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| 1 | MiR-98 promotes chondrocyte apoptosis by decreasing Bcl-2 expression in a rat model of osteoarthritis显示文摘 | Jing Wang Lingqiang Chen Song Jin Jun Lin Hongmei Zheng Hong Zhang Hongtao Fan Fang He Sha Ma Qin Li | 2016 | Acta Biochimica et Biophysica Sinica2016，48，10： | 8 |
| 2 | Orthogonal design to sift the optimal parameter of Neiguan acupuncture for cerebral infarction显示文摘The individual difference and non-repeatability in acupuncture have not only restricted the development of acupuncture,but have also affected the specificity of acupoints.The present study used instruments to control needle depth,lifting and thrusting frequency,and the duration of acupuncture.Effects of the quantified acupuncture were observed at Neiguan(PC6)with different stimulation parameters.A frequency of 1,2,or 3 Hz and duration of 5,60,or 180 seconds were used to observe cerebral blood flow and ratio of infarct volume recovery.Results showed that stimulation at Neiguan with a frequency of 1 Hz and long duration of 180 seconds or 2/3 Hz and long duration of 5/60seconds significantly increased cerebral blood flow and decreased the ratio of infarct volume.Interactions between frequency and duration play a critical role in quantified acupuncture therapy. | Yanan Zhang Sha Yang Xiaonong Fan Shu Wang Nina He Lingxin Li Ding Luo Xuemin Shi | 2013 | Neural Regeneration Research2013，8，28： | 7 |
| 3 | A Distributed Approach of Big Data Mining for Financial Fraud Detection in a Supply Chain显示文摘Supply Chain Finance(SCF)is important for improving the effectiveness of supply chain capital operations and reducing the overall management cost of a supply chain.In recent years,with the deep integration of supply chain and Internet,Big Data,Artificial Intelligence,Internet of Things,Blockchain,etc.,the efficiency of supply chain financial services can be greatly promoted through building more customized risk pricing models and conducting more rigorous investment decision-making processes.However,with the rapid development of new technologies,the SCF data has been massively increased and new financial fraud behaviors or patterns are becoming more covertly scattered among normal ones.The lack of enough capability to handle the big data volumes and mitigate the financial frauds may lead to huge losses in supply chains.In this article,a distributed approach of big data mining is proposed for financial fraud detection in a supply chain,which implements the distributed deep learning model of Convolutional Neural Network(CNN)on big data infrastructure of Apache Spark and Hadoop to speed up the processing of the large dataset in parallel and reduce the processing time significantly.By training and testing on the continually updated SCF dataset,the approach can intelligently and automatically classify the massive data samples and discover the fraudulent financing behaviors,so as to enhance the financial fraud detection with high precision and recall rates,and reduce the losses of frauds in a supply chain. | Hangjun Zhou Guang Sun Sha Fu Xiaoping Fan Wangdong Jiang Shuting Hu Lingjiao Li | 2020 | Computers, Materials & Continua2020，，8： | 3 |
| 4 | Draft genome of the wheata-genome progenitor Triticum urartu显示文摘 | Ling HQ Zhao S Liu D Wang J Sun H Zhang C Fan H Li D Dong L Tao Y Gao C Wu H Li Y Cui Y Guo X Zheng S Wang B Yu K Liang Q Yang W Lou X Chen J Feng M Jian J Zhang X Luo G Jiang Y Liu J Wang Z Sha Y Zhang B WuH Tang D Shen Q Xue P Zou S Wang X Liu X Wang F Yang Y An X Dong Z Zhang K Zhang X Luo MC Dvorak J Tong Y Wang J Yang H Li Z Wang D Zhang A Wang J | 2013 | Nature2013，469，7443： | 1 |
| 5 | Correction for the dynamical electron-diffraction effect in crystal-structure analysis显示文摘 | Sha B D Fan H F Li F H | 1993 | Acta Crystallographica Section A1993，49，： | 1 |
