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| 1 | The material and biological characteristics of osteoinductive calcium phosphate ceramics显示文摘The discovery of osteoinductivity of calcium phosphate(Ca-P)ceramics has set an enduring paradigm of conferring biological regenerative activity to materials with carefully designed structural characteristics.The unique phase composition and porous structural features of osteoinductive Ca-P ceramics allow it to interact with signaling molecules and extracellular matrices in the host system,creating a local environment conducive to new bone formation.Mounting evidence now indicate that the osteoinductive activity of Ca-P ceramics is linked to their physicochemical and three-dimensional structural properties.Inspired by this conceptual breakthrough,many laboratories have shown that other materials can be also enticed to join the rank of tissue-inducing biomaterials,and besides the bones,other tissues such as cartilage,nerves and blood vessels were also regenerated with the assistance of biomaterials.Here,we give a brief historical recount about the discovery of the osteoinductivity of Ca-P ceramics,summarize the underlying material factors and biological characteristics,and discuss the mechanism of osteoinduction concerning protein adsorption,and the interaction with different types of cells,and the involvement of the vascular and immune systems. | Zhurong Tang Xiangfeng Li Yanfei Tan Hongsong Fan Xingdong Zhang | 2018 | Regenerative Biomaterials2018，5，1： | 20 |
| 2 | Progress of the key materials for organic solar cells显示文摘Organic solar cells have attracted academic and industrial interests due to the advantages like lightweight,flexibility and roll-to-roll fabrication.Nowadays,18%power conversion efficiency has been achieved in the state-of-the-art organic solar cells.The recent rapid progress in organic solar cells relies on the continuously emerging new materials and device fabrication technologies,and the deep understanding on film morphology,molecular packing and device physics.Donor and acceptor materials are the key materials for organic solar cells since they determine the device performance.The past 25 years have witnessed an odyssey in developing high-performance donors and acceptors.In this review,we focus on those star materials and milestone work,and introduce the molecular structure evolution of key materials.These key materials include homopolymer donors,D-A copolymer donors,A-D-A small molecular donors,fullerene acceptors and nonfullerene acceptors.At last,we outlook the challenges and very important directions in key materials development. | Yang Tong Zuo Xiao Xiaoyan Du Chuantian Zuo Yuelong Li Menglan Lv Yongbo Yuan Chenyi Yi Feng Hao Yong Hua Ting Lei Qianqian Lin Kuan Sun Dewei Zhao Chunhui Duan Xiangfeng Shao Wei Li Hin-Lap Yip Zhengguo Xiaol Bin Zhang Qingzhen Bian Yuanhang Cheng Shengjian Liu Ming Cheng Zhiwen Jin Shangfeng Yang Liming Ding | 2020 | Science China Chemistry2020，63，6： | 15 |
| 3 | A retrospective comparison of the modified tension band technique and the parallel titanium cannulated lag screw technique in transverse patella fracture显示文摘 | Wang Chengxue Tan Lei Qi Baochang Hou Xiangfeng Huang Yulong Zhang Haipeng Yu Tiecheng | 2014 | Chinese Journal of Traumatology2014，17，4： | 14 |
| 4 | Friction Characteristics of Impregnated and Non-Impregnated Graphite against Cemented Carbide under Water Lubrication显示文摘The friction behavior of resin-impregnated and non-impregnated graphite sliding against a cemented carbide in dry, oil, and water environments using a ring–ring configuration was investigated. Friction coefficients were recorded at various speeds. The results showed that the impregnated graphite exhibited much better friction properties under water or oil lubrication than non-impregnated graphite, and the impregnated graphite could remain in the stable friction regime under high pressure × velocity(pv).Based on scanning electron microscopy and Raman spectroscopy analyses, the different characteristics between impregnated and non-impregnated graphite were able to be attributed to the structure of the graphite and wettability of the lubricants. | Gaolong Zhang Ying Liu Fei Guo Xiangfeng Liu Yuming Wang | 2017 | Journal of Materials Science & Technology2017，33，10： | 8 |
