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1Petrogenesis of Late Cretaceous Jiangla'angzong I-Type Granite in Central Lhasa Terrane, Tibet, China: Constraints from Whole-Rock Geochemistry, Zircon U-Pb Geochronology, and Sr-Nd-Pb-Hf Isotopes显示文摘The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean ^(206) Pb/^(238) U age of 86±1 Ma(mean square weighted deviation=0.37), which is in accordance with the muscovite Ar-Ar age(85±1 Ma) of Cu-Au ore-bearing skarns and the zircon U-Pb age(84±1 Ma) of adamellite. This suggests that the Jiangla'angzong magmatism and Cu–Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO_2(65.10–70.91 wt%), K_2O(3.44–5.17 wt%), and total K_2O+Na_2O(7.13–8.15 wt%), and moderate contents of A_(12)O_3(14.14–16.45 wt%) and CaO(2.33–4.11 wt%), with a Reitman index(σ43) of 2.18 to 2.33, and A/CNK values of 0.88 to 1.02. The P_2O_5 contents show a negative correlation with SiO_2, whereas Pb contents show a positive correlation with SiO_2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla'angzong granite is a high K calc–alkaline metaluminous I–type granite. It is enriched in light rare earth elements(LREE) and large ion lithofile elements(LILE), and depleted in heavy rare earth elements(HREE) and high field strength elements(HFSE), with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies(δCe=1.00–1.04). The relatively low initial 87 Sr/86 Sr ratios of 0.7106 to 0.7179, positive εHf(t) values of 1.0 to 4.1, and two-stage Hf model ages(TDM2) ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The(^(143) Nd/^(144) Nd)_t values from the Jiangla'angzong granite range from 0.5121 to 0.5123, its εNd(t) values range from-10.17 to-6.10, its(^(206) Pb/^(204) Pb)_t values range from 18.683 to 18.746, its(^(207) Pb/^(204) Pb)_t values range from 15.695 to 15.700, and its(^(208) Pb/^(204) Pb)_t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla'angzong granite was formed during the postcollision extension of the Qiangtang and Lhasa terranes.LIU Hong LI Guangming HUANG Hanxiao CAO Huawen YUAN Qian LI Yingxu OUYANG Yuan LAN Shuangshuang LU Menghong YAN Guoqiang 2018Acta Geologica Sinica(English Edition)2018,92,4:20
2Origin of the Newly Discovered Zhunuo Porphyry Cu-Mo-Au Deposit in the Western Part of the Gangdese Porphyry Copper Belt in the Southern Tibetan Plateau,SW China显示文摘The newly discovered Zhunuo porphyry Cu-Mo-Au deposit is located in the western part of the Gangdese porphyry copper belt in southern Tibet, SW China. The granitoid plutons in the Zhunuo region are composed of quartz diorite porphyry, diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry. The quartz diorite porphyry yielded zircon U-Pb ages of 51.9±0.7 Ma(Eocene) using LA-ICP-MS, whereas the diorite porphyry, granodiorite porphyry, biotite monzogranite and quartz porphyry yielded ages ranging from 16.2±0.2 to 14.0±0.2 Ma(Miocene). CuMo-Au mineralization is mainly hosted in the Miocene granodiorite porphyry. Samples from all granitoid plutons have geochemical compositions consistent with high-K calc-alkaline series magmatism. The samples display highly fractionated light rare-earth element(REE) distributions and heavy REE distributions with weakly negative Eu anomalies on chondrite-normalized REE patterns. The trace element distributions exhibit positive anomalies for large-ion lithophile elements(Rb, K, U, Th and Pb) and negative anomalies for high-field-strength elements(Nb and Ti) relative to primitive mantlenormalized values. The Eocene quartz diorite porphyry yielded εNd(t) values ranging from-3.6 to-5.2,(^(87)Sr/^(86)Sr)i values in the range 0.7046–0.7063 and initial radiogenic Pb isotopic compositions with ranges of 18.599–18.657 ^(206)Pb/^(204)Pb, 15.642–15.673 ^(207)Pb/^(204)Pb and 38.956–39.199 ^(208)Pb/^(204)Pb. In contrast, the Miocene granitoid plutons yielded ε_(Nd)(t) values ranging from-6.1 to-7.3 and(87Sr/86Sr)i values in the range 0.7071–0.7078 with similar Pb isotopic compositions to the Eocene quart diorite. The Sr-Nd-Pb isotopic compositions of the rocks are consistent with formation from