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| 1 | RNA-seq analysis of prostate cancer in the Chinese population identifies recurrent gene fusions, cancer-associated long noncoding RNAs and aberrant alternative splicings显示文摘在有前列腺癌症的不同赛跑的病人之中有显著不同;然而,位于这差别下面的机制仍然保持不清楚。这里,我们在场 transcriptome 的一处全面风景用 RNA-seq,越过关于基因熔化的前列腺癌症 transcriptomes 的揭示巨大的差异,长 noncoding RNA (长 ncRNA ) ,其他的拼接和体的变化从中国人口 14 主要前列腺癌症和他们的配对的正常对应物介绍。14 个肿瘤(21.4%) 中的三个在中国病人怀有 TMPRSS2 尔格熔化,和这熔化的低流行进一步在一个另外的肿瘤集合(10/54=18.5%) 被证实。尤其是,二新奇基因熔化, CTAGE5-KHDRBS3 (20/54=37%) 和 USP9Y-TTTY15 (19/54=35.2%) ,在我们的耐心的队经常发生了。介绍的进一步系统的 transcriptional 识别了是在肿瘤表示的差别的众多的长 ncRNAs。在长 ncRNA 和基因的表示之间的关联的分析建议长 ncRNAs 可以在 transcriptional 规定以外有功能。这研究在中国人口产出新卓见进前列腺癌症的致病。 | Shancheng Ren Zhiyu Peng Jian-Hua Mao Yongwei Yu Changjun Yin Xin Gao Zilian Cui Jibin Zhang Kang Yi Weidong Xu Chao Chen Fubo Wang Xinwu Guo Ji Lu Jun Yang Min Wei Zhijian Tian Yinghui Guan Liang Tang Chuanliang Xu Linhui Wang Xu Gao Wei Tian Jian Wang Huanming Yang Jun Wang Yinghao Sun | 2012 | Cell Research2012，22，5： | 66 |
| 2 | cMyc-mediated activation of serine biosynthesis pathway is critical for cancer progression under nutrient deprivation conditions显示文摘癌症房间被知道经历新陈代谢的 reprogramming 然而,支撑幸存和快速的增长 oncogenic 损害怎么在各种各样的强调条件下面协调新陈代谢的开关,尚待充分被阐明。这里,我们显示出葡萄糖或夫酸安的那剥夺,为癌症房间的二主要营养来源,被伴随由的戏剧性地激活的丝氨酸生合成小径(SSP ) 提高了 cMyc 表示。我们进一步鉴别那 cMyc 刺激了 SSP 激活由 transcriptionally 多重 SSP 酶的 upregulating 表示。而且,我们证明 cMyc 便于的 SSP 激活导致了提高的谷胱甘肽(GSH ) 生产,房间周期前进和 nucleic 酸合成,它在剥夺营养素的条件下面特别为房间幸存和增长是必要的。我们进一步揭开了那 phosphoserine 磷酸酶( PSPH ), SSP 小径的最后的限制率的酶,在 vitro 并且在 vivo 为 驾驶cMyc 的癌症前进是批评的,并且重要地, PSPH 的异常表示高度在 hepatocellular 与死亡被相关癌( HCC )病人,一般来说建议在这 调整cMyc 的酶,或 SSP 激活之间的一种潜在的原因的关系,并且癌症开发。一起拿,我们的结果表明 cMyc 的那异常表情导致提高的 SSP 激活,新陈代谢的开关的必要部分,在剥夺营养素的条件下面便于癌症前进。 | Linchong Sun Libing Song Qianfen Wan Gongwei Wu Xinghua Li Yinghui Wang Jin Wang Zhaoji Liu Xiuying Zhong Xiaoping He Shengqi Shen Xin Pan Ailing Li Yulan Wang Ping Gao Huiru Tang Huafeng Zhang | 2015 | Cell Research2015，25，4： | 33 |
| 3 | Spin-decoupled metasurface for simultaneous detection of spin and orbital angular momenta via momentum transformation显示文摘With inherent orthogonality,both the spin angular momentum(SAM)and orbital angular momentum(OAM)of photons have been utilized to expand the dimensions of quantum information,optical communications,and information processing,wherein simultaneous detection of SAMs and OAMs with a single element and a single-shot measurement is highly anticipated.Here,a single azimuthal-quadratic phase metasurface-based photonic momentum transformation(PMT)is illustrated and utilized for vortex recognition.Since different vortices are converted into focusing patterns with distinct azimuthal coordinates on a transverse plane through PMT,OAMs within a large mode space can be determined through a single-shot measurement.Moreover,spin-controlled dual-functional PMTs are proposed for simultaneous SAM and OAM sorting,which is implemented by a single spin-decoupled metasurface that merges both the geometric phase and dynamic phase.Interestingly,our proposed method can detect vectorial vortices with both phase and polarization singularities,as well as superimposed vortices with a certain interval step.Experimental results obtained at several wavelengths in the visible band exhibit good agreement with the numerical modeling.With the merits of ultracompact device size,simple optical configuration,and prominent vortex recognition ability,our approach may underpin the development of integrated and high-dimensional optical and quantum systems. | Yinghui Guo Shicong Zhang Mingbo Pu Qiong He Jinjin Jin Mingfeng Xu Yaxin Zhang Ping Gao Xiangang Luo | 2021 | Light(Science & Applications)2021，10，4： | 14 |