| 5 | Turnover and loss of nitrogenous compounds during composting of food wastes显示文摘Few people have so far explored into the research of the dynamics of various nitrogenous compounds(including water-soluble nitrogen)in composting of food wastes.This study aimed to investigate the solid-phase nitrogen,water-soluble nitrogen,nitrogen loss together with ammonia volatilization in the process of food wastes composting.A laboratory scale static aerobic reactor in the experiment was employed in the composting process of a synthetic food waste,in which sawdust was used as the litter amendment.In the experiment,oxygen was supplied by continuous forced ventilation for 15 days.The results have shown that the concentrations of total nitrogen and organic nitrogen decrease significantly in the composting process,whereasNH_(4)^(+)-N concentration increases together with little fluctuation in NO_(3)^(-)-N.After composting,the total content of the water-soluble nitrogen compounds in the compost greatly increased,the total nitrogen loss amounted to 50% of the initial nitrogen,mainly attributed to ammonia volatilization.56.7% of the total ammonia volatilization occurred in the middle and late composting of the thermophilic stage.This suggested that the control at the middle and late composting of thermophilic stage is the key to nitrogen loss in the food waste compost. | Yanmei YANG Xiangfeng ZHANG Zhifeng YANG Beidou XI Hongliang LIU | 2008 | Frontiers of Environmental Science & Engineering2008，2，2： | 8 |
| 6 | Adsorption behaviors of Cd^(2+) on Fe_2O_3/MnO_2 and the effects of coexisting ions under alkaline conditions显示文摘This study describes the adsorption features of cadmium on Fe2O3 and MnO2 in alkaline saline conditions. The adsorption reached equilibrium in 6 hours under alkaline conditions. The absorption of cadmium on Fe2O3 and MnO2 was consistent with Freundlich absorption isotherms, and the corresponding adsorption capacities were 16.3 and 16.7 mg·g-1, respectively. Moreover, the adsorption quantity of cadmium on Fe2O3 and MnO2 rose with increas-ing pH from acidic to neutral, and reached the maximum at pH= 9. The coexisting chlorides reduced the adsorption capacity of Fe2O3 and MnO2. The influence intensities of different cations follow the order of CaCl2>>KCl>NaCl. However, the influence of sodium salts on the capacities of Fe2O3 and MnO2 to adsorb cadmium appeared more complicated: the relatively low concentrations of sodium salts could reduce the adsorption capacity; with increasing concentrations of sodium salts, e.g. NaCl and NaNO3. the adsorption capacity decreased continually. Moreover, due to the competition adsorption and precipitation effects, the adsorption capabilities of Na2CO3, NaH2PO4 and Na2HSO4 could also be reduced and cadmium concentrations in the solution were reduced as well. | WANG Zuwei ZENG Xiangfeng YU Xiaoman ZHANG Hui LI Zhaojiang JIN Di | 2010 | Chinese Journal Of Geochemistry2010，29，2： | 6 |
| 7 | A Local Cluster of Omicron Variant COVID-19 Likely Caused by Internationally Mailed Document——Beijing Municipality,China,January 2022显示文摘On January 15,2022,a 26 years old female(Case A)went to a sampling site for coronavirus disease 2019(COVID-19)testing due to excessive fatigue and fever for two days.This patient preliminarily tested positive for severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)using a quantitative real-time reverse transcription polymerase chain reaction(qRT-PCR)method. | Daitao Zhang Shuangsheng Wu Zhenyong Ren Ying Sun Xiangfeng Dou Zhaomin Feng Fu Li Yi Tian Shujuan Cui Baiwei Liu Bing Lyu Xiaoli Wang Feng Liu Lina Jin Chu Jiang Lina Tian Zhenjiang Xin Zhichao Liang Lei Jia Quanyi Wang Yang Pan Peng Yang | 2022 | China CDC weekly2022，4，14： | 6 |