magma containing a component of remelted ancient crust. Zircon grains from the Eocene quartz diorite have ε_(Hf)(t) values ranging from-5.2 to +0.9 and two-stage Hf model ages ranging from 1.07 to 1.46 Ga, while zircon grains from the Miocene granitoid plutons have ε_(Hf)(t) values from-9.9 to +4.2 and two-stage Hf model ages ranging from 1.05–1.73 Ga, indicating that the ancient crustal component likely derives from Paleo- to Mesoproterozoic basement. This source is distinct from that of most porphyry Cu-Mo-Au deposits in the eastern part of the Gangdese porphyry copper belt, which likely originated from juvenile crust. We therefore consider melting of ancient crustal basement to have contributed significantly to the formation Miocene porphyry Cu-Mo-Au deposits in the western part of the Gangdese porphyry copper belt.HUANG Yong LI Guangming DING Jun DAI Jie YAN Guoqiang DONG Suiliang HUANG Hanxiao 2017Acta Geologica Sinica(English Edition)2017,91,1:19
3Superabsorbent Fibers for Comfortable Disposable Medical Protective Clothing显示文摘Disposable medical protective clothing for 2019-nCoV mainly consists of stacked layers with nanopore films,polymer coated nonwoven fabrics and melt-blown nonwoven fabrics against anti-microbial and anti-liquid penetration.However,such structures lack moisture permeability and breathability leading to an uncomfortable,stuffy wearing experience.Here,we propose a novel medical protective clothing material with a superabsorbent layer to enhance moisture absorption.Poly(acrylic acid-co-acrylamide)/polyvinyl alcohol superabsorbent fibers(PAAAM/PVA fibers)were prepared via wet spinning.And the superabsorbent composite layer was stacked from PAAAM/PVA fibers,bamboo pulp fibers(BPF)and ethylene-propyl-ene side by side fibers(ESF).The novel disposable medical protective composite fabric was obtained through gluing the superabsorbent layer to the inner surface of strong antistatic polypropylene nonwoven fabric.The resultant composite fabric possesses excellent absorption and retention capacity for sweat,up to 12.3 g/g and 63.8%,and a maximum hygroscopic rate of 1.04 g/h,higher than that of the conventional material(only 0.53 g/h).The moisture permeability of the novel material reached 12,638.5 g/(m^(2) d),which was 307.6%of the conventional material.The novel material can effectively reduce the humidity inside the protective clothing and significantly improve the comfort of medical staff.Lin Yang Hong Liu Shuai Ding Jiawei Wu Yan Zhang Zhongzhen Wang Lili Wei Mingwei Tian Guangming Tao 2020Advanced Fiber Materials2020,2,3:11
4An Optimization Algorithm for Service Composition Based on an Improved FOA显示文摘Large-scale service composition has become an important research topic in Service-Oriented Computing(SOC). Quality of Service(Qo S) has been mostly applied to represent nonfunctional properties of web services and to differentiate those with the same functionality. Many studies for measuring service composition in terms of Qo S have been completed. Among current popular optimization methods for service composition, the exhaustion method has some disadvantages such as requiring a large number of calculations and poor scalability. Similarly,the traditional evolutionary computation method has defects such as exhibiting slow convergence speed and falling easily into the local optimum. In order to solve these problems, an improved optimization algorithm, WS FOA(Web Service composition based on Fruit Fly Optimization Algorithm) for service composition, was proposed, on the basis of the modeling of service composition and the FOA. Simulated experiments demonstrated that the algorithm is effective, feasible, stable, and possesses good global searching ability.Yiwen Zhang Guangming Cui Yan Wang Xing Guo Shu Zhao 2015Tsinghua Science and Technology2015,20,1:11