| 4 | Two soybean bHLH factors regulate response to iron deficiency显示文摘Iron is an indispensable micronutrient for plant growth and development. Limited bioavailability of Fe in the soil leads to iron deficiency chlorosis in plants and yield loss. In this study, two soybean basic helix-loophelix transcription factors, Gmb HLH57 and Gmb HLH300,were identified in response to Fe-deficiency. Both transcription factors are expressed in roots and nodules,and are induced by Fe deficiency; these patterns were confirmed in transgenic hairy roots expressing constructs of the endogenous promoters fused to a GUS reporter gene. Bimolecular fluorescence complementation, yeast two-hybrid and coimmunoprecipitation(co-IP) assays indicated a physical interaction between Gmb HLH57 and Gmb HLH300. Studies on transgenic soybeans Reseoverexpressing Gmb HLH57 and Gmb HLH300 revealed that overexpression of each transcription factor, alone,results in no change of the responses to Fe deficiency,whereas overexpression of both transcription factors upregulated the downstream Fe uptake genes and increased the Fe content in these transgenic plants.Compared to wild type, these double overexpression transgenic plants were more tolerant to Fe deficiency.Taken together, our findings establish that Gmb HLH57 and Gmb HLH300 are important transcription factors involved in Fe homeostasis in soybean. | Lin Li Wenwen Gao Qi Peng Bin Zhou Qihui Kong Yinghui Ying Huixia Shou | 2018 | Journal of Integrative Plant Biology2018，60，7： | 10 |
| 5 | Pre-oxidation with KMnO4 changes extra-cellular organic matter's secretion characteristics to improve algal removal by coagulation with a low dosage of polyaluminium chloride显示文摘Microcystis aeruginosa was used to study the effect of KMnO4 pre-oxidation on algal removal through coagulation with polyaluminium chloride (PAC).KMnO4 pre-oxidation improved the coagulation efficiency of algal at a low dosage of PAC.The optimal KMnO4 feeding period was in the stationary growth phase of Microcystis aeruginosa.KMnO4 traumatized the algal cells and stimulated cellular release of organic matter,contributing to the pool of extra-cellular organic matter (EOM).KMnO4 also decomposed EOM,especially small molecular weight EOM.Lower concentrations of KMnO4,such as 2 mg/L,induced algae cells to produce moderate amounts of new EOM with molecular weights of 11,280,and 1500 kDa.These relatively large molecules combined easily with PAC,promoting coagulation and removal of algae.High concentrations of KMnO4 lysed algae cells and produced much high-molecular-weight EOM that did not enhance flocculation by PAC at lower dosages. | Lei Wang Junlian Qiao Yinghui Hu Lei Wang Long Zhang Qiaoli Zhou Naiyun Gao | 2013 | Journal of Environmental Sciences2013，25，3： | 10 |
| 6 | A refined coherent point drift(CPD)algorithm for point set registration显示文摘The coherent point drift (CPD) algorithm is a powerful approach for point set registration. However, it suffers from a serious problem-there is a weight parameter w that reflects the assumption about the amount of noise and number of outliers in the Gaussian mixture model, and its value has an influence on the point set registration performance In the original CPD algorithm, the value of w is set manually, and hence an improper value will lead to poor registration results. To solve this problem, a fully automatic algorithm for the selection of an optimal weight parameter is proposed using a hybrid optimization scheme that combines the genetic algorithm with the Nelder-Mead simplex method. The experiments show that the refined CPD algorithm is more effective and extends the original CPD algorithm in its methodology and applications. | WANG Peng WANG Ping QU ZhiGuo GAO YingHui SHEN ZhenKang | 2011 | Science China(Information Sciences)2011，54，12： | 9 |
| 7 | QSobel:A novel quantum image edge extraction algorithm显示文摘Edge extraction is an indispensable task in digital image processing. With the sharp increase in the image data, real-time problem has become a limitation of the state of the art of edge extraction algorithms.In this paper, QSobel, a novel quantum image edge extraction algorithm is designed based on the flexible representation of quantum image(FRQI) and the famous edge extraction algorithm Sobel. Because FRQI utilizes the superposition state of qubit sequence to store all the pixels of an image, QSobel can calculate the Sobel gradients of the image intensity of all the pixels simultaneously. It is the main reason that QSobel can extract edges quite fast. Through designing and analyzing the quantum circuit of QSobel, we demonstrate that QSobel can extract edges in the computational complexity of O(n2) for a FRQI quantum image with a size of2 n × 2n. Compared with all the classical edge extraction algorithms and the existing quantum edge extraction algorithms, QSobel can utilize quantum parallel computation to reach a significant and exponential speedup.Hence, QSobel would resolve the real-time problem of image edge extraction. | ZHANG Yi LU Kai GAO YingHui | 2015 | Science China(Information Sciences)2015，58，1： | 8 |
