application requirements.Since the traditional trial and error exploration is time-consuming and not necessarily successful,it is necessary to find reliable structural engineering strategies to discover new phosphor systems and also realize purposeful photoluminescence tuning.The adjustable 4f-5d electronic transitions of Eu^2+,the variable crystal structures of the silicate hosts and their coupling effect simultaneously account for the targeted luminescence behaviors and their precise emission color tuning.Thus,we aim at developing Eu^2+-doped silicate phosphors that can solve the application challenges through a comprehensive understanding of Eu^2+photoluminescence mechanism and the structure−property relationships.In this Account,we first illustrate the luminescence theory of Eu^2+in inorganic solids and summarize the research results of the effect originated from centroid shift,crystal field splitting,Stokes shift,and emission bandwidth.On the basis of the factors dominating the variation of luminescence characteristics,several structural strategies to manipulate Eu^2+emission in silicates are proposed,including(1)modify the chemical composition and crystal structure by various substitutions,(2)choose or change a suitable crystallographic site for Eu^2+and(3)control crystalline phase transition by external factors.Meanwhile,we briefly introduce the photoluminescence behaviors of Eu^2+in different silicates controlled by these structural engineering strategies.Second,we outline our recent research progress on blue LED pumped Eu^2+-doped silicate phosphors with emphasis on the design principle and the relationship between the structure and luminescence.The state-of-the-art LED application including full spectrum solid-state lighting,wide color gamut display and near-infrared night-vision technologies are introduced.Finally,we proposed the future research opportunities and challenges.The development of these Eu^2+-doped silicate phosphors exhibiting excellent luminescence performance is highly inspiring,and we expect this Account can be helpful for controlling the photoluminescence by theory-structure−property relationships and guide scientists discover the next generation of Eu^2+-doped phosphors for emerging applications.Ming Zhao Qinyuan Zhang Zhiguo Xia 2020Accounts of Materials Research2020,1,2:7
5Luminescence and energy transfer of color-tunable Lu2MgAl4SiO12:Eu^2+,Ce^3+,Mn^2+ phosphors显示文摘Energy transfer among the co-doped activators is an efficient route to achieve color-tunable emission in inorganic phosphors.Herein,photoluminescence tuning from blue to cyan has been achieved in the Lu2MgAl4 SiO12;Eu^2+,Ce^3+phosphors by varying the Ce^3+concentration with a fixed Eu^2+content.With the further introduction of a Mn^2+-Si^4+couple into the host lattice,the emission color can be tuned to red through the energy transfer of Eu^2+and Mn^2+.The luminescence properties and the energy transfer mechanism were studied in detail.The energy transfer from Eu^2+to Ce^3+is certified as a dipolequadrupole interaction with the energy transfer efficiency of 41.4%and Eu^2+to Mn^2+belongs to a dipole-dipole interaction with the energy transfer efficiency of 94.3%.The results imply that this singlephased Lu2MgAl4 SiO12:Eu^2+,Ce^3+,Mn^2+phosphor has a potential prospect for application in near-UV chip pumped white light emitting diodes.Zhiqiang Ming Jing Zhao Hendrik C.Swart Zhiguo Xia 2020Journal of Rare Earths2020,38,5:5