5Enhanced removal of ethylbenzene from gas streams in biotrickling filters by Tween-20 and Zn(Ⅱ)显示文摘The effects of Tween-20 and Zn(II)on ethylbenzene removal were evaluated using two biotrickling filters(BTFs),BTF1 and BTF2.Only BTF1 was fed with Tween-20 and Zn(II).Results show that ethylbenzene removal decreased from 94%to 69%for BTF1 and from 74%to 54%for BTF2 with increased organic loading from 64.8 to 189.0 g ethylbenzene/(m3·hr)at EBRT of 40 sec.The effect of EBRT(60–15 sec)at a constant ethylbenzene inlet concentration was more significant than that of EBRT(30–10 sec)at a constant organic loading.Biomass accumulation rate within packing media was reduced significantly.Lu Wang Chunping Yang Yan Cheng Jian Huang Haining Yang Guangming Zeng Li Lu Shanying He 2014Journal of Environmental Sciences2014,26,12:8
6Event-triggered Tracking Consensus with Packet Losses and Time-varying Delays显示文摘This paper mainly investigates the event-triggered tracking control for leader-follower multi-agent systems with the problems of packet losses and time-varying delays when both the first-order and the second-order neighbors' information are used. Event-triggered control laws are adopted to reduce the frequency of individual actuation updating under the sampleddata framework for discrete-time agent dynamics. The communication graph is undirected and the loss of data across each communication link occurs at certain probability, which is governed by a Bernoulli process. One numerical example is given to demonstrate the effectiveness of the proposed methods.It is found that the tracking consensus is sped up by using the second-order neighbors' information when packet losses and time-varying delays occur.Mei Yu Chuan Yan Dongmei Xie Guangming Xie 2016IEEE/CAA Journal of Automatica Sinica2016,3,2:7
7Chinese expert consensus on conversion therapy for hepatocellular carcinoma(2021 edition)显示文摘Recent advances in systemic and locoregional treatments for patients with unresectable or advanced hepatocellular carcinoma(HCC)have resulted in improved response rates.This has provided an opportunity for selected patients with initially unresectable HCC to achieve adequate tumor downstaging to undergo surgical resection,a‘conversion therapy’strategy.However,conversion therapy is a new approach to the treatment of HCC and its practice and treatment protocols are still being developed.Review the evidence for conversion therapy in HCC and develop consensus statements to guide clinical practice.Evidence review:Many research centers in China have accumulated significant experience implementing HCC conversion therapy.Preliminary findings and data have shown that conversion therapy represents an important strategy to maximize the survival of selected patients with intermediate stage to advanced HCC;however,there are still many urgent clinical and scientific challenges for this therapeutic strategy and its related fields.In order to summarize and learn from past experience and review current challenges,the Chinese Expert Consensus on Conversion Therapy for Hepatocellular Carcinoma(2021 Edition)was developed based on a review of preliminary experience and clinical data from Chinese and non-Chinese studies in this field and combined with recommendations for clinical practice.Sixteen consensus statements on the implementation of conversion therapy for HCC were developed.The statements generated in this review are based on a review of clinical evidence and real clinical experience and will help guide future progress in conversion therapy for patients with HCC.Hui-Chuan Sun Jian Zhou Zheng Wang Xiufeng Liu Qing Xie Weidong Jia Ming Zhao Xinyu Bi Gong Li Xueli Bai Yuan Ji Li Xu Xiao-Dong Zhu Dousheng Bai Yajin Chen Yongjun Chen Chaoliu Dai Rongping Guo Wenzhi Guo Chunyi Hao Tao Huang Zhiyong Huang Deyu Li Gang Li Tao Li Xiangcheng Li Guangming Li Xiao Liang Jingfeng Liu Fubao Liu Shichun Lu Zheng Lu Weifu Lv Yilei Mao Guoliang Shao Yinghong Shi Tianqiang Song Guang Tan Yunqiang Tang Kaishan Tao Chidan Wan Guangyi Wang Lu Wang Shunxiang Wang Tianfu Wen Baocai Xing Bangde Xiang Sheng Yan Dinghua Yang Guowen Yin Tao Yin Zhenyu Yin Zhengping Yu Bixiang Zhang Jialin Zhang Shuijun Zhang Ti Zhang Yamin Zhang Yubao Zhang Aibin Zhang Haitao Zhao Ledu Zhou Wu Zhang Zhenyu Zhu Shukui Qin Feng Shen Xiujun Cai Gaojun Teng Jianqiang Cai Minshan Chen Qiang Li Lianxin Liu Weilin Wang Tingbo Liang Jiahong Dong Xiaoping Chen Xuehao Wang Shusen Zheng Jia Fan 2022Hepatobiliary Surgery and Nutrition2022,11,2:4