| 6 | An invasive zone in human liver cancer identified by Stereo-seq promotes hepatocyte–tumor cell crosstalk,local immunosuppression and tumor progression显示文摘Dissecting and understanding the cancer ecosystem,especially that around the tumor margins,which have strong implications for tumor cell infiltration and invasion,are essential for exploring the mechanisms of tumor metastasis and developing effective new treatments.Using a novel tumor border scanning and digitization model enabled by nanoscale resolution-SpaTial Enhanced REsolution Omics-sequencing(Stereo-seq),we identified a 500µm-wide zone centered around the tumor border in patients with liver cancer,referred to as“the invasive zone”.We detected strong immunosuppression,metabolic reprogramming,and severely damaged hepatocytes in this zone.We also identified a subpopulation of damaged hepatocytes with increased expression of serum amyloid A1 and A2(referred to collectively as SAAs)located close to the border on the paratumor side.Overexpression of CXCL6 in adjacent malignant cells could induce activation of the JAK-STAT3 pathway in nearby hepatocytes,which subsequently caused SAAs’overexpression in these hepatocytes.Furthermore,overexpression and secretion of SAAs by hepatocytes in the invasive zone could lead to the recruitment of macrophages and M2 polarization,further promoting local immunosuppression,potentially resulting in tumor progression.Clinical association analysis in additional five independent cohorts of patients with primary and secondary liver cancer(n=423)showed that patients with overexpression of SAAs in the invasive zone had a worse prognosis.Further in vivo experiments using mouse liver tumor models in situ confirmed that the knockdown of genes encoding SAAs in hepatocytes decreased macrophage accumulation around the tumor border and delayed tumor growth.The identification and characterization of a novel invasive zone in human cancer patients not only add an important layer of understanding regarding the mechanisms of tumor invasion and metastasis,but may also pave the way for developing novel therapeutic strategies for advanced liver cancer and other solid tumors. | Liang Wu Jiayan Yan Yinqi Bai Feiyu Chen Xuanxuan Zou Jiangshan Xu Ao Huang Liangzhen Hou Yu Zhong Zehua Jing Qichao Yu Xiaorui Zhou Zhifeng Jiang Chunqing Wang Mengnan Cheng Yuan Ji Yingyong Hou Rongkui Luo Qinqin Li Liang Wu Jianwen Cheng Pengxiang Wang Dezhen Guo Waidong Huang Junjie Lei Shang Liu Yizhen Yan Yiling Chen Sha Liao Yuxiang Li Haixiang Sun Na Yao Xiangyu Zhang Shiyu Zhang Xi Chen Yang Yu Yao Li Fengming Liu Zheng Wang Shaolai Zhou Huanming Yang Shuang Yang Xun Xu Longqi Liu Qiang Gao Zhaoyou Tang Xiangdong Wang Jian Wang Jia Fan Shiping Liu Xinrong Yang Ao Chen Jian Zhou | 2023 | Cell Research2023，33，8： | 1 |
| 7 | Rhesus monkeys exhibiting spontaneous ritualistic behaviors resembling obsessive-compulsive disorder显示文摘Obsessive-compulsive disorder(OCD)is a chronic and debilitating psychiatric disorder that affects∼2%–3%of the population globally.Studying spontaneous OCD-like behaviors in non-human primates may improve our understanding of the disorder.In large rhesus monkey colonies,we found 10 monkeys spontaneously exhibiting persistent sequential motor behaviors(SMBs)in individual-specific sequences that were repetitive,time-consuming and stable over prolonged periods.Genetic analysis revealed severely damaging mutations in genes associated with OCD risk in humans.Brain imaging showed that monkeys with SMBs had larger gray matter(GM)volumes in the left caudate nucleus and lower fractional anisotropy of the corpus callosum.The GM volume of the left caudate nucleus correlated positively with the daily duration of SMBs.Notably,exposure to a stressor(human presence)significantly increased SMBs.In addition,fluoxetine,a serotonergic medication commonly used for OCD,decreased SMBs in these monkeys.These findings provide a novel foundation for developing better understanding and treatment of OCD. | Rongwei Zhai Geya Tong Zheqin Li Weichen Song Yang Hu Sha Xu Qiqi Wei Xiaocheng Zhang Yi Li Bingbing Liao Chenyu Yuan Yinqing Fan Ge Song Yinyin Ouyang Wenxuan Zhang Yaqiu Tang Minghui Jin Yuxian Zhang He Li Zhi Yang Guan Ning Lin Dan JStein Zhi-Qi Xiong Zhen Wang | 2023 | National Science Review2023，10，11： | 1 |
| 8 | Distribution and migration study of pesticides between peel and pulp in grape by online gel permeation chromatography–gas chromatography/mass spectrometry显示文摘 | Xiao-min Xu Sha Yu Rui Li Jun Fan Shi-hua Chen Hai-tao Shen Jian-long Han Bai-fen Huang Yi-ping Ren | 2012 | Food Chemistry2012，，1： | 1 |
| 9 | Discrimination of Ephedra plants with diffuse reflectance FT-NIRS and multivariate analysis显示文摘 | Qi Fan Yuanliang Wang Peng Sun Sha Liu Yang Li | 2009 | Talanta2009，，3： | 1 |
