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| 1 | Zeolite diagenesis and its control on petroleum reservoir quality of Permian in northwestern margin of Junggar Basin,China显示文摘Recently, silicate diagenesis has been the focus of many studies because of its impact on porosity and permeability in sedimentary rocks. In the process of diagenetic evolution, the crystallization, cementation, and corrosion of zeolite (as a diagenetic mineral) have different effects on properties of Permian reservoirs in the study area. In the Permian sediments in the northwestern margin of the Junggar Basin, Zeolite minerals have formed during diagenesis in an open hydrologic system, related to the hydration of abundant volcanic glass. Chemical property of groundwater, pH of pore water, cation property and ratios have directly influenced the transformation among various zeolites and the dissolution of zeolite mineral. The main species of zeolite include analcime, heulandite, and laumontite. Transformations of these minerals during diagenesis are: volcanic glass→ clinoptilolite→analcime→heulandite→laumontite. Corrosion of analcime obviously improved reservoir quality. Extensive heulandite cementation developed and intensively reduced reservoir pore spaces. Early zeolite cementation protected pore structure against compaction and provided substance for late dissolution. The dissolution of analcime was closely related with the organic acid recharged by hydrocarbon source rocks and the NaHCO3 type formation water in the Permian, and was sensitive to permeability of rocks. Within the CaCl2 type formation water, heulandite and laumontite were hardly dissolved. In the study area, the belt with dissolved analcime is the area for the development of secondary pores and favorable reservoirs. | ZHU ShiFa ZHU XiaoMin WANG XuLong LIU ZhenYu | 2012 | Science China Earth Sciences2012，55，3： | 27 |
| 2 | Study on multi-size seed-metering device for vertical plate soybean precision planter显示文摘Aiming to solve the problem of small range of the appropriately sowing seeds existing in a vertical disc seed-metering device,the planter plate series with four sizes were developed according to the variety and size distribution of all soybeans in China.The structure and working principle of the vertical disc soybean seed-metering device were detailed,and the influence of the diameter of soybean on the working performance of the seed-metering device was analyzed through the software EDEM virtual simulation,so as to achieve the goal of covering the soybean seeds with all sizes by the minimum planter plate series as well as to obtain the most appropriate operating speed of each planter plate by optimization.For the planter plates with the hole diameter of 7,9,12,16 mm,the appropriate size ranges of sowing seeds are 4.5-6.0,6.0-8.0,8.0-10.5,10.5-13.0 mm,respectively,and the appropriate operating speeds are 9,8,7,6 km/h,respectively.The results show that this planter plate series can meet the requirements of seeding with all sizes of soybeans at the range of the most appropriate operating speed.The study method can provide a reference for design and optimization of precision planters. | Liu Hongxin Guo Lifeng Fu Lulu Tang Shifa | 2015 | International Journal of Agricultural and Biological Engineering2015，8，1： | 13 |
| 3 | Genetic Mechanism of Dolomitization in Fengcheng Formation in the Wu-Xia area of Junggar Basin,China显示文摘The dolomitic rocks of the Fengcheng Formation are considered to be formed under special geologic conditions,and are significant hydrocarbon reservoir rocks in the Wu-Xia area in the Junggar Basin.Analyses of petrologic characteristics and stable isotope composition indicate that the dolomitizing host rock is volcanic and the dolomitizing fluids probably consists of brine from shore-shallow lakes with great evaporation and salinity in the Fengcheng Formation,which have formed under arid climatic conditions,as well as residual Mg-rich seawater from the underlying Jiamuhe Formation and Carboniferous.Dust tuff in the area has significant plagioclase content.Anorthite and labradorite hydrolysis by CO2 can be coupled with calcite precipitation.Late Mg-rich brine percolated and replaced calcite formed in the