| 8 | Wear behavior of WC-Ni sliding against graphite under water lubrication显示文摘Wear of hard materials in contact with softer materials is a neglected area of research. However, we observed considerable wear phenomenon at a hard WC-Ni surface sliding over soft graphite under water lubrication. The influences of applied load and the application history on the wear of surface were addressed in our experimental design. Wear of both graphite and WC-Ni surfaces increased with a greater applied load and repeated sliding. The topographies of the worn surfaces showed clear micro-scratches on the hard WC-Ni surface. Scanning electron microscopy and X-ray photoelectron spectroscopy analyses revealed that the abrasive wear of the WC-Ni surface could be attributed to hard WC particles embedded in the graphite surface. These hard particles were formed by shearing of sharp WC-Ni asperities under certain conditions and intrinsic defects of the WC-Ni surface could accelerate this wear process. | Gaolong Zhang Ying Liu Yuechang Wang Fei Guo Xiangfeng Liu Yuming Wang | 2017 | Journal of Materials Science & Technology2017，33，11： | 5 |
| 9 | Intrauterine growth restriction alters growth performance, plasma hormones,and small intestinal microbial communities in growing-finishing pigs显示文摘Background: The interaction of the gut microbiota with key metabolic and physiological processes may be associated with poor growth outcomes in animals born with intrauterine growth restriction(IUGR).Results: Growth performance, plasma hormone concentrations, and intestinal microbiota composition were analyzed in IUGR pigs and in normal birth weight(NBW) pigs when the NBW pigs reached 25, 50, and 100 kg of body weight(BW). Compared to NBW pigs, IUGR pigs had lower initial, weaned, and final BW, and lower average daily gain and average daily feed intake in all the considered time points. In the 25 kg BW group, IUGR pigs had higher concentrations of plasma ghrelin and pancreatic polypeptide(PP), but lower insulin concentration than NBW pigs, while the situation was reversed in the 50 kg BW group. As compared to NBW pigs, IUGR pigs had higher microbial alpha diversity in the jejunum and ileum;in the 50 and 100 kg BW groups, IUGR pigs had higher Firmicutes abundance but lower Proteobacteria abundance in the jejunum, and lower Lactobacillus abundance in the jejunum and ileum;in the 25 kg BW group, IUGR pigs showed higher unclassified Ruminococcaceae abundance in the ileum;and in 25 and 50 kg BW groups, IUGR pigs showed lower Ochrobactrum abundance in the jejunum.Spearman's correlation revealed that Lactobacillus was negatively correlated with growth performance, while unclassified Ruminococcaceae was positively correlated. Predictive metagenomic analysis detected significantly different expression of genes in the intestinal microbiota between IUGR and NBW pigs, suggesting different metabolic capabilities between the two groups.Conclusions: Growing-finishing IUGR pigs showed lower growth performance, higher microbial alpha diversity, and differences in plasma hormone concentrations compared to NBW pigs. Alterations in the abundance of Firmicutes,Proteobacteria, Ruminococcaceae, Lactobacillus, and Ochrobactrum in the small intestine may be associated with IUGR, and may therefore serve as a future target for gut microbiota intervention in growing-finishing IUGR pigs. | Liang Xiong Jinming You Wanghong Zhang Qian Zhu Francois Blachier Yulong Yin Xiangfeng Kong | 2021 | Journal of Animal Science and Biotechnology2021，12，1： | 5 |