6Bevacizumab biosimilar LY01008 compared with bevacizumab(Avastin)as first-line treatment for Chinese patients with unresectable,metastatic,or recurrent non-squamous non-small-cell lung cancer:A multicenter,randomized,double-blinded,phase Ⅲ trial显示文摘Background:Previous studies have demonstrated the preclinical pharmacological and toxicological consistency,and clinical pharmacokinetic equivalence of bevacizumab biosimilar LY01008 with reference bevacizumab(Avastin).This randomized controlled trial aimed to compare the efficacy and safety of LY01008 with Avastin in first-line treatment of Chinese patients with advanced or recurrent non-squamous non-small cell lung cancer(NSCLC).Methods:StageⅢB-ⅣNSCLC patients with evaluable lesions,good physical status,and adequate organ functions from 67 centers across China were randomized in a ratio of 1:1 to receive LY01008 or Avastin 15 mg/kg intravenously in combination with paclitaxel/carboplatin(combined treatment)for 4-6 cycles,followed by maintenance monotherapy with LY01008 until disease progression,intolerable toxicity,or death.The primary endpoint was objective response rate(ORR)in accordance with Response Evaluation Criteria in Solid Tumors(RECIST)version 1.1 confirmed by independent radiological review committees(IRRC).Secondary endpoints included disease control rate(DCR),duration of response(DoR),progression-free survival(PFS),overall survival(OS),and safety.This study was registered in Clinical Trials.gov(NCT03533127).Results:Between December 15^(th),2017,and May 15^(th),2019,a total of 649 patients were randomized to the LY01008(n=324)or Avastin(n=325)group.As of September 25th,2019 for primary endpoint analysis,589 patients received ORR evaluation,with a median number of combined treatment cycles of 5(range 1-6)andmedian duration of treatment of 3.0(range 0.0-5.1)months.ORRof responseevaluable patients in the LY01008 and Avastin groups were 48.5% and 53.0%,respectively.The stratified ORR ratio was 0.91(90%CI 0.80-1.04,within the prespecified equivalence margin of 0.75-1.33).Up to May 15^(th),2020,with a median follow-up of 13.6(range 0.8-28.4)months,no notable differences in DCR,median DoR,median PFS,median OS,and 1-year OS rate were observed between the LY01008 and Avastin groups.There were no clinically meaningful differences in safety and immunogenicity across treatment groups.Conclusions:LY01008 demonstrated similarity to Avastin in terms of efficacy and safety in Chinese patients with advanced or recurrent non-squamous NSCLC.LY01008 combined with paclitaxel/carboplatin is expected to become a new treatment option for unresectable,metastatic,LY01008 and Avastin groups.There were no clinically meaningful differences in safety and immunogenicity across treatment groups.Conclusions:LY01008 demonstrated similarity to Avastin in terms of efficacy and safety in Chinese patients with advanced or recurrent non-squamous NSCLC.LY01008 combined with paclitaxel/carboplatin is expected to become a new treatment option for unresectable,metastatic,or recurrent non-squamous NSCLC patients in the first-line setting.Yuankai Shi Kaijian Lei Yuming Jia Bingqiang Ni Zhiyong He Minghong Bi Xicheng Wang Jianhua Shi Ming Zhou Qian Sun Guolei Wang Dongji Chen Yongqian Shu Lianke Liu Zhongliang Guo Yong Liu Junquan Yang Ke Wang Ke Xiao LinWu Tienan Yi Debin Sun Mafei Kang Tianjiang Ma Yimin Mao Jinsheng Shi Tiegang Tang Yan Wang Puyuan Xing Dongqing Lv Wangjun Liao Zhiguo Luo Bin Wang Xiaohong Wu Xiaoli Zhu Shuhua Han Qisen Guo Rongyu Liu Zhiwei Lu Jianyong Zhang Jian Fang Changlu Hu Yinghua Ji Guolong Liu Hong Lu Dedong Wu Junhong Zhang Shuyang Zhu Zheng Liu Wensheng Qiu Feng Ye Yan Yu Yanqiu Zhao Qinhong Zheng Jun Chen Zhanyu Pan Yiping Zhang Wenjuan Lian Bo Jiang Bo Qiu Guojun Zhang Hua Zhang Yanju Chen Yuan Chen Hongbing Duan Manxiang Li Shengming Liu Lijun Ma Hongming Pan Xia Yuan Xueli Yuan Yulong Zheng Emei Gao Li Zhao Shumin Wang Can Wu 2021Cancer Communications2021,41,9:5