early time,which lead to precipitate dolostones with different occurrences,such as graniphyric,random bedded or lumpy.The diagenetic dolostones with different occurrences resulting from particular formation conditions occurred in different tectonic settings.The dolomitizing fluid has been driven by the thermal convection flow generated by volcanic eruptions.At the same time,the overthrusts of the Wu-Xia growth fault have speeded up the flow of deep Mg-rich water upwards,and induced the water to quickly penetrate and horizontally migrate in the strata.Fracture is the major and the most important reservoir space in dolomitic reservoir of the Fengcheng Formation.Fracture and fault plays a decisive role in controlling the formation of dolostone and the distribution of favorable reservoirs.The deliverability of oil and gas is determined by the development and match relations of dissolved pores and fractures to a certain degree. | ZHU Shifa ZHU Xiaomin NIU Huapeng HAN Xuefang ZHANG Yueqian YOU Xincai | 2012 | Acta Geologica Sinica(English Edition)2012，86，2： | 12 |
| 4 | Land-Use Spatial Optimization Based on PSO Algorithm显示文摘The optimization of land-use spatio-structure is one of the most important areas of land use management;constructing a spatial optimization model that is based on the micro spatial unit in a bottom-up mode plays an important role in coupling the quan-tity structure and spatial structure effectively.The objective of this research is to develop a land use spatial optimization model based on particle swarm optimization to make spatial decision in land use management.The model is implemented using real data-sets to emulate the process of spatial structure optimization in order to get the best landscape pattern under the control of decision environments.Simulation results revealed that the particle swarm optimization model has the ability to utilize the quantity and spa-tial structure.Furthermore,the result demonstrated that it can be used to stimulate the landscape pattern in designing the appropriate optimization environment,which could land quantity target to the basic spatial units effectively and provide appropriate spa-tio-structure for regional land use space layout decision making. | MA Shifa HE Jianhua LIU Feng YU Yan | 2011 | Geo-Spatial Information Science2011，14，1： | 8 |
| 5 | Reservoir differences and formation mechanisms in the Ke-Bai overthrust belt,northwestern margin of the Junggar Basin,China显示文摘There are some differences in reservoir quality of clastic rock between the hanging wall and the foot wall of the Ke-Bai overthrust belt,northwestern margin of the Junggar Basin,western China,which affect the effi cient petroleum exploration in this highly mature exploration area. Based on a large number of thin-sections,cast thin-sections,and physical property analysis of cores,we systematically discuss the Permian-Jurassic reservoir differences between the hanging wall and the foot wall of the Ke-Bai overthrust fault from the aspects of structural evolution,time-space distribution of the depositional system,diagenesis characteristics,and reservoir quality and analyzed the reasons for the differences in reservoir properties. The overthrusting of the Ke-Bai fault directly results in different burial histories,diagenesis evolution,and porosity evolution between the hanging wall and the foot wall. The differences of reservoir characteristics are mainly embodied in buried depth,grain size,sedimentary facies,diagenetic stage,and reservoir quality. The analysis results showed that burial history and depositional characteristics controlled by overthrusting are direct influencing factors of reservoir differences. Because of shallow burial depth of the hanging wall,the reservoir compaction is weak and primary pores are preserved well. The porosity of reservoir on the hanging wall is generally 10%-25%. The strata on the foot wall are deeply buried,and there are mainly mixed pores with the average porosity of 5%-20%. The favorable reservoir on the foot wall is generally developed near faults or in the channel sand bodies,which are usually dissolution development areas. | Zhu Xiaomin Zhu Shifa Xian Benzhong Chen Shuping Kuang Lichun Xue Xinke Xue Jingjing You Xincai | 2010 | Petroleum Science2010，7，1： | 7 |