| 8 | Modeling of gas-solid flow in a CFB riser based on computational particle fluid dynamics显示文摘A three-dimensional model for gas-solid flow in a circulating fluidized bed(CFB) riser was developed based on computational particle fluid dynamics(CPFD).The model was used to simulate the gas-solid flow behavior inside a circulating fluidized bed riser operating at various superficial gas velocities and solids mass fluxes in two fluidization regimes,a dilute phase transport(DPT) regime and a fast fluidization(FF) regime.The simulation results were evaluated based on comparison with experimental data of solids velocity and holdup,obtained from non-invasive automated radioactive particle tracking and gamma-ray tomography techniques,respectively.The agreement of the predicted solids velocity and holdup with experimental data validated the CPFD model for the CFB riser.The model predicted the main features of the gas-solid flows in the two regimes;the uniform dilute phase in the DPT regime,and the coexistence of the dilute phase in the upper region and the dense phase in the lower region in the FF regime.The clustering and solids back mixing in the FF regime were stronger than those in the DPT regime. | Zhang Yinghui Lan Xingying Gao Jinsen | 2012 | Petroleum Science2012，9，4： | 6 |
| 9 | A Review of Research Progress in the Genesis of Colloform Pyrite and Its Environmental Indications显示文摘Colloform pyrite is a special form of nano-micro polycrystalline aggregation growth, for which a suitable term is 'aggregates of nano-micro crystals'. This kind of colloform texture is observed in various geological bodies, such as ancient sedimentary rocks, modern marine and lake sediments, various types of ore deposits, and modern seafloor hydrothermal vents. This paper summarizes the latest developments and research into the definition, formation mechanisms, and environmental indications of colloform pyrite. There appears to be three main formation mechanisms of colloform pyrite: pseudomorphic replacement; biogenic precipitation; and inorganic precipitation. The morphology, particle size, trace element content and preferential growth orientations of colloform pyrite microcrystals can be important indicators for sedimentary environments, hydrothermal activity, and ore-forming processes. We suggest that the microscopic features of nano-micro crystals in colloform pyrite and their aggregation growth patterns need further investigation. The relationships between formation mechanisms of colloform pyrite, organic activity and depositional environments require further exploration. To reveal the nature of nano-micro grain aggregation growth in colloform pyrite and analyse its growth environment and evolutionary history, it is supposed to apply nanoscientific and nanotechnological methods, further integrate consideration of macroscopic geological backgrounds and microscopic mineral growth phenomena, combine high-resolution imaging systems and in situ quantitative microanalysis methods and constitute a mergence of earth science, thermodynamics and kinetics, life science, material science, and chemistry in the study. | GAO Shang HUANG Fei WANG Yinghui GAO Wenyuan | 2016 | Acta Geologica Sinica(English Edition)2016，90，4： | 4 |
| 10 | Coupling Effect of Morphology and Mechanical Properties Contributes to the Tribological Behaviors of Snake Scales显示文摘 | Long Zheng Yinghui Zhong Yihang Gao Jiayi Li Zhihui Zhang Zhenning Liu Luquan Ren | 2018 | Journal of Bionic Engineering2018，15，3： | 4 |