7Moisture-induced degradation of the narrow-band red-emitting SrLiAl3N4:Eu2+phosphor显示文摘The degradation of materials plays an important role in their application and service process. In this work, the moisture-induced degradation of SrLiAl3 N4:Eu2+(SLAN), a very promising narrow-band redemitting phosphor, was comprehensively investigated by treating it in two different moisture conditions in order to reveal the potential mechanism and optimize the luminescence properties. The degradation rate gradually slows down with the decreasing environmental humidity indicating that water plays a key role in the degradation. Moreover, we take the other option with 100% humidity at different temperatures for rapid degradation. In the rapid degradation, the luminescence of SLAN is quenched quickly and the phase and micro structure change obviously, with the phosphor being bleached. The host turns into NH_3, Al_2 O_3, Sr_3 Al_2(OH)_(12) and LiAl_2(OH)_7 finally. It is further confirmed that the rapid degradation occurs with the help of water and the phosphor is oxidized during this process.Wenxia Li Zhen Song Dianpeng Cui Zhiguo Xia Quanlin Liu 2018Journal of Rare Earths2018,36,4:4
8A numerical study on the effect of tidal flat's slope on tidal dynamics in the Xiangshan Bay, China显示文摘The Xiangshan Bay is a semi-enclosed and narrow bay, which is characterized by large scale tidal flats and has been historically utilized through coastal construction and aquaculture engineering. The hydrodynamic model using the Finite Volume Coastal Ocean Model(FVCOM) was constructed to examine the changes of tidal dynamics due to the variation of tidal flat slopes. According to the model results, a decreased slope of a tidal flat would amplify the M2 tidal amplitude and delay the M2 tidal phase in the inner harbor, due to an increased tidal prism, and vice versa. The amplitude of the main shallow-water tide M4 would be amplified/dampened in the entire bay due to the changed bottom friction, if the tidal flat's slope were reduced/increased at the Tie inlet. The phase was advanced. The change of a tidal flat's slope at the Tie inlet had greater impacts on tidal amplitude,phase and duration asymmetry, than that at the Xihu inlet. The impact of changes of the tidal flat slope at the Xihu inlet was small and was constrained locally. Changes in the tidal flats' slopes at the Tie and Xihu inlets changed the tidal duration asymmetry, residual current and tidal energy via modulating tides. The ebb dominance decreased when the tidal flat's slope at the Tie inlet was changed. Decreased/increased ebb dominance occurred when the tidal flat's slope was reduced/increased at the Xihu inlet. The residual current and tidal energy density was amplified/dampened and more/less tidal energy was dissipated, with reduced/increased slope at both of the inlets. The findings in this study are instructive to coastal engineering and estuarine management.LI Li YE Taoyan HE Zhiguo XIA Yuezhang 2018Acta Oceanologica Sinica2018,37,9:3
9Comprehensive test stand for high-intensity cyclotron development显示文摘A comprehensive test stand for high-intensity cyclotron development,a 10 MeV 430 μA cyclotron,has been successfully constructed at China Institute of Atomic Energy (CIAE) for the experimental verification of the viability of a 100 MeV high-intensity cyclotron (CYCIAE-100) being constructed at CIAE.The verification includes the overall design technology,detail design and engineering technology for the crucial parts of the machine,e.g.main magnet and beam diagnostics.It will also pave the way for future enhancement of the beam intensity.The test stand consists of a H-ion source,axial injection system,central region,main magnet and coil,RF resonator,stripping extraction,and auxiliary systems,which include the RF power amplifier,high voltage and DC power supplies,electric apparatus,beam diagnostics,control,vacuum,water cooling,pneumatic system,and safety interlock.This paper presents the work regarding the design and sub-system development of the test sand,and the results of the beam commissioning of the machine.ZHANG TianJue LI ZhenGuo CHU ChengJie XING JianSheng GUAN FengPing ZHONG JunQing JI Bin GE Tao YIN ZhiGuo HOU ShiGang PAN GaoFeng YAO HongJuan LU YinLong WANG ZhenHui WU LongCheng LIN Jun JIA XianLu WEI SuMin WEN LiPeng WANG Feng XIA Le CAI HongRu XIE HuaiDong CHEN RongFan ZHANG Yan ZHANG SuPing LIU GengShou ZOU Jian AN ShiZhong YANG JianJun BI YuanJie YANG Fang 2011Chinese Science Bulletin2011,56,3:3