8Multi-sensor optimal weighted fusion incremental Kalman smoother显示文摘In practical applications, the system observation error is widespread. If the observation equation of the system has not been verified or corrected under certain environmental conditions,the unknown system errors and filtering errors will come into being.The incremental observation equation is derived, which can eliminate the unknown observation errors effectively. Furthermore, an incremental Kalman smoother is presented. Moreover, a weighted measurement fusion incremental Kalman smoother applying the globally optimal weighted measurement fusion algorithm is given.The simulation results show their effectiveness and feasibility.SUN Xiaojun YAN Guangming 2018Journal of Systems Engineering and Electronics2018,29,2:4
9Hydroxycalciopyrochlore, A New Mineral Species from Sichuan, China显示文摘Hydroxycalciopyrochlore, ideally(Ca,Na,U,□)2(Nb,Ti)2O6(OH), cubic, is a new mineral species(IMA2011-026) within the pyrochlore supergroup that was found occurring at the Maoniuping mine, Mianning County, Xichang prefecture, Sichuan Province, southwest China. The mineral is found in an alkali feldspar granite rare-earth ore deposit(26–27 Ma). Associated minerals include calcite, barite, celestine, albite, aegirine, aegirine-augite, fluorite, parasite-(Ce), thorite, thorianite, zircon, galena, sphalerite, magnetite, and pyrite. Crystals occur mostly as octahedra, and less often as dodecahedra and tetrahexahedra or combinations thereof. Some occur with an allotriomorphic habit with a thick triangular tabular form. Crystals generally range from 0.1 to 1 mm in size. The mineral is brownishblack, greenish-black and black on fresh sections with a brown streak. The crystal is translucent, and has a greasy lustre on fresh sections. It is metamict without any observed parting or cleavage and with a conchoidal fracture. The Vickers microhardness is 572 kg/mm2(5–6 on the Mohs hardness scale). The density measured by hydrostatic weighing is 5.10(3) g/cm3. The strongest four reflections in the X-ray powder-diffraction pattern [d in(I) hkl] are: 2.9657(100) 2 2 2, 1.8142(34) 0 4 4, 1.5463(21) 2 2 6, 2.5688(18) 0 0 4. The unit-cell parameters are a = 10.381(4), V = 1118.7(7)3, Z = 8. The structure was solved and refined in the space group Fd3m with R = 0.09. The empirical formula is(Ca0.74Na0.58U0.40Ce0.05Fe0.02□0.21)2.00(Nb1.15Ti0.80Ta0.03Al0.01Mg0.01)2.00O6.02 [(OH)1.01F0.09]1.10, on the basis of 2 atoms of B pfu; the simplified formula is(Ca,Na,U,□)2(Nb,Ti)2O6(OH). Type material is deposited in the Geological Museum of China, Beijing, People's Republic of China, catalogue number M11800.YANG Guangming LI Guowu XIONG Ming PAN Baoming YAN Chenjie 2014Acta Geologica Sinica(English Edition)2014,88,3:3
10Biodegradation of 3,5-dimethyl-2,4-dichlorophenol in saline wastewater by newly isolated Penicillium sp.yz11-22N2显示文摘In this study,the performance of 3,5-dimethyl-2,4-dichlorophenol(DCMX) degradation by a screened strain was investigated.18 S r DNA and the neighbor-joining method were used for identification of the isolated strain.The results of phylogenetic analysis and scanning electron micrographs showed that the most probable identity of the screened strain should be Penicillium sp.Growth characteristics of Penicillium sp.and degradation processes of DCMX were examined.Fourier transform infrared spectroscopy of the inoculated DCMX solution was recorded,which supported the capacity of DCMX degradation by the screened Penicillium sp.Under different salinity conditions,the highest growth rate and removal efficiency for DCMX were obtained at p H 6.0.The removal efficiency decreased from 100%to 66% when the DCMX concentration increased from 5 to 60 mg/L,respectively.Using a Box–Behnken design,the maximum DCMX removal efficiency was determined to be 98.4%.With acclimation to salinity,higher removal efficiency could be achieved.The results demonstrate that the screened Penicillium sp.has the capability for degradation of DCMX.Zhou Yan Huijun He Chunping Yang Guangming Zeng Le Luo Panpan Jiao Huiru Li Li Lu 2017Journal of Environmental Sciences2017,29,7:3
