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| 1 | High precision and efficiency robotic milling of complex parts:Challenges,approaches and trends显示文摘Due to the advantages of large workspace,low cost and the integrated vision/force sensing,robotic milling has become an important way for machining of complex parts.In recent years,many scholars have studied the problems existing in the applications of robotic milling,and lots of results have been made in the dynamics,pose planning,deformation control etc.,which provides theoretical guidance for high precision and high efficiency of robotic milling.From the perspective of complex parts robotic milling,this paper focuses on machining process planning and control techniques including the analysis of the robot-workspace,robot trajectory planning,vibration monitoring and control,deformation monitoring and compensation.As well as the principles of these technologies such as robot stiffness characteristics,dynamic characteristics,chatter mechanisms,and deformation mechanisms.The methods and characteristics related to the theory and technology of robotic milling of complex parts are summarized systematically.The latest research progress and achievements in the relevant fields are reviewed.It is hoped that the challenges,strategies and development related to robotic milling could be clarified through the carding work in this paper,so as to promote the application of related theories and technologies in high efficiency and precision intelligent milling with robot for complex parts. | Zerun ZHU Xiaowei TANG Chen CHEN Fangyu PENG Rong YAN Lin ZHOU Zepeng LI Jiawei WU | 2022 | Chinese Journal of Aeronautics2022，35，2： | 9 |
| 2 | Using thermodynamic parameters to study self-healing and interface properties of crumb rubber modified asphalt based on molecular dynamics simulation显示文摘The thermodynamic property of asphalt binder is changed by the addition of crumb rubber,which in turn influences the self-healing property as well as the cohesion and adhesion within the asphalt-aggregate system.This study investigated the self-healing and interface properties of crumb rubber modified asphalt(CRMA)using thermodynamic parameters based on the molecular simulation approach.The molecular models of CRMA were built with representative structures of the virgin asphalt and the crumb rubber.The aggregate was represented by SiO2 and Al2O3 crystals.The selfhealing capability was evaluated with the thermodynamic parameter wetting time,work of cohesion and diffusivity.The interface properties were evaluated by characterizing the adhesion capability,the debonding potential and the moisture susceptibility of the asphalt-aggregate interface.The self-healing capability of CRMA is found to decrease as the rubber content increases.The asphalt-Al2O3 interface with higher rubber content has stronger adhesion and moisture stability.But the influence of crumb rubber on the interfacial properties of asphalt-SiO2 interface has no statistical significance.Comparing with the interfacial properties of the asphalt-SiO2 interface,the asphalt-Al2O3 interface is found to have a stronger adhesion but a worse moisture susceptibility for its enormous thermodynamic potential for water to displace the asphalt binder. | Dongliang HU Jianzhong PEI Rui LI Jiupeng ZHANG Yanshun JIA Zepeng FAN | 2020 | Frontiers of Structural and Civil Engineering2020，14，1： | 5 |
| 3 | Ultracompact dual-mode waveguide crossing based on subwavelength multimode-interference couplers显示文摘We propose and experimentally demonstrate a novel ultracompact dual-mode waveguide crossing based on subwavelength multimode-interference couplers for a densely integrated on-chip mode-division multiplexing system.By engineering the lateral-cladding material index and manipulating phase profiles of light at the nanoscale using an improved inverse design method, a subwavelength structure could theoretically realize the identical beat length for both TE_0 and TE1, which can reduce the scale of the device greatly. The fabricated device occupied a footprint of only 4.8 μm× 4.8 μm. The measured insertion losses and crosstalks were less than 0.6 d B and-24 d B from 1530 nm to 1590 nm for both TE0 and TE1 modes, respectively. Furthermore, our scheme could also be expandedto design waveguide crossings that support more modes. | WEIJIE CHANG LULUZI LU XINSHU REN DONGYU LI ZEPENG PAN MENGFAN CHENG DEMING LIU MINMING ZHANG | 2018 | Photonics Research2018，6，7： | 4 |