10Glass crystallization making red phosphor for high-power warm white lighting显示文摘Rapid development of solid-state lighting technology requires new materials with highly efficient and stable luminescence,and especially relies on blue light pumped red phosphors for improved light quality.Herein,we discovered an unprecedented red-emitting Mg_(2)AI_(4)Si_(5)0_(18):Eu^(2+)composite phosphor(λex=450 nm,λem=620 nm)via the crystallization of MgO-AI_(2)O_(3)-Sio_(2) aluminosilicate glass.Combined experimental measurement and first-principles calculations verify that Eu^(2+)dopants insert at the vacant channel of Mg_(2)AI_(4)Si_(5)0_(18)crystal with six-fold coordination responsible for the peculiar red emission.Importantly,the resulting phosphor exhibits high internal/external quantum efficiency of 94.5/70.6%,and stable emission against thermal quenching,which reaches industry production.The maximum luminous flux and luminous efficiency of the constructed laser driven red emitting device reaches as high as 274 Im and 54lm W^(-1),respectively.The combinations of extraordinary optical properties coupled with economically favorable and innovative preparation method indicate,that the Mg_(2)AI_(4)Si_(5)0_(18):Eu^(2+)composite phosphor will provide a significant step towards the development of high-power solid-state lighting.Tao Hu Lixin Ning Yan Gao Jianwei Qiao Enhai Song Zitao Chen Yayun Zhou Jing Wang Maxim S.Molokeev Xiaoxing Ke Zhiguo Xia Qinyuan Zhang 2021Light(Science & Applications)2021,10,4:2
11Solution‑Processed Transparent Conducting Electrodes for Flexible Organic Solar Cells with 16.61% Efficiency显示文摘Nonfullerene organic solar cells(OSCs)have achieved breakthrough with pushing the efficiency exceeding 17%.While this shed light on OSC commercialization,high-performance flexible OSCs should be pursued through solution manufacturing.Herein,we report a solution-processed flexible OSC based on a transparent conducting PEDOT:PSS anode doped with trifluoromethanesulfonic acid(CF3SO3H).Through a low-concentration and low-temperature CF3SO3H doping,the conducting polymer anodes exhibited a main sheet resistance of 35Ωsq−1(minimum value:32Ωsq−1),a raised work function(≈5.0 eV),a superior wettability,and a high electrical stability.The high work function minimized the energy level mismatch among the anodes,hole-transporting layers and electron-donors of the active layers,thereby leading to an enhanced carrier extraction.The solution-processed flexible OSCs yielded a record-high efficiency of 16.41%(maximum value:16.61%).Besides,the flexible OSCs afforded the 1000 cyclic bending tests at the radius of 1.5 mm and the long-time thermal treatments at 85°C,demonstrating a high flexibility and a good thermal stability.Juanyong Wan Yonggao Xia Junfeng Fang Zhiguo Zhang Bingang Xu Jinzhao Wang Ling Ai Weijie Song Kwun Nam Hui Xi Fan Yongfang Li 2021Nano-Micro Letters2021,13,3:2
12Research on the Angular Glint of Targets in the Near-Zone显示文摘This paper presents a method to analyze and calculate the angular glint of targets. By parting the target to very small size cells,using high-frequency approximation,the near-field radar cross section (RCS) is calculated based on the scattering from complex targets and environments (SCTE) system,and the angular glint is calculated by the phase grads. The results show that the angular glint can be calculated exactly in the SCTE system,and this method is correct and efficient. In the near-zone,the far-field theory is not applicable and the angular glint should be calculated by the near-field theory.XIA Yingqing TIAN Huamei DUAN Zhiguo WU Ling XU Penggen 2007Wuhan University Journal of Natural Sciences2007,12,3:2