11Preparation and electrochemical property of CMC/MWCNT composite using ionic liquid as solvent显示文摘Carboxymethyl cellulose sodium(CMC)/multi-walled carbon nanotube(MWCNT) composite was prepared by dissolving CMC with ionic liquid as solvent.The microstructure and electrochemical properties of CMC/MWCNTs were studied using field emission scanning electron microscopy(FE-SEM),high-resolution transmission electron microscopy(HR-TEM),X-ray diffraction(XRD) system and electrochemical workstation.The experimental results indicated that the CMC dissolved with ionic liquid could be uniformly enwrapped on the surface of MWCNTs,and the coating thickness of CMC was about 5.4 nm.There are obvious oxidation peaks in the cyclic voltammograms curves of glassy carbon electrode coated with a CMC/MWCNT composite in H2O2 phosphate buffer solution.The MWCNT content and ultrasonic time strongly affected the dispersivity and electrochemical property of CMC/MWCNT composite.While the MWCNT content and ultrasonic processing time was 2 wt% and 2 h respectively,CMC/MWCNT composite exhibited excellent electrocatalytic activity.ZHAO TingKai LIU LeHao LI GuangMing DU Li ZHAO Xing YAN Jin CHENG YouLiang DANG ALei LI TieHu 2012Chinese Science Bulletin2012,57,14:3
12A 3D Geological Model Constrained by Gravity and Magnetic Inversion and its Exploration Implications for the World-class Zhuxi Tungsten Deposit, South China显示文摘The Zhuxi tungsten deposit in Jiangxi Province,South China,contains a total W reserve of about 2.86 Mt at an average grade of 0.54 wt%WO3,representing the largest W deposit in the world.Numerous studies on the metallogeny of the deposit have included its timing,the ore-controlling structures and sedimentary host rocks and their implications for mineral exploration.However,the deep nappe structural style of Taqian-Fuchun metallogenic belt that hosts the W deposit,and the spatial shape and scale of deeply concealed intrusions and their sedimentary host rocks are still poorly defined,which seriously restricts the discovery of new deposits at depth and in surrounding areas of the W deposit.Modern 3 D geological modeling is an important tool for the exploration of concealed orebodies,especially in brownfield environments.There are obvious density contrast and weak magnetic contrast in the ore-controlling strata and granite at the periphery of the deposit,which lays a physical foundation for solving the 3 D spatial problems of the ore-controlling geological body in the deep part of the study area through gravity and magnetic modeling.Gravity data(1:50000)and aeromagnetic data(1:50000)from the latest geophysical surveys of 2016-2018 have been used,firstly,to carry out a potential field separation to obtain residual anomalies for gravity and magnetic interactive inversion.Then,on the basis of the analysis of the relationship between physical properties and lithology,under the constraints of surface geology and borehole data,human-computer interactive gravity and magnetic inversion for 18 cross-sections were completed.Finally,the 3 D geological model of the Zhuxi tungsten deposit and its periphery have been established through these 18 sections,and the spatial shape of the intrusions and strata with a depth of 5 km underground were obtained,initially realizing―transparency‖for ore-controlling bodies.According the analysis of the geophysical,geochemical,and geological characteristics of the Zhuxi tungsten deposit,we discern three principles for prospecting and prediction in the research area,and propose five new exploration targets in its periphery.YAN Jiayong LÜ Qingtian QI Guang FU Guangming ZHANG Kun LAN Xueyi GUO Xin WEI Jin LUO Fan WANG Hao WANG Xu 2020Acta Geologica Sinica(English Edition)2020,94,6:3