| 6 | Multiple Dolomitization and Fluid Flow Events in the Precambrian Dengying Formation of Sichuan Basin, Southwestern China显示文摘The Precambrian Dengying Formation is a set of large-scale, extensively dolomitized, carbonate reservoirs occurring within the Sichuan Basin. Petrographic and geochemical studies reveal dolomitization was a direct result of precipitation by chemically distinct fluids occurring at different times and at different intensities. Based on this evidence, dolomitization and multiple fluid flow events are analyzed, and three types of fluid evolution models are proposed. Results of analysis show that Precambrian Dengying Formation carbonates were deposited in a restricted peritidal environment(630–542 Ma). A high temperature and high Mg^(2+) concentration seawater was a direct result of dolomitization for the micrite matrix, and for fibrous aragonite in primary pores. Geochemical evidence shows low δ^(18)O values of micritic dolomite varying from-1.29‰ to-4.52‰ PDB, abundant light rare earth elements(REEs), and low dolomite order degrees. Microbes and meteoric water significantly altered dolomite original chemical signatures, resulting in algal micritic dolomite and the fine-grained, granular, dolosparite dolomite having very negative δ^(18)O values. Finely crystalline cement dolomite(536.3–280 Ma) and coarsely crystalline cement dolomite have a higher crystallization degree and higher order degree. The diagenetic sequence and fluid inclusion evidence imply a linear correlation between their burial depth and homogenization temperatures, which closely resemble the temperature of generated hydrocarbon. Compared with finely crystalline dolomite, precipitation of coarsely crystalline dolomite was more affected by restricted basinal fluids. In addition, there is a trend toward a more negative δ^(18)O value, higher salinity, higher Fe and Mn concentrations, REE-rich. Two periods of hydrothermal fluids are identified, as the exceptionally high temperatures as opposed to the temperatures of burial history, in addition to the presence of high salinity fluid inclusions. The early hydrothermal fluid flow event was characterized by hot magnesium-and silicon-rich fluids, as demonstrated by the recrystallized matrix dolomite that is intimately associated with flint, opal, and microcrystalline quartz in intergranular or intercrystalline pores. This event was likely the result of a seafloor hydrothermal chimney eruption during Episode I of the Tongwan Movement(536.3±5.5 Ma). In contrast, later hydrothermal fluids, which caused precipitation of saddle dolomite, were characterized by high salinity(15–16.05 wt% NaCl equivalent) and homogenization temperatures(250 to 265°C), δ^(18)O values that were more enriched, and REE signatures. Geochemical data and the paragenetic sequence indicate that this hydrothermal fluid was related to extensive Permian large igneous province activity(360–280 Ma). This study demonstrates the presence of complicated dolomitization processes occurring during various paleoclimates, tectonic cycles, and basinal fluids flow; results are a useful reference for these dolomitized Precambrian carbonates reservoirs. | PENG Bo LI Zongxing LI Guorong LIU Chenglin ZHU Shifa ZHANG Wang ZUO Yinhui GUO Yingchun WEI Xiaojie | 2018 | Acta Geologica Sinica(English Edition)2018，92，1： | 5 |
| 7 | Chelating agents role on phase formation and surface morphology of single orthorhombic YMn_2O_5 nanorods via modified polyacrylamide gel route显示文摘YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tartaric acid is employed as the chelating agent.In the gel routes,oxalic acid was used as a carboxyl chelating agent,while citric acid or tartaric acid was a carboxyl and hydroxyl chelating agent.The as-prepared samples were characterized by means of techniques such as X-ray powder diffraction(XRD)measurement,thermogravimetric analysis(TG),differential scanning calorimetry analysis(DSC),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),thermal expansion measurement and field-emission scanning electron microscopy(SEM)investigations.It was found that oxalic acid is the best chelating agent with Y(NO3)3·6H2O and Mn(CH3COO)2·4H2O as precursors to prepare a single orthorhombic YMn2O5nanorods at 1000°C.Scanning electron microscope observation shows that the morphology of YMn2O5powders is significantly dependent on the chelating agent.The peaks(single orthorhombic YMn2O5nanorods)at 642,600,573,546,521,493,486,468,448 and 400cm?1were observed from FTIR spectra.The phase,surface morphology and chelation mechanisms of YMn2O5samples have been discussed on the basis of the experimental results. | WANG ShiFa ZHANG ChuanFei SUN GuangAi CHEN Bo XIANG Xia DING QingPing ZU XiaoTao | 2014 | Science China Chemistry2014，57，3： | 4 |