| 10 | Regeneration of the HZSM-5 zeolite deactivated in the upgrading of bio-oil via non-thermal plasma injection (NTPI) technology显示文摘 | Yongsheng Fan Yixi Cai Xiaohua Li Haiyun Yin Lei Chen Sha Liu | 2014 | Journal of Analytical and Applied Pyrolysis2014，，： | 1 |
| 11 | A two-year(2020–2021)observation of marine phycotoxins in phytoplankton in typical mariculture areas of East China Sea显示文摘To learn the marine phycotoxins(MPTs)contamination status in mariculture areas in the East China Sea(ECS),from May 2020 to October 2021,80 net-concentrated phytoplankton samples were collected from 12 stations in three typical areas with high incidence of red tides,namely,Gouqi Island,Sandu’ao-Lianjiang,and Zhangzhou-Dongshan Island in ECS,and MPTs of the samples were detected.Six types of toxins were detected in 24 samples from 9 stations.Lipophilic marine toxins(LMTs)were more common and diverse in these areas.Pectenotoxin 2(PTX2)was the main lipophilic marine toxin(LMT)in the concentrated phytoplankton samples and the occurrence showed seasonal differences from north to south.According to the potential risks of pectenotoxin(PTXs)to seafood safety,it is suggested to execute regular monitoring on PTXs in ECS and a mandatory standard should be formulated based on the comprehensive analysis of in-situ monitoring and lab research.Meanwhile,contamination risks of cyclic imine toxins in the north and domoic acid(DA)in the south of ECS should also be paid with attention to.Only 2 paralytic shellfish toxins(PSTs),N-sulfocarbamoyl toxin C2(C2),and decarbamoyl gonyatoxin 3(dcGTX3),were found from spring samples in the north of ECS.As the biggest mussel culture county of China,Gouqi Island showed higher toxin diversity and the toxin detection rate was higher than the other two areas.In Gouqi Island area,PSTs were a serious potential threat in spring,and LMTs instead of PSTs became the main risk in summer-autumn seasons.To ensure the safety of seafood and marine environmental health,it is recommended to conduct long-term targeted tracking and monitoring of MPTs in this and similar mariculture areas. | Xiaoqing TIAN Chengqi FAN Yunyu TANG Haiyan ZHANG Wei KANG Sha CHEN Chongbin LI Ya’nan LU | 2022 | Journal of Oceanology and Limnology2022，40，6： | 1 |
| 12 | Effect of Resistance Training,Aerobic Exercise Before Doula-Assisted Delivery on the Psychological Well-Being and Labor Duration of Parturients显示文摘Objective:To investigate the impact of resistance training and aerobic exercise before doula-assisted delivery on the psychological well-being and labor duration of parturients.Methods:105 cases of parturients who gave birth in our hospital from February 2021 to April 2023 were included in this study.The patients were divided into a control group of 52 cases and an observation group of 53 cases.The patients in the control group received no particular intervention before delivery and only received doula assistance.The patients in the observation group received resistance training,aerobic exercise,and doula assistance prior to giving birth.After delivery,the mothers were observed for 2 hours in the delivery room and then returned to the maternal and infant ward.The observation indicators of the two groups were compared.Results:In comparison to the control group,the observation group exhibited shorter durations in the first,second,and third stages of labor,as well as the total delivery time.Additionally,the amount of postpartum blood loss at 2 hours was smaller in the observation group.The rate of cesarean section was lower,and the rate of vaginal natural delivery was higher in the observation group.Following the intervention,both groups of postpartum women showed decreased SAS and SDS scores compared to before the intervention.Moreover,the observation group had lower scores than the control group.These differences were all statistically significant(P<0.05).Conclusion:Resistance training and aerobic exercise before doula-assisted delivery can effectively improve the psychological state of parturients,shorten labor duration,increase the rate of natural vaginal delivery,and reduce pain and postpartum hemorrhage. | Jing Zhou Sha Tang Li Zhou Cong Jiang Wenjian Fan | 2023 | Journal of Clinical and Nursing Research2023，7，6： | 0 |