13Morphological differences in skeletal muscle atrophy of rats with motor nerve and/or sensory nerve injury显示文摘Skeletal muscle atrophy occurs after denervation. The present study dissected the rat left ventral root and dorsal root at L4-6 or the sciatic nerve to establish a model of simple motor nerve injury, sensory nerve injury or mixed nerve injury. Results showed that with prolonged denervation time, rats with simple motor nerve injury, sensory nerve injury or mixed nerve injury exhibited abnormal behavior, reduced wet weight of the left gastrocnemius muscle, decreased diameter and cross-sectional area and altered ultrastructure of muscle cells, as well as decreased cross-sectional area and increased gray scale of the gastrocnemius muscle motor end plate. Moreover, at the same time point, the pathological changes were most severe in mixed nerve injury, followed by simple motor nerve injury, and the changes in simple sensory nerve injury were the mildest. These findings indicate that normal skeletal muscle morphology is maintained by intact innervation. Motor nerve injury resulted in larger damage to skeletal muscle and more severe atrophy than sensory nerve injury. Thus, reconstruction of motor nerves should be considered first in the clinical treatment of skeletal muscle atrophy caused by denervation.Lei Zhao Guangming Lv Shengyang Jiang Zhiqiang Yan Junming Sun Ling Wang Donglin Jiang 2012Neural Regeneration Research2012,7,32:3
14Influences of anion concentration and valence on dispersion and aggregation of titanium dioxide nanoparticles in aqueous solutions显示文摘Dispersion and aggregation of nanoparticles in aqueous solutions are important factors for safe application of nanoparticles. In this study, dispersion and aggregation of nano-TiO_2 in aqueous solutions containing various anions were investigated. The influences of anion concentration and valence on the aggregation size, zeta potential and aggregation kinetics were individually investigated. Results showed that the zeta potential decreased from 19.8 to-41.4 mV when PO_4^(3-) concentration was increased from 0 to 50 mg/L, while the corresponding average size of nano-TiO_2 particles decreased from 613.2 to 540.3 nm. Both SO_4^(2-) and NO_3^-enhanced aggregation of nano-TiO_2in solution. As SO_4^(2-) concentration was increased from 0 to 500 mg/L, the zeta potential decreased from 19.8 to 1.4 mV, and aggregate sizes increased from 613.2 to 961.3 nm.The trend for NO_3^- fluctuation was similar to that for SO_4^(2-) although the range of variation for NO_3^- was relatively narrow. SO_4^(2-) and NO_3^-accelerated the aggregation rapidly, while PO_4^(3-) did so slowly. These findings facilitate the understanding of aggregation and dispersion mechanisms of nano-TiO_2 in aqueous solutions in the presence of anions of interest.Huijun He 2017Journal of Environmental Sciences2017,29,4:2
15Natural variation of H3K27me3 modification in two Arabidopsis accessions and their hybrid显示文摘Histone modifications affect gene expression, but hthe mechanism and biological consequence of natural variation igin histone modifications remain unclear. Here, we generated Hgenome-wide integrated maps of H3K27me3 modification and transcriptome for Col, C24 and their F1 hybrid. A total of 1,828 genomic regions showing variation in H3K27me3 modification between Col and C24 were identified, most of which were associated with genic regions. Natural variation of H3K27me3 modification between parents could result in allelic bias of H3K27me3 in hybrids. Furthermore, we found that H3K27me3 variation between Col and C24 was negatively correlated with gene expression differences between two accessions, especially with those arising from the cis-effect. Importantly,mutation of CLF, an Arabidopsis methyltransferase for H3K27,altered gene expression patterns between the parents.Together, these data provide insights into natural variation of histone modifications and their association with gene expression differences between Arabidopsis ecotypes.Mei Yang Xuncheng Wang Hao Huang Diqiu Ren Yan'e Su Pan Zhu Danmeng Zhu Liumin Fan Liangbi Chen Guangming He Xing Wang Deng 2016Journal of Integrative Plant Biology2016,58,5:2