| 11 | Adrenomedullin promotes the odontogenic differentiation of dental pulp stem cells through CREB/BMP2 signaling pathway显示文摘Adrenomedullin (AM ) 能支持增长, odontogenic 区别并且禁止牙齿的肉干细胞(DPSC ) 的 apoptosis。在有 DPSC 的联合的 AM 可以是为肉修理的有效策略。然而,在 DPSC 的 odontogenic 区别的 AM 的机制上没有报告。这研究的目的是调查 AM 通过支持 DPSC 的 odontogenic 区别的分子的机制。刚提取的智慧牙齿从 27 个病人被获得。在到经过 5 的经过 3 点的房间在这研究被使用。DPSC 在 Dulbeccos 被对待与或没有 10 7 M AM 修改的鹰中等文化,然后积累的钙免职被使用染色的茜素红 S 在 21 天以后分析。Odontogenic 区别标记被西方的污点分析和量的即时 PCR 决定。西方的污点分析结果证明 AM 有支持 DPSC 和 AM 的区别能提高的 odontogenic 的能力 CREB 和起来调整的 phosphorylation BMP2 的表示。H89 是能通过禁止 CREB 的 phosphorylation 禁止 DPSC 的 odontogenic 区别的一个 CREB 禁止者。少量能通过禁止 BMP2 的活动禁止 DPSC 的 odontogenic 区别。这些结果显示 AM 能由 upregulating 支持 DPSC 的 odontogenic 区别通过发信号的 CREB 的 BMP2 的表示小径。 | Qiang Zhu Jianyong Gao Gang Tian Zhen Tang Yinghui Tan | 2017 | Acta Biochimica et Biophysica Sinica2017，49，7： | 4 |
| 12 | Tailoring active color rendering and multiband photodetection in a vanadium-dioxide-based metamaterial absorber显示文摘Metamaterials have demonstrated exotic electromagnetic properties, which offer a good platform for realizing light absorption, photodetection, filtering, and so on. However, broadband multifunctional metamaterial absorbers are restricted in cascaded structures. Here, broadband multifunctional properties were realized by introducing vanadium dioxide into a metamaterial absorber. Through the modified design and highly efficient utilization of multiple resonant modes, both plasmonic tunable color filters and near-infrared photodetectors can be simultaneously achieved by this construction. Meanwhile, active color and a photodetection band in the near-infrared range can become tunable with the insulating–metallic transition of vanadium dioxide. Thus, the variations of rendering colors could correspondingly indicate shifts of the near-infrared photodetection bands. This method theoretically confirms the feasibility of designing multifunctional devices via a vanadium-dioxide-based metamaterial absorber, which holds great promise for future versatile utilization of multiple physical mechanisms to achieve numerous functionalities in a simple nanostructure or device. | SHICHAO SONG XIAOLIANG MA MINGBO PU XIONG LI YINGHUI GUO PING GAO XIANGANG LUO | 2018 | Photonics Research2018，6，6： | 4 |
| 13 | FORCED WAVE PROPAGATION IN VISCOELASTIC CABLE WITH SMALL SAG显示文摘Based on the linear viscoelastic differential constitutive law and cable structural model, the coupled longitudinal-transverse waves that propagate along a viscoelastic cable with small curvature is investigated. A mathematical model is presented that describes the three-dimensional nonlinear response of a viscoelastic cable. An asymptotic form of this model is obtained for the linear response of cables having small equihbrium curvature. The spectral relation governing the propagating waves is derived using transform methods. The spectral relation is employed in deriving a Green's function that is then used to construct solutions for in-plane response under distributed harmonic excitation. Analysis of forced response reveals the existence of two types of periodic waves that propagate through the cable, one characterizing extension-comprehensive deformation and the other characteristic transverse deformation. | Li Yinghui Jian Kailin~1 Gao Qing Yin Xuegang~1 (Department of Applied Mechanics and Engineering, Southwest Jiaotong University, Chengdu 610031, China) (1 State Key Laboratory of Mechanical Transmission, Chongqing University, Chongqing 400044, China) | 2001 | Acta Mechanica Solida Sinica2001，14，2： | 4 |
| 14 | Identification of a novel seed size associated locus SW9-1 in soybean显示文摘Seed size is one of the vital traits determining seed appearance, quality, and yield. Untangling the genetic mechanisms regulating soybean 100-seed weight (100-SW), seed length and seed width across environments may provide a theoretical basis for improving seed yield. However, there are few reports related to QTL mapping of 100-SW across multiple ecological regions. In this study, 21 loci associated with seed size traits were identified using a genome-wide association of 5361 single nucleotide polymorphisms (SNPs) across three ecoregions in China, which could explain 8.12%–14.25% of the phenotypic variance respectively. A new locus, named as SW9-1 on chromosome 9 that explained 10.05%–10.93% of the seed weight variance was found significantly related to seed size traits, and was not previously reported. The selection effect analysis showed that SW9-1 locus has a relatively high phenotypic effect (13.67) on 100-SW, with a