| 13 | CFP1调控小鼠卵母细胞组蛋白H3K4me3修饰和发育潜质显示文摘文章简介受精过程中,合子DNA在卵母细胞中母源性因子的作用下发生重编程,促进合子基因组的重编程和转录激活,因此受精卵基因组重编程过程是表观遗传因子调控机制的理想模型,但调节机制很少被研究过。 | Chao Yu Xiaoying Fan Qian-Qian Sha Hui-Han Wang Bo-Tai Li Xing-Xing Dai Li Shen Junping Liu Lie Wang Kui Liu Fuchou Tang 范衡宇 | 2018 | 科学新闻2018，0，4： | 0 |
| 14 | Histological Assessment and Transcriptome Analysis Provide Insights into the Toxic Effects of Perfluorooctanoic Acid to Juvenile Half Smooth Tongue Sole Cynoglossus semilaevis显示文摘Perfluorooctanoic acid(PFOA)is a widespread synthetic persistent organic pollutant that may enrich along the food chain and affect the growth,development,reproduction,and lipid metabolism of aquatic organisms,particularly the benthic organisms.How-ever,the toxic effects of PFOA on the half-smooth tongue sole Cynoglossus semilaevis,a commercial benthic fish in China,have rarely been reported.Because juvenile fish are sensitive to environmental pollutants,in the present study,histological assessment and tran-scriptome sequencing were performed to determine the short-term impact of PFOA on juvenile half-smooth tongue soles.Histologi-cal analysis showed that PFOA exposure caused hepatocyte rupture,intestinal villi breakage,increased goblet cell count,and brain ab-normal.Transcriptome results showed that some interesting signaling pathways,such as glycolysis/gluconeogenesis,PPAR signaling pathway and GABAergic synapse signaling pathway,were enriched after PFOA exposure.In addition,some metabolic,immune and neural genes were differentially expressed,which including ependymin,hbb1-like and gad 1,and they were up-regulated after 14 days of exposure.Transcriptome results also indicated that half-smooth tongue sole might improve energy metabolism in response to PFOA toxicity after 7 days of exposure.These findings provide a basis for studying the ecological effects of PFOA on marine benthic fishes. | ZHAN Min SHI Kunpeng ZHANG Xue FAN Qingxin XU Qian LIU Xinbao LI Zhujun LIU Hongning XIA Yanting SHA Zhenxia | 2023 | Journal of Ocean University of China2023，22，6： | 0 |
| 15 | Determining Critical Support Discharge of a Riverhead and River Network Analysis: Case Studies of Lhasa River and Nyangqu River显示文摘A riverhead is the demarcation point of continuous water channel and seasonal channel, which is characterized by a critical flow that can support a continuous water body. In this study, the critical support discharge(CSD) is defined as the critical steady flows required to form the origin of a stream. The CSD is used as the criterion to determine the beginning of the riverhead, which can be controlled by hydro-climate factors(e.g., annual precipitation, annual evaporation, or minimum stream flow in arid season). The CSD has a close correlation with the critical support/source area(CSA) that largely affects the density of the river network and the division of sub-watersheds. In general, river density may vary with regional meteorological and hydrological conditions that have to be considered in the analysis. In this paper, a new model referring to the relationship of CSA and CSD is proposed, which is based on the physical mechanism for the origin of riverheads. The feasibility of the model was verified using two watersheds(Duilongqu Basin of the Lhasa River and Beishuiqu Basin of the Nyangqu River) in Tibet Autonomous Region to calculate the CSA and extract river networks. A series of CSAs based on different CSDs in derived equation were tested by comparing the extracted river networks with the reference network obtained from a digitized map of river network at large scales. Comparison results of river networks derived from digital elevation model with real ones indicate that the CSD(equal to criterion of flow quantity(Q_c)) are 0.0028 m^3/s in Duilongqu and 0.0085 m^3/s in Beishuiqu. Results show that the Q_c can vary with hydro-climate conditions. The Q_c is high in humid region and low in arid region, and the optimal Q_c of 0.0085 m^3/s in Beishuiqu Basin(humid region) is higher than 0.0028 m^3/s in Duilongqu Basin(semi-arid region). The suggested method provides a new application approach that can be used to determine the Q_c of a riverhead in complex geographical regions, which can also reflect the effect of hydro-climate change on rivers supply in different regions. | SHA Yukun LI Weipeng FAN Jihui CHENG Genwei | 2016 | Chinese Geographical Science2016，26，4： | 0 |
