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| 1 | A 12R long-period stacking-ordered structure in a Mg-Ni-Y alloy显示文摘A hitherto unreported long-period stacking-ordered(LPSO) phase, designated 12 R, was observed in a Mg_(80)Ni_5Y_(15)(at.%) alloy. Microstructure was investigated by electron diffraction and high-angle annular dark-field scanning transmission electron microscopy. Results show that the 12 R has a trigonal lattice(a = b = 1.112 nm, c = 3.126 nm, α = β = 90°, and γ = 120°). Unit cell of the 12 R is consisted of three ABCAtype building blocks and each building block contains dominant Ni_6 Y_8-type building clusters. A sound structural model is proposed based on relative positions of Ni_6 Y_8 clusters in neighboring building blocks. | Cheng Liu Yuman Zhu Qun Luo Bin Liu Qinfen Gu Qian Li | 2018 | Journal of Materials Science & Technology2018,34,12: | 7 |
| 2 | Simulation of regional land subsidence in the southern Yangtze Delta显示文摘Investigation of the deformation characteristics of individual hydrostratigraphic units is the key to construct a regional land subsidence model. All of 12 hydrostratigraphic units in the study area were discussed throughout. On the basis of the measured data of groundwater level, five kinds of changing patterns of groundwater level were deduced and the relationship between the deformation characteris-tics of aquifer units and the corresponding changing patterns of groundwater level was discussed. The study area is 1.7×104 km2, where the geological condition is complex. The changing patterns of groundwater level the hydrostratigraphic units have experienced vary from site to site and from time to time. Consequently, the deformation characteristics of units are sophisticated. An identical hydros-tratigraphic unit may exhibit different deformation characteristics, such as elasticity, elasto-plasticity, visco-elasticity, and visco-elasto-plasticity, at different sites or during different periods, not to mention the different units. The existing models are difficult to describe the complex visco-elasto-plastic con-stitutive law under the condition of land subsidence. So the Merchant’s model was modified to depict the visco-elasto-plastic behavior of units. Then a three-dimensional flow model with variable parame-ters and a vertical one-dimensional subsidence model were constructed and coupled. The coupled model was applied in simulating land subsidence in the southern Yangtze Delta and a satisfactory re-sult was obtained. The simulation results show that the new coupled model can depict the complex geological conditions and describe the developing process of land subsidence very well in the south-ern Yangtze Delta. The new model can surely be used to predict land subsidence in the future, which is very helpful to taking measurements to control land subsidence. | XUE YuQun WU JiChun ZHANG Yun YE ShuJun SHI XiaoQing WEI ZiXin LI QinFen YU Jun | 2008 | Science China Earth Sciences2008,51,6: | 6 |
| 3 | Severity of early allograft dysfunction following donation after circulatory death liver transplantation:a multicentre study显示文摘Background:Early allograft dysfunction(EAD)is associated with decreased graft and patient survival rates.This study aimed to identify the severity of EAD and develop a predictive model for EAD after donation after circulatory death(DCD)liver transplantation(LT).Furthermore,the influence of operative time on EAD incidence was also evaluated.Methods:In this retrospective,multicentre cohort study,nomograms were established based on a single-centre training cohort(n=321)and validated in a 3-center validation cohort(n=501).Results:The incidence rate of EAD was 46.4%(149/321)in the training cohort and 40.5%(203/501)in the validation cohort.Of the 149 EAD patients in the training cohort,77 patients with either elevated alanine aminotransferase(ALT)or aspartate aminotransferase(AST)were classified as having EAD type A,and the rest of the EAD patients were classified as having EAD type B.Recipients with EAD type B had lower graft and patient survival rates than recipients with EAD type A(P=0.043 and 0.044,respectively).We further developed a nomogram to predict EAD(graft weight,cold ischemia time,donor age,model for end-stage liver disease(MELD)score)and another nomogram to predict EAD type B(graft weight,cold ischemia time,MELD score).The nomograms for the prediction of EAD and EAD type B had good discrimination[concordance