13miR-150 regulates glucose utilization through targeting GLUT4 in insulin-resistant cardiomyocytes显示文摘MicroRNAs(miRNAs)play an important role in cardiac function and metabolism.However,whether they regulate insulin resistance(IR)of cardiomyocytes remains unclear.The aim of the present study was to shed light on this issue with a focus on miR-150.We found here that miR-150 level was elevated in myocardium of type 2 diabetes mellitus(T2DM)rat model and in insulin-resistant cardiomyocytes induced by high glucose(25 mM)and high insulin(1μM).Deregulation of miR-150 downregulated the protein and mRNA levels of glucose transporter 4(GLUT4)as assessed by western blot,real-time polymerase chain reaction(qPCR),and immunofluorescence assays.Overexpression of miR-150 inhibited glucose utilization in cardiomyocytes as detected by 2-deoxyglucose transport and glucose consumption assays.In contrast,knockdown of miR-150 significantly increased glucose uptake in cardiomyocytes.Moreover,GLUT4 translocation was increased after transfection of miR-150 inhibitor(AMO-150).Collectively,miR-150 reduced glucose utilization by directly decreasing the expression and translocation of GLUT4 in the cardiomyocytes with IR and therefore might be a new therapeutic target for metabolic diseases such as T2DM.Jin Ju Dan Xiao Nannan Shen Tong Zhou Hui Che Xia Li Shuqian Zhang Justine Nyakango Mokembo Nabanit Kumar Jha Seth Mikaye Monayo Zhiguo Wang Yong Zhang 2020Acta Biochimica et Biophysica Sinica2020,52,10:2
14Ultrasound-assisted preparation and charaterization of anionic sufactant modified montmorillonites显示文摘Zhang Zepeng Liao Libing Xia Zhiguo 0,,04:1
15Preparation of Incompact Strontium Aluminate Phosphors显示文摘The incompact long afterglow pigment SrAl2O4: Eu, Dy was synthesized by ceramics technology.The agglomerated starting raw material had little effect on the synthesis of SrA12O4 matrix through solid-state reaction method,but the shrinkage and densification was retarded greatly by the agglomerated powder by the formation of large and extensive pore network.The sintering mechanism is surface diffusion ( without flux B2O3 ) and grain boundary diffusion (with B2O3 as flux)respectively, and the as-prepared long afterglow pigment glows in the dark for over 4000 min.Luo Xixian Xiao Zhiguo Xia Wei Cao Wanghe 2004Journal of Rare Earths2004,22,z1:1
16Synthesis, Structure, and Thermally Stable Luminescence of Eu2 + -Doped Ba2 Ln ( Bo3 ) 2 CI ( Ln = Y, Gd and Lu) Host Compounds显示文摘Xia Zhiguo Wang Xiaoming Wang Yingxia 2011Inorg Chem2011,50,10:1
17Solid-state reaction preparation and photoluminescence properties of Na,2 Ba6 ( Si2 07 ) ( SiO4 ) 2 : Eu2 + phosphors显示文摘Shi Pinglu Xia Zhiguo 2014Mater Res Bu112014,49,1:1
18Growth and Characterization of Single-Crystal Y2O3:Eu Nanobelts Prepared with a Simple Technique显示文摘Xia Li Qiang Li Zhiguo Xia et at 2006Crystal Growth & Design2006,6,:1
19Thermodynamic and Kinetic Analysis of Low-temperature Thermal Reduction of Graphene Oxide显示文摘The thermodynamic state and kinetic process of low-temperature deoxygenation reaction of graphene oxide(GO) have been investigated for better understanding on the reduction mechanism by using Differential Scanning Calorimetry(DSC), Thermogravimetry-Mass Spectrometry(TG-MS), and X-ray Photoelectron Spectroscopy(XPS). It is found that the thermal reduction reaction of GO is exothermic with degassing of CO_2, CO and H_2O. Graphene is thermodynamically more stable than GO. The deoxygenation reaction of GO is kinetically controlled and the activation energy for GO is calculated to be 167 k J/mol(1.73 e V/atom).Kuibo Yin Haitao Li Yidong Xia Hengchang Bi Jun Sun Zhiguo Liu Litao Sun 2011Nano-Micro Letters2011,3,1:1
20显示文摘Zhou Jun Xia Zhiguo You Hongpeng 2013Journal of Lu- minescence2013,135,:1
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