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| 1 | Advanced characterization of pores and fractures in coals by nuclear magnetic resonance and X-ray computed tomography显示文摘This paper demonstrates capabilities of low-field nuclear magnetic resonance (NMR) and microfocus X-ray computed tomography (μCT) in advanced, nondestructive, and quantitative characterization of pore types, producible porosity, pore structure, and spatial disposition of pore-fractures in coals. Results show that the NMR transverse relaxation time (T2) at 0.5–2.5, 20–50, and >100 ms correspond to pores of <0.1 μm, >0.1 μm, and fractures, respectively. A much higher T2 spectrum peak reflects a much better development of pores (or fractures) corresponding to the T2, and vice versa. Three basic components in coals, i.e., the pores (or fractures), coal matrix, and minerals have their distinctive range of CT numbers. Among these, the CT number of pores is commonly less than 600 HU. The producible porosity, which is a determination of permeability, can be calculated by T2 cutoff value (T2C) of coal NMR. The coal pore structure can be efficiently estimated by the newly proposed 'T2C based model'. Finally, μCT scan was proven capable of modeling and spatial visualization of pores and fractures. | YAO YanBin, LIU DaMeng, CAI YiDong & LI JunQian School of Energy Resources, China University of Geosciences, Beijing 100083, China | 2010 | Science China Earth Sciences2010，53，6： | 61 |
| 2 | Progress in the study of mercury methylation and demethylation in aquatic environments显示文摘Mercury(Hg) and its compounds are a class of highly toxic and pervasive pollutants.During the biogeochemical cycling of Hg,methylmercury(MeHg),a potent neurotoxin,can be produced and subsequently bioaccumulated along the food chain in aquatic ecosystems.MeHg is among the most widespread contaminants that pose severe health risks to humans and wildlife.Methylation of inorganic mercury to MeHg and demethylation of MeHg are the two most important processes in the cycling of MeHg,determining the levels of MeHg in aquatic ecosystems.This paper reviews recent progress on the study of Hg methylation and demethylation in aquatic environments,focusing on the following three areas:(1) sites and pathways of Hg methylation and demethylation,(2) bioavailability of Hg species for methylation and demethylation,and(3) application of isotope addition techniques in quantitatively estimating the net production of MeHg. | LI YanBin CAI Yong | 2013 | Chinese Science Bulletin2013，58，2： | 8 |
| 3 | Mobility of toxic metals in sediments: Assessing methods and controlling factors显示文摘Metals and metalloids(termed as metals in this article)are important constituent elements of the earth’s crust.A number of metals,if present in excess,are toxic to organisms and therefore they are usually defined as toxic metals.Toxic metals in the environment can be divided into two groups:those | Yanbin Li Yong Cai | 2015 | Journal of Environmental Sciences2015，27，5： | 7 |
| 4 | Knockdown of S-phase Kinase-associated Protein-2 Expression in MCF-7 Inhibits Cell Growth and Enhances the Cytotoxic Effects of Epirubicin显示文摘S 阶段联系 kinase 的 protein-2 (Skp2 ) 在调停 ubiquitin 的解朊作用起一个关键作用,导致房间从的前进一对一个 proliferative 状态静止。Skp2 完了在许多肿瘤表示了并且相反地与 p27 表示相关,包括乳癌。在这研究,我们使用了小介入的 RNA (siRNAs ) 在人的乳癌 MCF-7 细胞禁止 Skp2 表示并且如果击倒,从而由 RNA 干扰(RNAi ) Skp2 调查将禁止乳癌细胞生长并且在 MCF-7 细胞上影响 epirubicin 的效果。三 Skp2 siRNA 构造被重新结合并且短暂地 transfected 人乳癌 MCF-7 房间。Skp2 的下面规定被反向的抄写聚合酶链反应和蛋白质印迹分析证实。我们证明 Skp2 siRNA 转染减少了 Skp2 蛋白质并且在 MCF-7 房间导致了 p27 蛋白质的累积。Skp2 siRNA 在 vitro 并且在 vivo 禁止了房间增长。由 RNAi 的 Skp2 击倒在 vitro 的增加的细胞的 apoptosis。有治疗进一步与 epirubicin 跟随的 Skp2 siRNA 的治疗禁止了癌症房间线的增长,与 epirubicin 跟随的控制 siRNA 相比。因此, Skp2 击倒由 RNAi 的表示禁止乳癌细胞生长并且提高 epirubicin 的效果。Skp2 的调停 siRNA 的基因 silencing 能是为在规定下面的 p27 的抑制的新奇癌症基因治疗。 | Lichun SUN Li CAI Yan YU Qingwei MENG Xuesong CHENG Yanbin ZHAO Guangjie SUI Fengmin ZHANG | 2007 | Acta Biochimica et Biophysica Sinica2007，39，12： | 6 |