greater contribution by the accessions with bigger seeds (3.69) than the accessions with small seeds (1.66). Increases in seed weight were accompanied by increases in the frequency of SW9-1T allele, with >90% of the bred varieties with a 100-SW >30 g carrying SW9-1T. Analysis of SW9-1 allelic variation in additional soybean accessions showed that SW9-1T allele accounting for 13.83% of the wild accessions, while in 46.55% and 51.57% of the landraces and bred accessions, respectively, this results indicating that the SW9-1 locus has been subjected to artificial selection during the early stages of soybean breeding, especially the utilization of SW9-1T in edamame for big seed. These results suggest that SW9-1 is a novel and reliable locus associated with seed size traits, and might have an important implication for increasing soybean seed weight in molecular design breeding. Cloning this locus in future may provide new insights into the genetic mechanisms underlying soybean seed size traits. | Jiajia Li Jinghui Zhao Yinghui Li Yali Gao Sunan Hua Muhammad Nadeem Genlou Sun Wenming Zhang Jinfeng Hou Xiaobo Wang Lijuan Qiu | 2019 | The Crop Journal2019，7，4： | 4 |
| 15 | NONLINEAR VIBRATION ANALYSIS OF VISCOELASTIC CABLE WITH SMALL SAG显示文摘Both the inplane and out-of-plane transverse vibrations of a viscoelastic cable subjected to aninitial stress distributing uniform on the cross section are studied.The constitution of the cable material is as-sumed to be of the hereditary integral type.The partial differential-integral equations of motion are derivedfirst.Then by applying Galerkin’s method,the governing equations are reduced to a set of second-order non-linear differential-integral equations which are solved by finite difference numerical integration procedures.Finally,the effects of the viscosity parameter and the elaslic parameter on the transient amplitudes of the firstmode are investigated by numerical simulation. | Li Yinghui Jian Kailin Gao Qing Yin Xuegang | 2001 | Acta Mechanica Solida Sinica2001，14，4： | 3 |
| 16 | Integrating global socio-economic influences into a regional land use change model for China显示文摘与快速的经济开发和都市化,在中国的陆地使用在最近的年里经历了巨大的变化;并且这以后将可能继续。在中国的陆地使用问题是迫切的并且需要推进学习。快速的陆地使用变化和经济开发为综合陆地使用变化研究使中国成为一个理想的区域,特别地多重因素的考试和在全球经济集成的上下文的全球地区性的相互作用。这份报纸论述一条综合建模途径在使用在地区性的规模改变的土地上检验全球社会经济的过程的影响。我们由联合一个简单全球社会经济的模型(GLOBFOOD ) 和地区性的空间分配模型(线索) 开发一个综合模型系统。模型系统用一个应用程序被说明在中国打使用。为一个给定的气候变化,人口生长,和各种各样的社会经济的状况,一个全球社会经济的模型在陆地使用上模仿全球市场和经济的影响,并且确定不同土地的变化使用类型。空间分发模型决定的陆地使用在由采用一个加权的适用性索引的每个空间格子很适当的陆地使用的类型,源于生态系统国家和地点条件的专家知识。一系列模型模拟将被进行并且分析了表明综合模型的能力与使用在中国改变的地区性的土地连接全球社会经济的因素。结果在中国允许陆地使用和风景的未来动力学的探索[出版摘要] | Xia XU Qiong GAO Changhui PENG Xuefeng CUI Yinghui LIU Li JIANG | 2014 | Frontiers of Earth Science2014，8，1： | 2 |
| 17 | Correlation of chloride diffusion coefficient and microstructure parameters in concrete: A comparative analysis using NMR,MIP, and X-CT显示文摘Permeability is a major indicator of concrete durability,and depends primarily on the microstructure characteristics of concrete,including its porosity and pore size distribution.In this study,a variety of concrete samples were prepared to investigate their microstructure characteristics via nuclear magnetic resonance(NMR),mercury intrusion porosimetry(MIP),and X-ray computed tomography(X-CT).Furthermore,the chloride diffusion coefficient of concrete was measured to explore its correlation with the microstructure of the concrete samples.Results show that the proportion of pores with diameters<1000 nm obtained by NMR exceeds that obtained by MIP,although the difference in the total porosity determined by both methods is minimal.X-CT measurements obtained a relatively small porosity;however,this likely reflcts the distribution of large pores more accurately.A strong correlation is observed between the chloride diffusion coefficient and the porosity or contributive porosity of pores with sizes<1000 nm.Moreover,microstructure parameters measured via NMR reveal a lower correlation coefficient R2 versus the chloride diffusion coefficient relative to the parameters determined via MIP,as NMR can measure non-connected as well as connected pores.In addition,when analyzing pores with sizes>50 um,X-CT obtains the maximal contributive porosity,followed by MIP and NMR. | Yurong ZHANG Shengxuan XU Yanhong GAO Jie GUO Yinghui CAO Junzhi ZHANG | 2020 | Frontiers of Structural and Civil Engineering2020，14，6： | 2 |