| 8 | Identification of abnormal conditions in high-dimensional chemical process based on feature selection and deep learning显示文摘Identification of abnormal conditions is essential in the chemical process.With the rapid development of artificial intelligence technology,deep learning has attracted a lot of attention as a promising fault identification method in chemical process recently.In the high-dimensional data identification using deep neural networks,problems such as insufficient data and missing data,measurement noise,redundant variables,and high coupling of data are often encountered.To tackle these problems,a feature based deep belief networks(DBN)method is proposed in this paper.First,a generative adversarial network(GAN)is used to reconstruct the random and non-random missing data of chemical process.Second,the feature variables are selected by Spearman’s rank correlation coefficient(SRCC)from high-dimensional data to eliminate the noise and redundant variables and,as a consequence,compress data dimension of chemical process.Finally,the feature filtered data is deeply abstracted,learned and tuned by DBN for multi-case fault identification.The application in the Tennessee Eastman(TE)process demonstrates the fast convergence and high accuracy of this proposal in identifying abnormal conditions for chemical process,compared with the traditional fault identification algorithms. | Wende Tian Zijian Liu Lening Li Shifa Zhang Chuankun Li | 2020 | Chinese Journal of Chemical Engineering2020，28，7： | 3 |
| 9 | Effects of the vegetation restoration years on soil microbial community composition and biomass in degraded lands in Changting County,China显示文摘We evaluated the effects of the number of years of restoration of vegetation on soil microbial community structure and biomass in degraded ecosystems.We investigated the microbial community structure by analyzing their phospholipid fatty acids then examined microbial biomass carbon and nitrogen by chloroform fumigation extraction of restoration soils over several years.The data were compared with those of highly degraded lands and native vegetation sites.The results show that the duration of vegetation on the sites substantially increased microbial biomass and shifted the microbial community structure even after only 4 years.However,microbial communities and biomass did not recover to the status of native vegetation even after 35 years of vegetation cover.A redundancy analysis and Pearson correlation analysis indicated that soil organic carbon,total nitrogen,available potassium,soil water content,silt content and soil hardness explained 98.4%of total variability in the microbial community composition.Soil organic carbon,total nitrogen,available potassium and soil water content were positively correlated with microbial community structure and biomass,whereas,soil hardness and silt content were negatively related to microbial community structure and biomass.This study provides new insights into microbial community structure and biomass that influence organic carbon,nitrogen,phosphorus and potassium accumulation,and clay content in soils at different stages of restoration. | Yonghui Bai Xuan Zha Shifa Chen | 2020 | Journal of Forestry Research2020，31，4： | 3 |