| 4 | Sustainable functional urethral reconstruction:Maximizing early continence recovery in robotic-assisted radical prostatectomy显示文摘Objective:To evaluate the safety profile and short-term functional outcome of sustainable functional urethral reconstruction(SFUR)in robotic-assisted radical prostatectomy(RARP).Methods:One hundred and sixty-two consecutive prostate cancer patients who underwent RARP were retrospectively analyzed,in which 53 had undergone SFUR while the other 109 had undergone conventional RARP procedures.Immediate,2-week,1-month and 3-month continence recovery and other perioperative data were compared to evaluate short-term surgical and functional outcome.Results:The median age was 68 and 67 years in the experimental group and control group,respectively(pZ0.206),with a median prostate-specific antigen(PSA)of 13.6 ng/mL(interquartile range[IQR],8.46e27.32 ng/mL)in the experimental group and 13.84 ng/mL(IQR,9.12e26.80 ng/mL)in control group(pZ0.846).Immediate,2-week,1-month and 3-month continence recovery rates between the groups were 34.0%vs.3.7%,50.9%vs.14.7%,62.3%vs.27.5%,and 79.2%vs.63.3%(all p<0.05).The morphological changes made by the new reconstruction technique were maintained on magnetic resonance imaging(MRI)3 months postoperatively.Nerve-sparing procedures and adoption of the new reconstruction technique were significantly relevant to continence recovery on logistics regression model(p<0.001).Conclusions:SFUR is a safe and easy-to-handle modification that may contribute to early continence return for RARP.Long-term follow-up and prospective studies are required to further evaluate its value in postoperative quality-of-life improvement. | Zepeng Jia Yifan Chang Yan Wang Jing Li Min Qu Feng Zhu Huan Chen Bijun Lian Meimian Hua Yinghao Sun Xu Gao | 2021 | Asian Journal of Urology2021，8，1： | 2 |
| 5 | Inhibition of p53 and/or AKT as a new therapeutic approach specifically targeting ALT cancers显示文摘While the majority of all human cancers court teract telomere shortening by expressing telomerase,-15%of all cancers maintain telomere length by a telomerase?independent mechanism known as alternative lengthening of telomeres(ALT).Here,we show that high load of intrinsic DNA damage is present in ALT cancer cells,leading to apoptosis stress by activating p53-independent,but JNK/c-IVIyc-dependent apoptotic pathway.Notably,ALT cells expressing wild-type p53 show much lower apoptosis than p53-deficient ALT cells.Mechanistically,we find that intrinsic DNA damage in ALT cells induces low level of p53 that is insufficient to initiate the transcription of apoptosis-related genes,but is sufficient to stimulate the expression of key components of mTORC2(mTOR and Rictor),which in turn leads to phosphorylation of AKT.Activated AKT(p-AKT)thereby stimulates downstream anti-apoptotic events.Therefore,p53 and AKT are the key factors that suppress sponta?neous apoptosis in ALT cells.Indeed,inhibition of p53 or AKT selectively induces rapid death of ALT cells in vitro,and p53 inhibitor severely suppresses the growth of ALT-cell xenograft tumors in mice.These findings reveal a previously unrecognized function of p53 in antiapoptosis and identify that the inhibition of p53 or AKT has a potential as therapeutics for specifically targeting ALT cancers. | Yuanlong Ge Shu Wu Zepeng Zhang Xiaocui Li Feng Li Siyu Yan Haiying Liu Junjiu Huang Yong Zhao | 2019 | Protein & Cell2019，10，11： | 2 |
| 6 | Fast Distance Protection Scheme for Wind Farm Transmission Lines Considering R-L and Bergeron Models显示文摘The distributed capacitance of the line becomes larger as the scale of wind farms,the transmission voltage level,and the transmission distance increase.Hence,the error of the traditional time-domain distance protection scheme based on the R-L model,which ignores the distributed capacitance of the line,becomes unacceptable.Therefore,the error of the time-domain fault location method based on the R-L model,especially the maximum error range,is theoretically analyzed in this paper.On this basis,a novel fault location method based on the RL and Bergeron models is proposed.Then,a fast time-domain distance protection scheme is designed.In the proposed scheme,the error in the fitting calculation is used to construct a weight matrix,and an algorithm for solving the time-domain differential equations is designed to improve the calculation speed and stability.Compared with the traditional frequency-domain distance protection scheme,the proposed scheme is independent of the power supply characteristics;thus,it is suitable for wind farm transmission lines.In addition,compared with the traditional method based on the R-L model,the proposed scheme effectively avoids the negative influence of the distributed capacitance of the line,which significantly improves the operating speed.Different types of faults are simulated by PSCAD/EMTDC to verify the effectiveness and superiority of the proposed scheme. | Zepeng Hu Bin Li Yuping Zheng Tonghua Wu Jiawei He Bin Yao Yaru Sheng Wei Dai Xindong Li | 2023 | Journal of Modern Power Systems and Clean Energy2023，11，3： | 2 |