16Engineering core–shell Co_(9)S_(8)/Co nanoparticles on reduced graphene oxide: Efficient bifunctional Mott–Schottky electrocatalysts in neutral rechargeable Zn–Air batteries显示文摘It is significant for the rational construction of the high–efficient bifunctional electrocatalysts for in–depth understandings of how to improve the electron transfer and ion/oxygen transport in catalyzing oxygen reduction reaction and oxygen evolution reaction(ORR and OER),but still full of vital challenges.Herein,we synthesize the novel“three–in–one”catalyst that engineers core–shell Mott–Schottky Co_(9)S_(8)/Co heterostructure on the defective reduced graphene oxide(Co_(9)S_(8)/Co–rGO).The Co_(9)S_(8)/Co–rGO catalyst exhibits abundant Mott–Schottky heterogeneous–interfaces,the well–defined core–shell nanostructure as well as the defective carbon architecture,which provide the multiple guarantees for enhancing the electron transfer and ion/oxygen transport,thus boosting the catalytic ORR and OER activities in neutral electrolyte.As expected,the integrated core–shell Mott–Schottky Co_(9)S_(8)/Co–rGO catalyst delivers the most robust and efficient rechargeable ZABs performance in neutral solution electrolytes accompanied with a power density of 59.5 mW cm^(-2) and superior cycling stability at 5 mA cm^(-2) over 200 h.This work not only emphasizes the rational designing of the high–efficient bifunctional oxygen catalysts from the fundamental understanding of accelerating the electron transfer and ion/oxygen transport,but also sheds light on the practical application prospects in more friendly environmentally neutral rechargeable ZABs.Xingkun Wang Guangming Zhan Yurou Wang Yan Zhang Jian Zhou Ren Xu Huiyu Gai Huanlei Wang Heqing Jiang Minghua Huang 2022Journal of Energy Chemistry2022,31,5:2
17Experimental Investigation and Visualization Study of the Condensation Characteristics in a Propylene Loop Heat Pipe显示文摘At present,the structural design of a loop heat pipe(LHP)condenser mostly relies on experience.To analyze the condensation flow pattern in an LHP and to find a more accurate empirical correlation that can better guide condenser design in existing empirical correlations,a test system was designed and fabricated to observe the condensation phenomenon in the condenser and to evaluate the LHP’s heat transfer performance.Since propylene has a wide temperature range to different temperature control requirements,it was chosen as the working fluid.In this paper,the condensation process in the condenser was observed,and the operating parameters of a propylene LHP were measured at 283 K.The condensation flow patterns in the 2.5 mm×2.5 mm channel mainly included stratified flow,wavy flow and intermittent flow.By comparing the experimental results with four typical condensation flow regime maps,it was found that the Breber and Cavallini flow regime maps can successfully predict most of the condensation flow patterns of the LHP even with ultra-small mass flux.In addition,four condensation heat transfer coefficient correlations were selected to compare the predicted values of heat transfer coefficient with the experimental results.The study showed that the predicted values from the correlation by Cavallini et al.matched 90%of the experimental values well with an error of less than 20%,and this correlation is recommended for highly accurate LHP design.YAN Kaifenu XIE Rongjian LI Nanxi XU Guangming WU Yinong 2021Journal of Thermal Science2021,30,5:1
18Crystal structure of chiral binaphthol rare earth complexes and their catalysis in asymmetric transfer hydrogenation of acetophenone显示文摘Yan Pengfei Nie Chunhong Li Guangming 2006Appl Organometal Chem2006,20,6:1
19Application of a biosensor for monitoring of ethanol 显示文摘Wen Guangming Zhang Yan Shuang Shaomin 2007Biosensors and Bioelectronics2007,23,:1
20Overcoming muhidrug - re- sistance in vitro and in vivo using the novel P - glycoprotein inhibi- tor1416显示文摘Yan XU Feng ZHI Guangming X L 2012Biosci2012,,32:1
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