| 18 | Contour detection improved by frequency domain filtering of gradient image显示文摘We propose an intermediate computational step,frequency domain filtering of gradient image,to improve contour detection performance of gradient-based edge detectors.This step is inspired by analyzing the spectrum distribution of object contours and texture edges in the frequency domain of gradient image.We illustrate the principle and efect of this step by adding it to the Canny edge detector.The resulting operator can selectively retain object contours and region boundaries,and meanwhile can dramatically reduce non-meaningful elements caused by textured background.We use several types of images to compare the proposed method and other related methods qualitatively and quantitatively.Experimental results show that the proposed method can efectively enhance the contour detection of Canny edge detector and achieves similar detection performance to two other related methods but runs faster. | QU ZhiGuo GAO YingHui WANG Ping WANG Peng TAN XianSi SHEN ZhenKang | 2014 | Science China(Information Sciences)2014，57，1： | 2 |
| 19 | Synthetic vector optical fields with spatial and temporal tunability显示文摘As an intrinsic nature of light,polarization plays a critical role in the vectorial characteristic of optical fields.Vector optical fields with an inhomogeneous polarization distribution show many exotic phenomena and applications not existing in scalar optical fields.Existing polarization optics,however,mainly focuses on the manipulation of polarization distribution on a single transverse plane.Here,we propose a synthetic approach to realize polarization manipulation with spatial and temporal degrees.The underlying mechanism relies on decoupling two orthogonal polarization states through asymmetric photonic spin-orbit interactions to obtain customer-tailored phase and amplitude difference in both transverse and longitudinal space,thereby changing the resulting polarization distribution at will in three-dimensional(3 D)space.Remarkably,a longitudinally varied cylindrical vector field is experimentally demonstrated by a monolayer metasurface,in which the polarization distribution switches continuously and periodically between radial and azimuthal polarization.Furthermore,the vector field can be dynamically tuned by rotating the incident polarization state.Our work extends polarization optics from two-dimensional space to 3 D space,allowing the arbitrary generation and manipulation of 3D vector optical fields with temporal tunability. | Fei Zhang MingBo Pu YingHui Guo XiaoLiang Ma Xiong Li Ping Gao XianGang Luo | 2022 | Science China(Physics,Mechanics & Astronomy)2022，65，5： | 2 |
| 20 | Dynamic dispersion stability of graphene oxide with metal ions显示文摘Graphene oxide(GO),an important chemical precursor of graphene,can stably disperse in aqueous surrounding and undergo aggregation as metal cations introduced.The usual instability of GO with ions is caused by the shielding effect of ions and crosslinking between GO and ions.However,the dynamic stability of GO under ions exchange still remains unclear.Here,we investigated the dynamic dispersion stability of GO with metal ions and observed a redispersion behavior in concentrated Fe3+solution,other than permanent aggregation.The exchange with Fe3+ions drives the reversion of zeta(ζ)potential and enables the redispersion to individual GO-Fe3+complex sheets,following a dynamic electric double layer(EDL)mechanism.It is found that the specifically strong electrostatic shielding effect and coordination attraction between Fe3+and functional oxygen groups allows the selective redispersion of GO in concentrated Fe3+solution.The revealed dynamic dispersion stability complements our understanding on the dispersive stability of GO and can be utilized to fabricate graphene-metal hybrids for rich applications. | Yinghui He Yingjun Liu Fan Guo Kai Pang Bo Fang Ya Wang Dan Chang Zhen Xu Chao Gao | 2020 | Chinese Chemical Letters2020，31，6： | 2 |
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