| 7 | On-chip cyclic-AWG-based 12 × 12 silicon wavelength routing switches with minimized port-to-port insertion loss fluctuation显示文摘With the rapidly increasing bandwidth requirements of optical communication networks, compact and low-cost large-scale optical switches become necessary. Silicon photonics is a promising technology due to its small footprint, cost competitiveness, and high bandwidth density. In this paper, we demonstrate a 12 × 12 silicon wavelength routing switch employing cascaded arrayed waveguide gratings(AWGs) connected by a silicon waveguide interconnection network on a single chip. We optimize the connecting strategy of the crossing structure to reduce the switch's footprint. We develop an algorithm based on minimum standard deviation to minimize the port-toport insertion loss(IL) fluctuation of the switch globally. The simulated port-to-port IL fluctuation decreases by about 3 dB compared with that of the conventional one. The average measured port-to-port IL is 13.03 dB, with a standard deviation of 0.78 dB and a fluctuation of 2.39 dB. The device can be used for wide applications in core networks and data centers. | ZEPENG PAN SONGNIAN FU LULUZI LU DONGYU LI WEIJIE CHANG DEMING LIU MINMING ZHANG | 2018 | Photonics Research2018，6，5： | 2 |
| 8 | Effect of Pre-Anthesis Drought Hardening on Post-Anthesis Physiological Characteristics,Yield and WUE in Winter Wheat显示文摘A drought event can cause yield loss or entire crops to fail.In order to study the effects of continuous drought on physiological characteristics,yield,and water use efficiency(WUE)of winter wheat(Triticum aestivum L.),the variety“Zhoumai 22”was grown in controlled water conditions of the pot-planted winter wheat under a mobile rainout shelter.Foot planting and safe wintering were used to evaluate,winter wheat under different drought conditions,including light,moderate and severe drought at the jointing,heading,and filling stages.The soil water content was controlled at 60–70%,50–60%,or 40–50%of field capacity.Experimental trials included 3 pre-anthesis drought hardening,3 three-stage continuous drought,and 1 test control conditions.Under drought stress conditions,winter wheat leaf water potential,soil plant analysis development(SPAD),photosynthesis parameters,and yield declined due to pre-anthesis drought hardening.And the degree of decline:continuous drought>pre-anthesis drought hardening.Changes in the post-anthesis photosynthetic capacity of winter wheat were mainly related to the pre-anthesis drought level,rather than post-anthesis rehydration.The threshold of non-stomata limiting factors caused by photosynthesis at the filling stage is 40–50%FC,while comprehensive yield and WUE affected,the yield in severe drought treatments was the most significant,B3C3 and B3C3G3 decreased by 55.68%and 55.88%,respectively.Pre-anthesis drought was the main reason for the decreased crop yield.Thus,severe drought should be avoided during planting,while pre-anthesis light drought is a suitable choice for watersaving and crop production,as proper pre-anthesis drought hardening(60–70%FC)is feasible and effective. | Ruitao Lou Daoxi Li Yanbin Li Zepeng Bian Yanan Zhu | 2021 | Phyton-International Journal of Experimental Botany2021，90，1： | 2 |
| 9 | Geological and geochemical characteristics of the Baogudi Carlintype gold district(Southwest Guizhou, China) and their geological implications显示文摘The newly discovered Baogudi gold district is located in the southwestern Guizhou Province,China,where there are numerous Carlin-type gold deposits.To better understand the geological and geochemical characteristics of the Baogudi gold district,we carried out petrographic observations,elemental analyses,and fluid inclusion and isotopic composition studies.We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou.Three mineralization stages,namely,the sedimentation diagenesis,hydrothermal(main-ore and late-ore substages),and supergene stages,were identified based on field and petrographic observations.The main-ore and late-ore stages correspond to Au and Sb mineralization,respectively,which are similar to typical Carlin-type