| 10 | Exploring Smart Growth Boundaries of Urban Agglomeration with Land Use Spatial Optimization:A Case Study of Changsha-Zhuzhou-Xiangtan City Group,China显示文摘Urban agglomeration is the main spatial organization mode used by the Chinese government to promote the policy of new urbanization strategy.Hence,a better understanding of the urban growth boundary(UGB)has profound theoretical and practical significance regarding sustainable urban development.This study devised a raster-based land use spatial optimization(LUSO)framework,and utilized ant colony optimization(ACO)algorithm to delimit the smart growth boundaries of the Changsha-Zhuzhou-Xiangtan city group(CZTCG)in China.The aim of this study is to design a LUSO model to explore an optimal pattern of urban agglomeration for sustainable growth.Multi growth scenario including a single development center,multipolar development and balanced development patterns are generated by the LUSO model for the year of 2050,and the optimum spatial pattern is chosen based on objectives comparison and the present stage of economic and social development in CZTCG.The main results are listed as the following.1)It is feasible to identify the growth boundaries of the urban agglomeration using the land use spatial optimization model,and the optimal form of the spatial pattern can be defined.2)With the growth trend of the urban agglomeration gradually spreads from a single center to multi-centers and even small towns,the total optimization target performance gradually increases,which means that the traditional pie-shaped development does not meet the maximum comprehensive benefit of the city group.3)Subject to the regional social and economic development stage,absolute fair development or simply developing the central city is not conducive to promoting the coordinated development of the urban agglomeration.Gradient equalization and gradual advancement are the best choice for UGB delineation of urban agglomeration.The findings of this study would be useful to identify the UGB in CZTCG for more sustainable urban development in the future. | MA Shifa ZHAO Yabo TAN Xiaohong | 2020 | Chinese Geographical Science2020，30，4： | 2 |
| 11 | A cellular automaton model for a bridge traffic bottleneck显示文摘A cellular automaton (CA) model is proposed in this paper to analyze a bridge traffic bottleneck. The simulation results with this model show that there are several phase transitions in the traffic average density, velocity and flow for each lane under a periodic boundary condition. An unstable phase in the traffic average density and velocity for the upstream and downstream lanes of the bridge is shown in a range of initial traffic densities. The critical points of the phase transitions and the phenomenon of the unstable phase found in the simulation are also explained with the mean-field theory. | Shifa Xiao Lingjiang Kong Muren Liu | 2005 | Acta Mechanica Sinica2005，21，3： | 2 |
| 12 | Selective growth of wide band gap atomically thin Sb2O3 inorganic molecular crystal on WS2显示文摘Heterostructures combined by different individual two-dimensional(2D)materials are essential building blocks to realize unique electronic,optoelectronic properties and multifunctional applications.To date,the direct growth of 2D/2D atomic van der Waals heterostructures(vdWHs)have been extensively investigated.However,the heterostructures from 2D inorganic molecular crystals and atomic crystals have been rarely reported.Here we report two-step direct epitaxial growth of the inorganic molecular-atomic Sb2O3/WS2 vdWHs.The thickness of Sb2O3 nanosheets on WS2 nanosheets can be tuned by variable growth temperatures.Oriented growth behavior of Sb2O3 on WS2 was determined through statistics.Optical images,Raman spectra,Raman mappings and selected-area electron diffraction(SAED),etc.,reveal that Sb2O3/WS2 heterostructures are vertically stacked with high crystal quality.Electrical transport measurements demonstrate that the heterotransistors based on the heterostructures possess high current on/off ratio of 5 × 10^5,obvious gate-tunable and current rectification output characteristics.Optoelectronic characterizations show that the heterostructures have a clear photoresponse with high responsivity of 16.4 AW.The growth of vdWHs from 2D inorganic molecular-atomic crystals may open up new opportunities in 2D functional electronics and optoelectronics. | Guangzhuang Sun Bo Li Shifa Wang Zhengwei Zhang Jia Li Xidong Duan Xiangfeng Duan | 2019 | Nano Research2019，12，11： | 2 |