| 5 | Pore structure of selected Chinese coals with heating and pressurization treatments显示文摘Pore structure of Chinese coals with heating and pressurization treatments was studied using small angle X-ray scattering(SAXS),N2adsorption/desorption isotherms and scanning electron microscope(SEM).SAXS was performed for some samples after heat treatment at seven elevated temperatures from 25 to 250°C at 0 MPa and for other samples with hydrostatic pressure treatment at 0,5,10,15 and 20 MPa at the room temperature.The results show that N2adsorption isotherm together with SAXS could be a comprehensive method to evaluate the pore shape and the pore size distribution:the pore shapes are generally spherical for low rank coal and they are mainly ellipsoidal for high rank coal.All these measurements were then interpreted using the fractal theory to reveal relationship between surface fractals and coal rank,and the evolution of surface fractals under heating and pressurization treatments.The results show that surface fractal dimension(Ds)changes with different treating temperature and pressure and maximum vitrinite reflectance(Ro,m).Especially in the bituminous stage,Ds shows an increasing trend with Ro,m under varied temperatures.Moreover,Ds shows an increasing trend with increasing temperature before 200°C,and a decreasing trend after 200°C.Furthermore,the results show that Ds has a more complex relationship with Ro,m under varied treating temperature than that under varied treating pressure. | CAI YiDong LIU DaMeng PAN ZheJun YAO YanBin LI JunQian QIU YongKai | 2014 | Science China Earth Sciences2014，57，7： | 5 |
| 6 | Angiotensin Ⅱ suppresses adriamycin-induced apoptosis through activation of phosphatidylinositol 3-kinase/Akt signaling in human breast cancer cells显示文摘 | Yanbin Zhao Xuesong Chen Li Cai Yanmei Yang Guangjie Sui Jin Wu | 2008 | Acta Biochimica et Biophysica Sinica2008，40，4： | 5 |
| 7 | A microfluidic biosensor for rapid detection of Salmonella typhimurium based on magnetic separation,enzymatic catalysis and electrochemical impedance analysis显示文摘Rapid screening of foodborne pathogens is of great significance to ensure food safety.A microfluidic biosensor based on immunomagnetic separation,enzyme catalysis and electrochemical impedance analysis was developed for rapid and sensitive detection of S.typhimurium.First,the bacterial sample,the magnetic nanoparticles(MNPs)modified with capture antibodies,and the enzymatic probes modified with detection antibodies and glucose oxidase(GOx)were simultaneously injected into the microfluidic chip,followed by mixing and incubation to form MNP-bacteria-probe sandwich complexes.Then,glucose with high impedance was injected into the chip and catalyzed by the GOx on the complexes into hydrogen peroxide with high impedance and gluconic acid with low impedance,which was finally measured using the low-cost interdigitated microelectrode and the electrochemical impedance analyzer to determine the target bacteria.Under the optimal conditions,this biosensor could quantitatively detect S.typhimurium at the concentrations from 1.6×10^(2) CFU/m L to 1.6×10^(6) CFU/m L in 1 h with the low detection limit of 73 CFU/m L.Besides,this biosensor was demonstrated with good feasibility for practical applications by detecting the S.typhimurium spiked chicken meat samples. | Yingjia Liu Dong Jiang Siyuan Wang Gaozhe Cai Li Xue Yanbin Li Ming Liao Jianhan Lin | 2022 | Chinese Chemical Letters2022，33，6： | 3 |
| 8 | Pore structure and its impact on CH 4 adsorption capacity and flow capability of bituminous and subbituminous coals from Northeast China显示文摘 | Yidong Cai Dameng Liu Zhejun Pan Yanbin Yao Junqian Li Yongkai Qiu | 2013 | Fuel2013，，： | 2 |
| 9 | Supramolecular Hydrogels of Indole-Capped Short Peptides as Vaccine Adjuvants显示文摘 | Zhongyan Wang Yanbin Cai Linan Yi Jie Gao Zhimou Yang | 2017 | Chinese Journal of Chemistry2017，35，7： | 2 |
| 10 | Organelle-inspired supramolecular nanomedicine to precisely abolish liver tumor growth and metastasis显示文摘Organelles are responsible for the efficient storage and transport of substances in living systems.A myriad of extracellular vesicles(EVs)acts as a bridge to exchange signaling molecules in cell-cell communication,and the highly dynamic tubulins and actins contribute to efficient intracellular substance transport.The inexhaustible cues of natural cargo delivery by organelles inspire researchers to explore the construction of biomimetic architectures for“smart”delivery carriers.Herein,we report a 10-hydroxycamptothecin(HCPT)-peptide conjugate HpYss that simulates the artificial EV-to-filament transformation process for precise liver cancer therapy.Under the sequential stimulus of extracellular alkaline phosphatase(ALP)and intracellular glutathione(GSH),HpYss proceeds via tandem self-assembly with a morphological transformation from nanoparticles to nanofibers.The experimental phase diagram elucidates the influence of ALP and GSH contents on the self-assembled nanostructures.In addition,the dynamic transformation of organelle-mimetic architectures that are formed by HpYss in HepG2 cells enables the efficient delivery of the anticancer drug HCPT to the nucleus,and the size-shape change from extracellular nanoparticles(50-100 nm)to intracellular nanofibers(4-9 nm)is verified to be of key importance for nuclear delivery.Nuclear targeting of HpYss amplifies apoptosis,thus significantly enhancing the inhibitory effect of HCPT(>10-fold)to HepG2 cells.Benefitting from the spatiotemporally controlled nanostructures,HpYss exhibited deep penetration,enhanced accumulation,and long-term retention in multicellular spheroid and xenograft models,potently abolishing liver tumor growth and preventing lung metastasis.We envision that our organelle-mimicking delivery strategy provides a novel paradigm for designing nanomedicine to cancer therapy. | Jie Zhan Yuhan Wang Shaodan Ma Qin Qin Ling Wang Yanbin Cai Zhimou Yang | 2022 | Bioactive Materials2022，7，3： | 1 |