index(C-index)=0.712(0.666-0.758),0.707(0.641-0.773)]and calibration[Hosmer-Lemeshow(HL)P=0.384,P=0.425]in the validation cohort.An increased operative time(>6 h)was associated with increased EAD and EAD type B incidence in the high-risk group(P=0.005,P=0.020,respectively).Conclusions:EAD type B was associated with decreased graft and patient survival rates.The novel nomograms effectively predicted the incidence of EAD and EAD type B in DCD LT patients. | Kun Wang Di Lu Yuhui Liu Wangyao Li Li Zhuang Zhenyu Ma Qinfen Xie Binhua Pan Yichao Wu Junli Chen Lidan Lin Xiaowen Feng Qiang Wei Xuyong Wei Haiyang Xie Zhengxin Wang Shusen Zheng Xiao Xu | 2021 | Hepatobiliary Surgery and Nutrition2021,10,1: | 4 |
| 4 | Space qualification mechanical tests of HTS filters for satellite application显示文摘High performance high-temperature superconducting (HTS) filters have been designed and constructed for satellite application. The filters are actually a superconducting integration of an 8-pole band-pass filter with an adjustable band-stop filter onto a single piece of LaAlO3 substrate (with dimension of 0.5×45×20 mm3). Typical results of the filters, i.e., Filters A (made by YBCO) & B (made by TBCCO) will be reported. The measured responses of Filter A showed excellent specifications, e.g., an insertion loss less than 0.1 dB, a return loss better than -22.5 dB in pass-band, band-edge steepness greater than 12 dB/MHz and out-of-band rejection at a certain band deeper than -110 dB. To satisfy the requirement of rocket launch and space operation, three filters of the above design have undergone mechanical environmental simulation tests for space qualification. Detailed analysis of the response curves of Filter B measured before and after the tests showed that no noticeable change in the per-formance can be found. All the filters passed the rigorous ground simulation tests, which is the first time in China for HTS devices and provided a solid foundation for satellite applications of high-temperature superconductors in the near future. | HUANG JianDong SUN Liang LI ShunZhou MENG QingDuan ZHANG Qiang LI Fei ZHANG XueQiang LI ChunGuang HE AiSheng LI Hong GU ChangZhi LUO Qiang SUN QinFen WANG XiaoLin SUN YiFan WANG ZhiBing WANG YunFei LUO Sheng HE YuSheng | 2007 | Chinese Science Bulletin2007,52,13: | 3 |
| 5 | An Integrated Approach to Automatic Management of Virtualized Resources in Cloud Environments显示文摘 | LI Qiang HAO Qinfen XIAO Liming | 2011 | Computer Journal2011,54,6: | 1 |
| 6 | Therapeutic effect of human umbilical cord mesenchymal stem cells on neonatal rat hypoxic–ischemic encephalopathy显示文摘 | Xinhua Zhang Qinfen Zhang Wei Li Dekang Nie Weiwei Chen Chunxiang Xu Xin Yi Jinhong Shi Meiling Tian Jianbing Qin Guohua Jin Wenjuan Tu | 2014 | Journal of Neuroscience Research2014,,1: | 1 |
| 7 | Molecular characterization of StNAC2 in potato and its overexpression confers drought and salt tolerance 显示文摘 | Xu Qinfen He Qin Li Shuai | 2014 | Acta Physiologie Plantarum2014,36,: | 1 |
| 8 | Therapeutic Effect of Human Umbilical Cord Mesenchymal Stem Cells on Neonatal Rat Hypoxic-Ischemic Encephalopathy 显示文摘 | Xinhua Zhang Qinfen Zhang Wei Li | 2014 | Journal of Neuroscience Re- search2014,92,1: | 1 |
| 9 | Boosting nitrogen electrocatalytic fixation by three-dimensional TiO_(2-δ)N_δnanowire arrays显示文摘Owing to the environmental and inherent advantages,nitrogen reduction reaction(NRR)by electrocatalysts attracts global attention.The surface engineering is widely employed to enhance the electrocatalytic activity by atomic defects and heterostructure effects.A three-dimensional(3D)free-standing integrated electrode was fabricated by numerous nearly-single-crystal TiO_(2-δ)N_δnanowire arrays.Based on the high electronic conductivity network,it exposes numerous active sites as well to facilitate the selective nitrogen adsorption and*H adsorption suppression.The synergistic effects between Ti^(3+)and oxygen vacancy(O_v)boost the intrinsic catalytic activity,in which Ti^(3+)acquired electrons via Ovcan effectively activate the N≡N bond and make it easy to bind with protons.The energy barrier of primary protonation process(*N_(2)+H^(+)+e^(-)→*NNH)can be dramatically decreased.The highest ammonia yield rate(14.33μg h^(-1)mgcat^(-1))emerges at-0.2 V,while the optimal ammonia Faradaic efficiency(9.17%)is acquired at-0.1 V.Density functional theory(DFT)calculation reveals that the Ti^(3+)can be served as the active sites for nitrogen adsorption and activation,while ammonia synthesis is accomplished by the distal pathway.The high electronic conductivity integrated network and synergistic effects can significantly facilitate nitrogen absorption and accelerate electrocatalytic reaction kinetic,which are responsible for the excellent NRR performance at room temperature. | Jianjia Mu Xuan-Wen Gao Zhaomeng Liu Wen-Bin Luo Zhenhua Sun Qinfen Gu Feng Li | 2022 | Journal of Energy Chemistry2022,,12: | 1 |