| 10 | Pt3Ag alloy wavy nanowires as highly effective electrocatalysts for ethanol oxidation reaction显示文摘Direct ethanol fuel cell(DEFC)has received tremendous research interests because of the more convenient storage and transportation of ethanol vs.compressed hydrogen.However,the electrocatalytic ethanol oxidation reaction typically requires precious metal catalysts and is plagued with relatively high over potential and low mass activity.Here we report the synthesis of Pt3Ag alloy wavy nanowires via a particle attachment mechanism in a facile solvothermal process.Transmission microscopy studies and elemental analyses show highly wavy nanowire structures with an average diameter of 4.6±1.0 nm and uniform Pt3Ag alloy formation.Electrocatalytic studies demonstrate that the resulting alloy nanowires can function as highly effective electrocatalysts for ethanol oxidation reactions(EOR)with ultrahigh specific activity of 28.0 mA/cm^2 and mass activity of 6.1 A/mg,far exceeding that of the commercial Pt/carbon samples(1.10 A/mg).The improved electrocatalytic activity may be partly attributed to partial electron transfer from Ag to Pt in the Pt3Ag alloy,which weakens CO binding and the CO poisoning effect.The one-dimensional nanowire morphology also contributes to favorable charge transport properties that are critical for extracting charge from catalytic active sites to external circuits.The chronoamperometry studies demonstrate considerably improved stability for long term operation compared with the commercial Pt/C samples,making the Pt3Ag wavy nanowires an attractive electrocatalyst for EOR. | Xiaoyang Fu Chengzhang Wan Aixin Zhang Zipeng Zhao Huaixun Huyan Xiaoqing Pan Shuaijing Du Xiangfeng Duan Yu Huang | 2020 | Nano Research2020，13，5： | 5 |
| 11 | Research progress on hydrothermal dissolution and hydrolysis of lignocellulose and lignocellulosic waste显示文摘 | Yan ZHAO Wenjing LU Jiajun CHEN Xiangfeng ZHANG Hongtao WANG | 2014 | Frontiers of Environmental Science & Engineering2014，8，2： | 5 |
| 12 | Acetone Sensors Based on La^(3+) Doped ZnO Nano-rods Prepared by Solvothermal Method显示文摘La3+ doped ZnO nano-rods with different doping concentration were prepared via solvothermal method.The doped ZnO nano-rods were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM),respectively.The effect of La3+ doping on the gas-sensing properties was investigated.The results revealed that the sensor based on 6 mol% La3+ doped ZnO nano-rods exhibited high response to dilute acetone,and the responses to 0.01×10-6 acetone reached 2.4 when operating at 425 ℃.The response time and the recovery time for 0.01×10-6 acetone were only 16 and 3 s,respectively. | Xiangfeng Chu Xiaohua Zhu Yongping Dong Xiutao Ge Shouquan Zhang Wenqi Sun | 2012 | Journal of Materials Science & Technology2012，28，3： | 4 |
| 13 | Formaldehyde Sensing Properties of SnO–Graphene Composites Prepared via Hydrothermal Method显示文摘Graphene(G) was prepared by reducing graphene oxide(GO) with hydrazine hydrate. SnO –graphene composites with different amounts of graphene were prepared via hydrothermal method. SnO –G composites were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM). The effects of the graphene content in the composites and the hydrothermal temperature on the gas-sensing responses of the materials to formaldehyde vapor were investigated. The gas-sensing selectivity of the sensor based on Sn O–1% G(100 °C, 10 h) composite to five kinds of gases(1000 × 10-6) was also studied. The results revealed that the sensor based on Sn O–1% G(100 °C, 10 h) exhibited high response to formaldehyde vapor when the operating temperature of the sensor was 133 °C and the response to 0.001 × 10-6formaldehyde attained 3.9. The response time and recovery time for 0.001 × 10-6formaldehyde were 24 and 12 s, respectively. | Xiangfeng Chu Xiaohua Zhu Yongping Dong Wangbing Zhang Linshan Bai | 2015 | Journal of Materials Science & Technology2015，31，9： | 4 |
| 14 | Recombinant osteopontin attenuates hyperoxia-induced acute lung injury through inhibiting nuclear factor kappa B and matrix metalloproteinases 2 and 9显示文摘 | Zhang Xiangfeng Liu Fen Zhu Guangfa Wang Zengzhi | 2014 | Chinese Medical Journal2014，，23： | 4 |