| 11 | Geological controls on prediction of coalbed methane of No. 3 coal seam in Southern Qinshui Basin, North China显示文摘 | Yidong Cai Dameng Liu Yanbin Yao Junqian Li Yongkai Qiu | 2011 | International Journal of Coal Geology2011，，2： | 1 |
| 12 | Special issue on toxic metal pollution显示文摘Metals and metalloids are an integral part of the Earth’s crust.Some of these elements are of great concern due to their high toxicity and threat to humans,wildlife,and the ecosystem.For simplicity,the term toxic metals is adopted to represnt | CAI Yong LI YanBin | 2013 | Chinese Science Bulletin2013，58，2： | 1 |
| 13 | Dynamic permeability change during coalbed methane production and its controlling factors显示文摘 | Chen Yaxin Liu Dameng Yao Yanbin Cai Yidong Chen Longwei | 2015 | Journal of Natural Gas Science and Engineering2015，25，： | 1 |
| 14 | Steganalysis of MSU Stego Video Based on Block Matching of Interframe Collusion and Motion Detection显示文摘MSU Stego Video is a public video steganographic tool, which has strong robustness and is regarded as a real video steganographic tool. In order to increase the detection rate, this paper proposes a new steganoalysis method against MSU, which uses the chessboard character of MSU embedded video, proposes a down-sample block-based collusion method to estimate the original frame and checks the chessboard mode of the different frame between tested frame and estimated frame to detect MSU steganographic evidences. To reduce the error introduced by severe movement of the video content, a method that abandons severe motion blocks from detecting is proposed. The experiment results show that the false negative rate of the proposed algorithm is lower than 5%, and the false positive rate is lower than 2%. Our algorithm has significantly better performance than existing algorithms. Especially to the video that has fast motion, the algorithm has more remarkable performance. | REN Yanzhen WANG Mingjie ZHAO Yanbin WANG Lina CAI Tingting | 2012 | Wuhan University Journal of Natural Sciences2012，17，5： | 0 |
| 15 | Imaging cellular distribution of fluorescent supramolecular nanofibers显示文摘In this study, we used the 4-nitro-2,1,3-benzoxadiazole(NBD) as an aromatic capping group for a peptide to construct the supramolecular nanofibers. Taking the advantage of the fluorescence property of NBD, we could directly observe the cellular distribution of the self-assembled nanofibers. We found that the distributions of the nanofibers of NBD-FFETIGGY are different in four mammalian cells and two plant cells. The nanofibers are mainly located at the surface of two mammalian cells and one plant cell, while in the intracellular space of other cells. Different distributions of nanofibers lead to different protein binding patterns of the nanofibers in two different cell lines. We believe that a useful and versatile platform has been offered to the image cellular distribution of nanofibers, which can provide useful information to the biological functions of the self-assembled nanostructures. | Jingyu Wang Jing Zheng Yanbin Cai Jinxin Zheng Jie Gao Qingqiu Gong Zhimou Yang | 2016 | Science China Chemistry2016，59，6： | 0 |
| 16 | Synergistic interphase modification with dual electrolyte additives to boost cycle stability of high nickel cathode for all-climate battery显示文摘B-containing electrolyte additives are widely used to enhance the cycle performance at low temperature and the rate capability of lithium-ion batteries by constructing an efficient cathode electrolyte interphase(CEI)to facilitate the rapid Li+migration.Nevertheless,its wide-temperature application has been limited by the instability of B-derived CEI layer at high temperature.Herein,dual electrolyte additives,consisting of lithium tetraborate(Li_(2)TB)and 2,4-difluorobiphenyl(FBP),are proposed to boost the widetemperature performances of LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM)cathode.Theoretical calculation and electrochemical performances analyses indicate that Li_(2)TB and FBP undergo successive