mineralization.The mass transfer associated with alteration and mineralization shows that a significant amount of Au,As,Sb,Hg,Tl,Mo,and S were added to mineralized rocks during the main-ore stage.Remarkably,arsenic,Sb,and S were added to the mineralized rocks during the late-ore stage.Element migration indicates that the sulfidation process was responsible for ore formation.Four types of fluid inclusions were identified in ore-related quartz and fluorite.The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4±N2system,with medium to low temperatures(180–260℃)and low salinity(0–9.08%NaCl equivalent).The late-ore stage fluids featured H2O–NaCl±CO2±CH4,with low temperature(120–200℃)and low salinity(0–7.48%Na Cl equivalent).The temperature,salinity,and CO2and CH4concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage.The calculated δ^13C,d D,and δ^18O values of the ore-forming fluids range from-14.3 to-7.0%,-76 to-55.7%,and 4.5–15.0%,respectively.Late-ore-stage stibnite had δ^34S values ranging from-0.6 to 1.9%.These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids,with minor contributions from strata.Collectively,the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou.It is likely that the Baogudi gold district,together with other Carlin-type gold deposits in southwestern Guizhou,was formed in response to a single widespread metallogenic event. | Songtao Li Yong Xia Jianzhong Liu Zhuojun Xie Qinping Tan Yimeng Zhao Minghua Meng Lijin Tan Rong Nie Zepeng Wang Guanghong Zhou Haiyan Guo | 2019 | Acta Geochimica2019，38，4： | 1 |
| 10 | Constructing heterostructures of ZIF-67 derived C,N doped Co_(2)P and Ti_(2)VC_(2)T_(x)MXene for enhanced OER显示文摘Oxygen evolution reaction(OER)is central to technologies such as electrochemical water splitting,and developing efficient and low-cost non-precious metal electrocatalysts for OER is of great significance to reducing cell voltage and developing hydrogen production by electrochemical water splitting.Herein,we prepared a carbon,nitrogen co-doped porous Co_(2)P derived from the metal-organic framework(ZIF-67),which is anchored on bimetallic MXene nanosheets(named MX@MOF-Co_(2)P).It was used as the OER catalyst and exhibited great electrocatalytic performance with very small overpotentials(246 mV at 10 mA^(-2)and 407 mV at 200 mA cm^(-2))as well as ultralow Tafel slope(28.18 mV dec^(-1)).Combining charac-terizations and theoretical calculations,it was found that the remarkable performance was from follows:the obtained MX@MOF-Co_(2)P inherited the porous structure of the pristine MOF with a large number of open active sites;carbon and nitrogen doping also modulated the electronic structure of the active center;the synergistic effect between cobalt phosphide and MXenes booted the electronic transfer.This work represents a promising strategy for the development of non-precious metal catalysts derived from metal-organic frameworks to achieve efficient energy conversion. | Jinzhou Li Chao Chen Zepeng Lv Wansen Ma Meng Wang Qian Li Jie Dang | 2023 | Journal of Materials Science & Technology2023，，14： | 1 |
| 11 | Influence mechanism of machining angles on force induced error and their selection in five axis bullnose end milling显示文摘In the machining of complicated surfaces,the cutters with large length/diameter ratios are used widely and the deformation of the machining system is one of the principal error sources.During the process planning stage,the cutting direction angle,the cutter lead and tilt angles are usually optimized to minimize the force induced error.It may lead to a low machining efficiency for bullnose end mills,as the material removal rates are different largely for different machining angles.In this paper,the influence mechanism of the machining angles on the force induced error is studied based on the models of the instantaneous cutting force when the cutter flute traveling through the cutting contact point and the stiffness of the machining system.In order to evaluate the machining angles,the force induced error/efficiency indicator(FEI)is defined as the division of the force induced error and the equal volume sphere of the removed material.FEI is dimensionless,with the lower FEI,the lower force induced error and the higher machining efficiency.For optimal selection of the machining angles,the critical FEI is calculated with the constraint of force induced error and the desired material removal rate,and the critical FEI separate the set of the machining angles into two subsets.After the feed rate scheduling process,the machining angles in the optimal subset would have higher machining accuracy and efficiency,while the machining angles in the other subset have lower machining accuracy and efficiency.Through the machining experiment of five axis machining and freeform surface machining,the effectiveness and superiority of the proposed FEI method is verified with a bullnose end mill,which can improve the machining efficiency with the constraint of force induced error. | Zerun ZHU Fangyu PENG Rong YAN Zepeng LI Jiawei WU Xiaowei TANG Chen CHEN | 2020 | Chinese Journal of Aeronautics2020，33，12： | 1 |