| 16 | Flexible mille-feuille structure electromagnetic interference shielding film with excellent thermal conductivity and Joule heating显示文摘The intelligent electronic devices have urgent demands for electromagnetic interference(EMI)shielding films with excellent heat dissipation capability.However,it is challenging to obtain excellent EMI shielding and thermal conductivity performances simultaneously.Herein,inspired by mille-feuille structure,the multifunctional EMI shielding films developed by a layer-by-layer self-assembly and hot-pressing strategy.The ingenious introduction of silver nanoparticles(AgNPs)with large specific surface area and highly conductive into the network formed by TEMPO-oxidized cellulose nanofibrils(TOCNFs)with large aspect ratio to form the TOCNFs/AgNPs.And the graphene nanoplates(GNPs)with high conductivity loss distributed alternately with TOCNFs/AgNPs to construct mille-feuille structure,which had highly efficient conductive network,complete thermally conduction pathway and rich heterogeneous interfaces.Consequently,the designed films presented high electrical conductivity of 8520 S/cm,superb EMI effectiveness(SE)of 98.05 dB,and excellent thermal conductivity of 18.82 W/(m·K).Furthermore,the films possessed outstanding Joule heating performances with low voltages,including high heating temperature(100℃),fast response time(<20 s),and impressive heating stability and reliability.Thus,such high-performance EMI shielding films with fascinating thermal conductivity and Joule heating performances have substantial application in flexible electronics,electromagnetic waves shielding and thermal management. | Dingwen Yin Huijuan Xiu Simin Wang Yanfei Pan Na Li Rui Cheng Shaoyan Huang Sha Fan Jinbao Li | 2024 | Nano Research2024，17，5： | 0 |
| 17 | Precise assembly and joining of silver nanowires in three dimensions for highly conductive composite structures显示文摘Three-dimensional(3D)electrically conductive micro/nanostructures are now a key component in a broad range of research and industry fields.In this work,a novel method is developed to realize metallic 3D micro/nanostructures with silver-thiol-acrylate composites via two-photon polymerization followed by femtosecond laser nanojoining.Complex 3D micro/nanoscale conductive structures have been successfully fabricated with∼200 nm resolution.The loading of silver nanowires(AgNWs)and joining of junctions successfully enhance the electrical conductivity of the composites from insulating to 92.9 Sm^−1 at room temperature.Moreover,for the first time,a reversible switching to a higher conductivity is observed,up to∼10^5Sm^−1 at 523 K.The temperature-dependent conductivity of the composite is analyzed following the variable range hopping and thermal activation models.The nanomaterial assembly and joining method demonstrated in this study pave a way towards a wide range of device applications,including 3D electronics,sensors,memristors,micro/nanoelectromechanical systems,and biomedical devices,etc. | Ying Liu Wei Xiong Da Wei Li Yao Lu Xi Huang Huan Liu Li Sha Fan Lan Jiang Jean-François Silvain Yong Feng Lu | 2019 | International Journal of Extreme Manufacturing2019，1，2： | 0 |
| 18 | Orange-derived extracellular vesicles nanodrugs for efficient treatment of ovarian cancer assisted by transcytosis effect显示文摘Extracellular vesicles(EVs)have recently received much attention about the application of drug carriers due to their desirable properties such as nano-size,biocompatibility,and high stability.Herein,we demonstrate orange-derived extracellular vesicles(OEV)nanodrugs(DN@OEV)by modifying cRGD-targeted doxorubicin(DOX)nanoparticles(DN)onto the surface of OEV,enabling significantly enhancing tumor accumulation and penetration,thereby efficiently inhibiting the growth of ovarian cancer.The obtained DN@OEV enabled to inducement of greater transcytosis capability in ovarian cancer cells,which presented the average above 10-fold transcytosis effect compared with individual DN.It was found that DN@OEV could trigger receptor-mediated endocytosis to promote early endosome/recycling endosomes pathway for exocytosis and simultaneously reduce degradation in the early endosomes-late endosomes-lysosome pathway,thereby inducing the enhanced transcytosis.In particular,the zombie mouse model bearing orthotopic ovarian cancer further validated DN@OEV presented high accumulation and penetration in tumor tissue by the transcytosis process.Our study indicated the strategy in enhancing transcytosis has significant implications for improving the therapeutic efficacy of thedrugdelivery system. | Feng Long Yao Pan Jinheng Li Suinan Sha Xiubo Shi Haoyan Guo Chuanqing Huang Qian Xiao Chao Fan Xingmei Zhang Jun-Bing Fan Ying Wang | 2023 | Acta Pharmaceutica Sinica B2023，13，12： | 0 |