| 15 | Ultrafast growth of large single crystals of monolayer WS2 and WSe2显示文摘Monolayer transition metal dichalcogenides(TMDs)have attracted considerable attention as atomically thin semiconductors for the ultimate transistor scaling.For practical applications in integrated electronics,large monolayer single crystals are essential for ensuring consistent electronic properties and high device yield.The TMDs available today are generally obtained by mechanical exfoliation or chemical vapor deposition(CVD)growth,but are often of mixed layer thickness,limited single crystal domain size or have very slow growth rate.Scalable and rapid growth of large single crystals of monolayer TMDs requires maximization of lateral growth rate while completely suppressing the vertical growth,which represents a fundamental synthetic challenge and has motivated considerable efforts.Herein we report a modified CVD approach with controllable reverse flow for rapid growth of large domain single crystals of monolayer TMDs.With the use of reverse flow to precisely control the chemical vapor supply in the thermal CVD process,we can effectively prevent undesired nucleation before reaching optimum growth temperature and enable rapid nucleation and growth of monolayer TMD single crystals at a high temperature that is difficult to attain with use of a typical thermal CVD process.We show that monolayer single crystals of 450μm lateral size can be prepared in 10 s,with the highest lateral growth rate up to 45μm/s.Electronic characterization shows that the resulting monolayer WSe2 material exhibits excellent electronic properties with carrier mobility up to 90 cm^2 V^-1 s^-1,comparable to that of the best exfoliated monolayers.Our study provides a robust pathway for rapid growth of high-quality TMD single crystals. | Zhengwei Zhang Peng Chen Xiangdong Yang Yuan Liu Huifang Ma Jia Li Bei Zhao Jun Luo Xidong Duan Xiangfeng Duan | 2020 | National Science Review2020，7，4： | 4 |
| 16 | Three-dimensional graphene membrane cathode for high energy density rechargeable lithium-air batteries in ambient conditions显示文摘锂空气电池在活动电源供应的高精力密度为应用吸引了重要兴趣,还对有在周围的条件下面的稳定的骑车性能的可充电的 Li 空气电池的发展有可观的挑战。这里,我们报导一三维(3D ) 恐水病的 graphene 膜作为为高效 Li 空气电池的潮湿抵抗的阴极。 3D graphene 膜为有效电荷运输展示一个高度互连的 graphene 网络,为氧和电解质离子的有效散开的高度多孔的结构,为绝缘的分泌物产品的高能力存储的一个大特定的表面区域,并且为 O 2/H2 O 选择。当延迟时,这些隧道便于 O 2 ingression 潮湿散开并且保证优秀控告 / 解除骑车在周围的条件下面的稳定性。膜能因此与非凡的性能启用柔韧的 Li 空气电池,包括超过 5,700 mAh/g 的一个最大的阴极能力并且优秀再装骑车行为(> 在 140 mAh/g 的 2,000 个周期,并且 > 在 1,400 mAh/g 的 100 个周期) 。graphene 膜空气阴极能交付 100,000-300,000 mAh/g 的一个一生能力,比得上典型的锂离子电池阴极的。有显著地改进的单个费用能力和 Li 离子电池的比得上那些的一生能力的 Li 空气电池的稳定的操作可以为为未来其他的吸引人的高精力密度存储提供活动电源供应。这些电池可以提供长得多的电池生活并且极大地减少再装频率。 | Xing Zhong Benjamin Papandrea Yuxi Xu Zhaoyang Lin Hua Zhang Yuan Liu Yu Huang Xiangfeng Duan | 2017 | Nano Research2017，10，2： | 4 |
| 17 | Removal of chromium (Ⅵ) from aqueous solutions using quaternized chitosan microspheres显示文摘In this study, quaternized chitosan microspheres(QCMS) were prepared and its Cr(VI) removal potential was investigated. Batch experiments were conducted to examine kinetics, adsorption isotherm, p H effect,and thermodynamic parameters. Equilibrium was attained within 50 min and maximum removal of 97.34%was achieved under the optimum conditions at p H 5. Adsorption data for Cr(VI) uptake by the QCMS were analyzed according to Langmuir, Freundlich, and Temkin adsorption models. The maximum uptake of Cr(VI)was 39.1 mg·g^(-1). Thermodynamic parameters for the adsorption system were determinated at 293 K, 303 K,313 K and 323 K.(ΔH° = 16.08 k J·mol^(-1);ΔG° =- 5.84 to- 8.08 k J·mol^(-1)and ΔS° = 74.81 J·K^(-1)·mol^(-1)).So the positive values of both ΔH° and ΔS° suggest an endothermic reaction and increase in randomness at the solid–liquid interface during the adsorption. ΔG° values obtained were negative indicating a spontaneous adsorption process. The kinetic process was described by a pseudo-second-order rate equation very well. The results of the present study indicated that the QCMS could be considered as a potential adsorbent for Cr(VI) in aqueous solutions. | Chao Hua Runhu Zhang Fang Bai Ping Lu Xiangfeng Liang | 2017 | Chinese Journal of Chemical Engineering2017，25，2： | 4 |