| 12 | Synthesis of ZnS nanocrystals withcontrollable structure and morphology and their photoluminescence property 显示文摘 | Zepeng Li Bingbing Liu Xianglin Li | 2007 | Nanotechnology2007，18，： | 1 |
| 13 | Structure-guided manipulation of the regioselectivity of the cyclosporine A hydroxylase CYP-sb21 from Sebekia benihana显示文摘The cytochrome P450 enzyme CYP-sb21 from the rare actinomycete Sebekia benihana is capable of hydroxylating the immunosuppressive drug molecule cyclosporine A(CsA)primarily at the 4th N-methyl leucine(MeLeu4),giving rise toγ-hydroxy-N-methyl-L-Leu4-CsA(CsA-4-OH).This oxidative modification of CsA leads to dramatically reduced immunosuppressive activity while retaining the hair growth-promoting side-effect,thus demonstrating great application potential in both pharmaceutical and cosmetic industries.However,this P450 enzyme also hydroxylates CsA at the unwanted position of the 9th N-methyl leucine(MeLeu9),indicating that the regioselectivity needs to be improved for the development of CsA-4-OH into a commercial hair growth stimulator.Herein,we report the crystal structure of CYP-sb21 in its substrate-free form at 1.85Å.Together with sequence and 3D structure comparisons,Autodock-based substrate docking,molecular dynamics(MD)simulation,and site-directed mutagenesis,we identified a number of key residues including R294,E264,and M179 that can improve catalytic efficiency or change the regioselectivity of CYP-sb21 towards CsA,setting the stage for better enzymatic preparation of CsA-4-OH.This study also provides new insights into the substrate recognition and binding mechanism of P450 enzymes that accommodate bulky substrates. | Fengwei Li Li Ma Xingwang Zhang Jingfei Chen Feifei Qi Yinyue Huang Zepeng Qu Lishan Yao Wei Zhang Eung-Soo Kim Shengying Li | 2020 | Synthetic and Systems Biotechnology2020，5，3： | 1 |
| 14 | Decoration of C_(60) nanorods with nickel and their magnetic properties显示文摘We studied the coating of C60 nanorods with nickel by electroless plating method and investigated their magnetic properties. The morphology and structure of the nickel layer coated on C60 nanorods were characterized by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and Raman spectroscopy. The coated nickel is in the form of nano-sized crystals and becomes a continuous layer as reaction time increases. The hysteresis loop shows a super paramagnetic characteristic similar to that of nanometer-sized nickel particle. These results suggest that the average size of nickel particles on C60 rods is below 10 nm. Our study has shown that electroless plating is an efficient and simple method for coating C60 nanorods with nickel. | CHEN Ao LIU BingBing HOU YuanYuan WEN GeHui LIU DeDi LU ShuangChen LI ZePeng LI XiangLin ZOU YongGang ZOU Bo LI DongMei CUI Tian ZOU GuangTian | 2009 | Chinese Science Bulletin2009，54，14： | 1 |
| 15 | Super enhancers targeting ZBTB16 in osteogenesis protect against osteoporosis显示文摘As the major cell precursors in osteogenesis, mesenchymal stem cells(MSCs) are indispensable for bone homeostasis and development. However, the primary mechanisms regulating osteogenic differentiation are controversial. Composed of multiple constituent enhancers, super enhancers(SEs) are powerful cis-regulatory elements that identify genes that ensure sequential differentiation. The present study demonstrated that SEs were indispensable for MSC osteogenesis and involved in osteoporosis development. Through integrated analysis, we identified the most common SE-targeted and osteoporosis-related osteogenic gene,ZBTB16. ZBTB16, positively regulated by SEs, promoted MSC osteogenesis but was expressed at lower levels in osteoporosis.Mechanistically, SEs recruited bromodomain containing 4(BRD4) at the site of ZBTB16, which then bound to RNA polymerase IIassociated protein 2(RPAP2) that transported RNA polymerase Ⅱ(POL Ⅱ) into the nucleus. The subsequent synergistic regulation of POL Ⅱ carboxyterminal domain(CTD) phosphorylation by BRD4 and RPAP2 initiated ZBTB16 transcriptional elongation, which facilitated MSC osteogenesis via the key osteogenic transcription factor SP7. Bone-targeting ZBTB16 overexpression had a therapeutic effect on the decreased bone density and remodeling capacity of Brd4^(fl/fl)Prx1-cre mice and osteoporosis(OP) models.Therefore, our study shows that SEs orchestrate the osteogenesis of MSCs by targeting ZBTB16 expression, which provides an attractive focus and therapeutic target for osteoporosis. | Wenhui Yu Zhongyu Xie Jinteng Li Jiajie Lin Zepeng Su Yunshu Che Feng Ye Zhaoqiang Zhang Peitao Xu Yipeng Zeng Xiaojun Xu Zhikun Li Pei Feng Rujia Mi Yanfeng Wu Huiyong Shen | 2023 | Bone Research2023，11，3： | 1 |