| 13 | Development of bis-thiobarbiturates as successful urease inhibitors and their molecular modeling studies显示文摘Bis-thiobarbiturate derivatives 1–15 have been synthesized, characterized by1 HNMR and EI-MS and screened for urease inhibition. All compounds showed various degree of urease inhibitory activity with IC_(50) values ranging 7.45 0.12 74.24 0.81 mmol/L while the standard thiourea behaved normally(IC_(50) = 21.10 0.12). Compounds 1(IC_(50) = 7.45 0.12 μmol/L), 9(IC_(50) = 18.17 1.03 μmol/L) and 13(IC_(50) = 8.61 0.45 μmol/L) showed excellent urease inhibitory activity in the series. Molecular modeling studies were performed to understand the binding site with the bimetallic nickel center of the enzyme.Structure-activity relationship has also been established for these compounds. This study identified bisthiobarbiturate as a novel class of urease inhibitors. | Fazal Rahim Muhammad Ali Shifa Ullah Umer Rashid Hayat Ullah Muhammad Taha Muhammad Tariq Javed Wajid Rehman Aftab Ahmad Khan Obaid Ur Rahman Abid Muhammad Bilal | 2016 | Chinese Chemical Letters2016，27，5： | 2 |
| 14 | Simulation of the gas temperature deviation in large-scale tangential coal fired utility boilers显示文摘 | XU Minghou YUAN Jianwei DING Shifa | 1998 | Computer Methods inApplied Mechanics and Engineering1998，155，34： | 1 |
| 15 | Room Temperature Ferromagnetic n-type Semiconductor in (In1-xFex)2O3-σ 显示文摘 | He Jun Xu Shifa Young K | 2005 | Appl Phys Lett2005，86，05： | 1 |
| 16 | Strong phenyl-perfluorophenyl π-π stacking and C - H…F-C hydrogen bonding interactions in the crystals of the corresponding aromatic aldimines显示文摘 | Zhu Shizheng Zhu Shifa Jin Guifang | | 0，，15： | 1 |
| 17 | Development of far field and near field optical trapping 显示文摘 | Xin Huo Shi Pan Shifa Wu | 2005 | Chinese Optics Letters2005，，： | 1 |
| 18 | Transition-metal-catalyzed Formation of Trans Alkenes via Coupling of Aldehydes显示文摘 | Zhu Shifa Liao Yuanxi Zhu S Z | 2004 | Org Lett2004，6，3： | 1 |
| 19 | Effects of bismuth on structural and dielectric properties of cobalt-cadmium spinel ferrites fabricated via micro-emulsion route显示文摘Spinel ferrites have a significant role in high-tech applications.In the present work nano-crystalline ferrites having general formula Co0.5Cd0.5BixFe2-xO4 with(x=0.0,0.05,0.1,0.15,0.2,and 0.25)are synthesized via micro-emulsion route.Powder x-ray diffraction(XRD)studies discover the FCC spinel structure.Crystalline size is calculated in a range of 11 nm-15 nm.Lattice parameter calculations are reduced due to its substitution which leads to the exchange of large ionic radius of Fe^3+for small ionic radius of Bi^3+.The x-ray density is analyzed to increase with doping.Fourier transform infrared spectroscopy(FTIR)is performed to analyze absorption band spectra.The two absorption bands are observed in a range of 400 cm^-1-600 cm^-1,and they are the characteristic feature of spinel structure.Thermo-gravimetric analysis(TGA)reveals the total weight loss of nearly 1.98%.Dielectric analysis is carried out by impedance analyzer in a frequency span from 1 MHz to 3 GHz by using the Maxwell Wagner model.Dielectric studies reveal the decrease of dielectric parameters.The alternating current(AC)conductivity exhibits a plane behavior in a low frequency range and it increases with the applied frequency increasing.This is attributed to the grain effects in a high frequency range or may be due to the reduction of porosity.Real and imaginary part of impedance show the decreasing trend which corresponds to the grain boundary action.The imaginary modulus shows the occurrence of peak that helps to understand the interfacial polarization.Cole-Cole graph shows a single semicircle which confirms that the conduction mechanism is due to the grain boundaries at low frequency.Dielectric studies reveal the applicability of these ferrites in high frequency equipment,microwave applications,high storage media,and semiconductor devices. | Furhaj Ahmed Sheikh Muhammad Khalid Muhammad Shahzad Shifa H M Noor ul Huda Khan Asghar Sameen Aslam Ayesha Perveen Jalil ur Rehman Muhammad Azhar Khan Zaheer Abbas Gilani | 2019 | Chinese Physics B2019，28，8： | 1 |
| 20 | Development of far field and near field optical trapping显示文摘 | Xin Huo Shi Pan Shifa Wu | 2005 | Chinese Optics Letters2005，，： | 1 |
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