| 18 | A Silicon Monoxide Lithium-Ion Battery Anode with Ultrahigh Areal Capacity显示文摘Silicon monoxide(SiO)is an attractive anode material for next-generation lithium-ion batteries for its ultra-high theoretical capacity of 2680 mAh g−1.The studies to date have been limited to electrodes with a rela-tively low mass loading(<3.5 mg cm^(−2)),which has seriously restricted the areal capacity and its potential in practical devices.Maximizing areal capacity with such high-capacity materials is critical for capitalizing their potential in practi-cal technologies.Herein,we report a monolithic three-dimensional(3D)large-sheet holey gra-phene framework/SiO(LHGF/SiO)composite for high-mass-loading electrode.By specifically using large-sheet holey graphene building blocks,we construct LHGF with super-elasticity and exceptional mechanical robustness,which is essential for accommodating the large volume change of SiO and ensuring the structure integrity even at ultrahigh mass loading.Additionally,the 3D porous graphene network structure in LHGF ensures excellent electron and ion transport.By systematically tailoring microstructure design,we show the LHGF/SiO anode with a mass loading of 44 mg cm^(−2)delivers a high areal capacity of 35.4 mAh cm^(−2)at a current of 8.8 mA cm^(−2)and retains a capacity of 10.6 mAh cm^(−2)at 17.6 mA cm^(−2),greatly exceeding those of the state-of-the-art commercial or research devices.Furthermore,we show an LHGF/SiO anode with an ultra-high mass loading of 94 mg cm^(−2)delivers an unprecedented areal capacity up to 140.8 mAh cm^(−2).The achievement of such high areal capacities marks a critical step toward realizing the full potential of high-capacity alloy-type electrode materials in practical lithium-ion batteries. | Jiang Zhong Tao Wang Lei Wang Lele Peng Shubin Fu Meng Zhang Jinhui Cao Xiang Xu Junfei Liang Huilong Fei Xidong Duan Bingan Lu Yiliu Wang Jian Zhu Xiangfeng Duan | 2022 | Nano-Micro Letters2022，14，3： | 4 |
| 19 | A survey analysis of heavy metals bio-accumulation in internal organs of sea shell animals affected by the sustainable pollution of antifouling paints used for ships anchored at some domestic maritime spaces显示文摘Some samples of sea shell animals stuck and multiplied on the bottom (beneath the seawater) coated with antifouling paints were collected at some domestic maritime spaces, and the content of heavy metals was detected through Inductively Coupled Plasma-Mass Spectroscopy. Meanwhile, comparison with sea shell animals was made on market for edible use. It shows that the content of heavy metals in internal organs of these marine animals is very high due to the large amount of copper and zinc con- tained in the antifouling paints, and this also does severely harm to sea environment and ecology. To study and develop the novel antifouling paints without copper(I) oxide is an imperative task which brooks no delay. | WANG JunLian WANG FengQi YU Jie ZHUANG yan ZHOU XiangFeng ZHANG XiaoBin PENG BiXian | 2008 | Chinese Science Bulletin2008，53，16： | 3 |
| 20 | Differential Expressing of Centromere Protein CenpG in Breast Cancer显示文摘Using indirect immunofluorescence (IIF), an anti-centromere protein CenpG-serum was verified. Western blot of the protein extracts of 31 samples of breast cancer tissues and their normal (not cancerous ) tissues a little far away from them in the same individuals showed that, in the majority of the tests (71%), centromere protein CenpG over expressed in breast cancer tissues. And moreover, a kind of protein component whose molecular weight is 43 kd, and which can be recognized by anti-CenpG serum was found in two of the cancer samples. The results suggested that CenpG (together whith it, there may be other relative components),which has been found and named recently, may be related to cancer,and its differential expressing is probably related to malignant cell proliferation. | 梁前进 Lu Xiangfeng Cheng Xiaolei Zhang Huanxiang He Dacheng WANG Yongchao | 2002 | High Technology Letters2002，8，1： | 3 |
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