| 16 | Effects of Multi-Stage Continuous Drought on Photosynthetic Characteristics, Yield and Water Use Efficiency of Winter Wheat显示文摘A drought event can cause entire crops to fail or yield loss.In order to study the effects of continuous drought on photosynthetic characteristics,yield,and water use efficiency(WUE)of winter wheat(Triticum aestivum L.),the winter wheat variety“Aikang 58”was selected as test material with controlling the water of the pot-planted winter wheat under a mobile rainout shelter.Based on foot planting and safe wintering,winter wheat was evaluated under different drought conditions,including light,moderate and severe drought at the jointing(B),heading(C),and filling(G)stages.The soil water content was controlled in a range of 60%to 70%,50%to 60%,and 40%to 50%of the field capacity,respectively.In the experiment,there were 9 single-stage droughts,3 three-stage droughts,and 1 test control(totaling 13 trials).The results are as follows:Under a single-stage drought,the change of net photosynthetic rate(Pn)and stomatal conductance(Gs)have similar trends,and they both decrease significantly with the severity of the drought.Under three-stage continuous droughts,the change curve of Gs shows a constant downward trend;the change curve of Pn showed a“valley shape,”and the minimum value of Pn appeared at the heading stage.All droughts will reduce the yield of winter wheat.Under the three-stage continuous drought conditions,except for light drought,moderate drought and severe drought will cause significant yield reduction,mainly due to lack of water at the jointing and heading stages.Continuous drought will reduce the WUE,and the difference will reach a significant level under moderate and severe drought.The present results suggested that when water resources are scarce,it is a better irrigation model to save water and achieve high grain yield by applying appropriate water stress(60%–70%FC)during the critical growth period of winter wheat. | Daoxi Li Ruitao Lou Yanbin Li Zepeng Bian Ya’nan Zhu | 2020 | Phyton-International Journal of Experimental Botany2020，89，3： | 1 |
| 17 | Kinetic Limits of Graphite Anode for Fast‑Charging Lithium‑Ion Batteries显示文摘Fast-charging lithium-ion batteries are highly required,especially in reducing the mileage anxiety of the widespread electric vehicles.One of the biggest bottlenecks lies in the sluggish kinetics of the Li^(+)intercalation into the graphite anode;slow intercalation will lead to lithium metal plating,severe side reactions,and safety concerns.The premise to solve these problems is to fully understand the reaction pathways and rate-determining steps of graphite during fast Li^(+)intercalation.Herein,we compare the Li^(+)diffusion through the graphite particle,interface,and electrode,uncover the structure of the lithiated graphite at high current densities,and correlate them with the reaction kinetics and electrochemical performances.It is found that the rate-determining steps are highly dependent on the particle size,interphase property,and electrode configuration.Insufficient Li^(+)diffusion leads to high polarization,incomplete intercalation,and the coexistence of several staging structures.Interfacial Li^(+)diffusion and electrode transportation are the main rate-determining steps if the particle size is less than 10μm.The former is highly dependent on the electrolyte chemistry and can be enhanced by constructing a fluorinated interphase.Our findings enrich the understanding of the graphite structural evolution during rapid Li^(+)intercalation,decipher the bottleneck for the sluggish reaction kinetics,and provide strategic guidelines to boost the fast-charging performance of graphite anode. | Suting Weng Gaojing Yang Simeng Zhang Xiaozhi Liu Xiao Zhang Zepeng Liu Mengyan Cao Mehmet Nurullah Ateş Yejing Li Liquan Chen Zhaoxiang Wang Xuefeng Wang | 2023 | Nano-Micro Letters2023，15，11： | 1 |