| 19 | A metabolite of Danshen formulae (IDHP) induces angiogenesis and protects rat brains against focal ischemia via CaMKKβ/AMPK(Thr172)/eNOS(Ser1177) signaling显示文摘OBJECTIVE Only limited number of drugs are currently available for treating ischemic stroke.Therapeutic angiogenesis has recently emerged as one of the most promising therapies for cerebral ischemic injury.Isopropyl-β-(3,4-dihydroxyphenyl)-α-hydroxypropanoate(IDHP)is a metabolite derived from the botanical formulation for Dantonic®.Here,we investigated the angiogenic efficacy of IDHP in cerebral ischemia.METHODS The in vivo effects of IDHP were evaluated in the C57BL/6 mouse Matrigel plug and rat transient middle cerebral artery occlusion(tMCAO)models.Primary human umbilical vein endothelial cells(HUVEC)and human brain microvascular endothelial cells(HBMEC)were used to explore the effects of IDHP on stimulating proliferation,migration and tube formation in vitro.ELISA and Western blotting were used to quantitate the release and expression of relevant target molecules and signaling pathways.RESULTS IDHP reduced infarct volume and improved sensorimotor function in rats subjected to tMCAO by promoting angiogenesis,and promoted Matrigel neovascularization in mice.Moreover,IDHP produced a biphasic modulation on proliferation and migration both in HUVEC and HBMEC.It also induced tube formation in a 12-day HUVEC-HDF co-culture model and in Matrigel assays.IDHP-induced angiogenesis was accompanied by increased levels of p-AMPKα(Thr172)and p-eNOS(Ser1177)both in vitro and in vivo,and the decreased level of VEGF in rat brains on day 1 whereas enhanced level of VEGF on day 3 and 7 after tMCAO.Mechanistically,AMPK knockdown or pharmacologically inhibiting AMPK and its upstream kinases(CaMKKβ)inhibited the eNOS phosphorylation induced by IDHP in HUVEC.Furthermore,selective eNOS inhibitor(L-NIO),selective CaMKKβinhibitor(STO)and AMPKa inhibitor(Compound C)blocked the capillary-like tube formation in the co-culture model induced by IDHP(10 nmol·L^(-1)).CONCLUSION Collectively,these findings showed that IDHP protected rats from cerebral ischemia-reperfusion injury by promoting angiogenesis via activating CaMKKβ/AMPK(Thr172)/eNOS(Ser1177)signaling,and suggest it to be a promising new drug candidate for the prevention and/or treatment of cerebral ischemia and other vascular occlusive diseases. | LIAO Sha LIU Rui-min XU Dan-ni ZHU Ming-hui ZHAO Qi LUO Xian-lin LI Zhu LUO Quan-li FAN Tai-ping ZHENG Xiao-hui | 2021 | 中国药理学与毒理学杂志2021，35，10： | 0 |
| 20 | Few-Atom Copper Catalyst for the Electrochemical Reduction of CO to Acetate:Synergetic Catalysis between Neighboring Cu Atoms显示文摘Single-atom catalysts(SACs)are gaining increasing recognition because of their superior catalytic properties for various reactions.However,the performance of SACs is often limited by the lack of neighboring metal centers to cooperate in catalysis.Herein,a synergetic interaction between neighboring Cu atoms of a few-atom catalyst(FAC)on graphdiyne(GDY)is found to greatly enhance the production of acetate in the CO electroreduction reaction relative to Cu SACs.In a 1.0 M KOH electrolyte,this Cu FAC exhibits an acetate Faradaic efficiency of 53.8±1.5%,an ultrahigh relative purity of up to 97 wt%for liquid products,and excellent stability over 23 h continuous electrolysis at–0.8 V versus reversible hydrogen electrode.Theoretical studies suggest that the intersite catalytic communication between two neighboring metal atoms confined in each pore of GDY facilitates the formation of acetic acid through either stepwise hydrogenation of CH_(2)CO^(*)or the direct reaction of H_(2)Owith CH_(2)CO^(*).Our study demonstrates the unprecedented synergetic catalysis of Cu FAC in promoting the selective CO electroreduction toward acetate production. | Weifeng Rong Haiyuan Zou Sha Tan Enyuan Hu Fan Li Chao Tang Hao Dai Shuting Wei Yongfei Ji Lele Duan | 2023 | CCS Chemistry2023，5，5： | 0 |
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