decomposition to form a unique dual-layer CEI.FBP acts as a synergistic filming additive to Li_(2)TB,enhancing the hightemperature performance of NCM cathode while preserving the excellent low-temperature cycle stability and the superior rate capability conferred by Li_(2)TB additive.Therefore,the capacity retention of NCM‖Li cells using optimal FBP-Li_(2)TB dual electrolyte additives increases to 100%after 200 cycles at-10℃,99%after 200 cycles at 25℃,and 83%after 100 cycles at 55℃,respectively,much superior to that of base electrolyte(63%/69%/45%).More surprisingly,galvanostatic c ha rge/discharge experiments at different temperatures reveal that NCM‖Li cells using FBP-Li_(2)TB additives can operate at temperatures ranging from-40℃to 60℃.This synergistic interphase modification utilizing dual electrolyte additives to construct a unique dual-layer CEI adaptive to a wide temperature range,provides valuable insights to the practical applications of NCM cathodes for all-climate batteries. | Zhangyating Xie Jiarong He Zhiyong Xia Qinqin Cai Ziyuan Tang Jie Cai Yili Chen Xiaoqing Li Yingzhu Fan Lidan Xing Yanbin Shen Weishan Li | 2023 | Journal of Energy Chemistry2023，，11： | 0 |
| 17 | Unveiling the parasitic-reaction-driven surface reconstruction in Ni-rich cathode and the electrochemical role of Li_(2)CO_(3)显示文摘Nickel-rich transition-metal oxides are widely regarded as promising cathode materials for high-energydensity lithium-ion batteries for emerging electric vehicles. However, achieving high energy density in Ni-rich cathodes is accompanied by substantial safety and cycle-life obstacles. The major issues of Ni-rich cathodes at high working potentials are originated from the unstable cathode-electrolyte interface, while the underlying mechanism of parasitic reactions towards surface reconstructions of cathode materials is not well understood. In this work, we controlled the Li_(2)CO_(3) impurity content on LiNi_(0.83)Mn_(0.1)Co_(0.07)O_(2) cathodes using air, tank-air, and O_(2) synthesis environments. Home-built high-precision leakage current and on-line electrochemical mass spectroscopy experiments verify that Li_(2)CO_(3) impurity is a significant promoter of parasitic reactions on Ni-rich cathodes. The rate of parasitic reactions is strongly correlated to Li_(2)CO_(3) content and severe performance deterioration of Ni83 cathodes.The post-mortem characterizations via high-resolution transition electron microscope and X-ray photoelectron spectroscopy depth profiles reveal that parasitic reactions promote more Ni reduction and O deficiency and even rock-salt phase transformation at the surface of cathode materials. Our observation suggests that surface reconstructions have a strong affiliation to parasitic reactions that create chemically acidic environment to etch away the lattice oxygen and offer the electrical charge to reduce the valence state of transition metal. Thus, this study advances our understanding on surface reconstructions of Nirich cathodes and prepares us for searching for rational strategies. | Jiyu Cai Zhenzhen Yang Xinwei Zhou Bingning Wang Ana Suzana Jianming Bai Chen Liao Yuzi Liu Yanbin Chen Shunlin Song Xuequan Zhang Li Wang Xiangming He Xiangbo Meng Niloofar Karami Baasit Ali Shaik Sulaiman Natasha A.Chernova Shailesh Upreti Brad Prevel Feng Wang Zonghai Chen | 2023 | Journal of Energy Chemistry2023，，10： | 0 |
| 18 | Mercury transformation processes in nature: Critical knowledge gaps and perspectives for moving forward显示文摘The transformation of mercury(Hg) in the environment plays a vital role in the cycling of Hg and its risk to the ecosystem and human health. Of particular importance are Hg oxidation/reduction and methylation/demethylation processes driven or mediated by the dynamics of light, microorganisms, and organic carbon, among others. Advances in understanding those Hg transformation processes determine our capacity of projecting and mitigating Hg risk. Here, we provide a critical analysis of major knowledge gaps in our understanding of Hg transformation in nature, with perspectives on approaches moving forward. Our analysis focuses on Hg transformation processes in the environment, as well as emerging methodology in exploring these processes. Future avenues for improving the understanding of Hg transformation processes to protect ecosystem and human health are also explored. | Zhiyuan Gao Wang Zheng Yanbin Li Yurong Liu Mengjie Wu Shouying Li Ping Li Guangliang Liu Xuewu Fu Shuxiao Wang Feiyue Wang Yong Cai Xinbin Feng Baohua Gu Huan Zhong Yongguang Yin | 2022 | Journal of Environmental Sciences2022，34，9： | 0 |
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