| 18 | Localized-domains staging structure and evolution in lithiated graphite显示文摘Intercalation provides to the host materials a means for controlled variation of many physical/chemical properties and dominates the reactions in metal‐ion batteries.Of particular interest is the graphite intercalation compounds with intriguing staging structures,which however are still unclear,especially in their nanostructure and dynamic transition mechanism.Herein,the nature of the staging structure and evolution of the lithium(Li)‐intercalated graphite was revealed by cryogenic‐transmission electron microscopy and other methods at the nanoscale.The intercalated Li‐ions distribute unevenly,generating local stress and dislocations in the graphitic structure.Each staging compound is found macroscopically ordered but microscopically inhomogeneous,exhibiting a localized‐domains structural model.Our findings uncover the correlation between the long‐range ordered structure and short‐range domains,refresh the insights on the staging structure and transition of Li‐intercalated/deintercalated graphite,and provide effective ways to enhance the reaction kinetic in rechargeable batteries by defect engineering. | Suting Weng Siyuan Wu Zepeng Liu Gaojing Yang Xiaozhi Liu Xiao Zhang Chu Zhang Qiuyan Liu Yao Huang Yejing Li Mehmet NAteş Dong Su Lin Gu Hong Li Liquan Chen Ruijuan Xiao Zhaoxiang Wang Xuefeng Wang | 2023 | Carbon Energy2023，5，1： | 1 |
| 19 | Effect of microbial fermentation on the sensory characteristics and chemical compositions of Chinese sweet tea(Lithocarpus litseifolius(Hance)Chun)显示文摘Sweet tea,which has hundreds of years of use among in Chinese folk,is a traditional herbal tea with pleasant sweetness,bitterness and astringency.In the current study,we used traditional microbial fermentation to improve sensory characteristics of sweet tea,especially for the reduction of bitterness and astringency.The dynamic changes of non-volatile,volatile compounds and microbial community were investigated during microbial fermentation.The contents of polyphenols,flavonoids,soluble sugar,soluble protein,catechins and dihydrochalcones decreased significantly while the tea pigments,free amino acids and gallic acid content inversely increased during microbial fermentation.A total of 61 volatile compounds were identified and quantified in sweet tea,of which 20 key compounds were identified as odor active compounds(OAV),including 3 aldehydes,1 ketone,4 alcohols,9 esters,4 alkenes and 3 other compounds.In addition,eight fungi and four bacteria were considered as core microorganisms,such as Aspergillus,Alternaria,Cladosporium,Epicoccum,Itersonilia,Penicillium,Periconia,Wallemia,Aureimonas,Enterobacter,Klebsiella and Stenotrophomonas,which were significantly correlated with non-volatile compounds and flavor compounds.These results provided theoretical guidance for processing of fermented sweet tea. | Weimin Huang Changyi Zhang Zepeng Gu Cheng Li Zhengfeng Fang Zhen Zeng Zhiqing Zhang Bin Hu Hong Chen Wenjuan Wu Tiqiang Wang Xiguo Lan Yuntao Liu | 2022 | Food Bioscience2022，46，2： | 1 |
| 20 | MIL-101(Cr)-decorated Ti/TiO_(2) anode for electrochemical oxidation of aromatic pollutants from water显示文摘Hydroxyl radicals(·OH) generated on anode play a vital role in electrochemical oxidation(EO) of organic pollutants for water treatment. Inspired by the four-electron oxygen evolution reaction(OER), we supposed an anode-selection strategy to stabilize deeply oxidized states(*O and*OOH) which are beneficial to generating·OH. To verify the hypothesis, a candidate anode component(MIL-101(Cr), a well-known metal-organic framework with active variable-valence transition metal centers) was used to coat Ti/TiO_(2)plate to fabricate anodes. Compared to TiO_(2)(101) plane on undecorated anode surface, fast and complete removal of aniline and phenol, and improved energy utilization were achieved on MIL-101(Cr)-coatedTi/TiO_(2)anode. Mechanism investigation, including pollutant degradation pathways, showed the predominate contribution(69.60%–75.13%) of·OH in pollutant mineralization. Density functional theory(DFT)computations indicated Cr site in MIL-101(Cr) was more conducive to stabilizing*O and*OOH, leading to thermodynamical spontaneous generation of·OH. This work opens up an exciting avenue to explore·OH production, and supplies a useful guidance to the development of anode materials for EO process. | Zepeng Zhang Yunyun Li Longzhang Dong Zhonglong Yin Ziqi Tian Weiben Yang Zhen Yang | 2023 | Chinese Chemical Letters2023，34，2： | 0 |
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