| 10 | Aquifer Thermal storage:a numerical simulation of field experiments in China显示文摘 | Xue Yuqun Xie Chunhong Li Qinfen | | 0,,10: | 1 |
| 11 | Co‑packaged optics(CPO):status,challenges,and solutions显示文摘Due to the rise of 5G,IoT,AI,and high-performance computing applications,datacenter trafc has grown at a compound annual growth rate of nearly 30%.Furthermore,nearly three-fourths of the datacenter trafc resides within datacenters.The conventional pluggable optics increases at a much slower rate than that of datacenter trafc.The gap between application requirements and the capability of conventional pluggable optics keeps increasing,a trend that is unsustainable.Copackaged optics(CPO)is a disruptive approach to increasing the interconnecting bandwidth density and energy efciency by dramatically shortening the electrical link length through advanced packaging and co-optimization of electronics and photonics.CPO is widely regarded as a promising solution for future datacenter interconnections,and silicon platform is the most promising platform for large-scale integration.Leading international companies(e.g.,Intel,Broadcom and IBM)have heavily investigated in CPO technology,an inter-disciplinary research feld that involves photonic devices,integrated circuits design,packaging,photonic device modeling,electronic-photonic co-simulation,applications,and standardization.This review aims to provide the readers a comprehensive overview of the state-of-the-art progress of CPO in silicon platform,identify the key challenges,and point out the potential solutions,hoping to encourage collaboration between diferent research felds to accelerate the development of CPO technology. | Min Tan Jiang Xu Siyang Liu Junbo Feng Hua Zhang Chaonan Yao Shixi Chen Hangyu Guo Gengshi Han Zhanhao Wen Bao Chen Yu He Xuqiang Zheng Da Ming Yaowen Tu Qiang Fu Nan Qi Dan Li Li Geng Song Wen Fenghe Yang Huimin He Fengman Liu Haiyun Xue Yuhang Wang Ciyuan Qiu Guangcan Mi Yanbo Li Tianhai Chang Mingche Lai Luo Zhang Qinfen Hao Mengyuan Qin | 2023 | Frontiers of Optoelectronics2023,16,1: | 1 |
| 12 | Adsorption of Dissolved Organic Matter by Ferrallitic Soils显示文摘Batch experiments and XAD resin were used to investigate the adsorption of dissolved organic matter(DOM) by ferrallitic soils. The effects of soil properties and DOM characteristics on the adsorption were also studied to reveal the adsorption mechanism. The results showed that:(1) ferrallitic soils were high in DOM adsorption capacity,which increased with initial DOM concentrations,and the kinetics of DOM adsorption in the ferrallitic soils can be divided into the two stages: fast and slow reactions,it could be better fitted by first-order model;(2) the adsorption isotherms of DOM on ferrallitic soils could be better fitted by Freundlich equation,indicating the adsorption process was a physical multilayer adsorption process;( 3) for different soils,the adsorption capacity of DOM was listed as follows: rhodic ferralsol > haplic ferralsol > paddy soil,for example,adsorbing capacity of compost DOM was up to 594. 906,309. 317 and 206. 316 mg / kg in the initial concentration of 50 mg / L,positively correlated with CEC,free iron oxide,free aluminium oxide and clay content,while negatively correlated with sand content;(4) for different DOMs,higher hydrophobic DOM had the larger adsorption capacity,which listed as follows: compost DOM( H-DOM) > soil DOM( M-DOM) > straw DOM( L-DOM);(5) for different DOM components,the adsorption capacity decreased as follows: hydrophobic neutrals( HON) > acid-insoluble matter( AIM) > hydrophobic bases( HOB) > hydrophobic acids( HOA) > hydrophillic matter( HIM),and the chain structure of aliphatic alkanes and higher aromaticity in DOM were the key factors influencing adsorption capacity as revealed by fourier-transform infrared spectroscopy( FT-IR);(6)the contribution to DOM adsorption by different fractions was the result of their adsorption capacities and contents. For different hydrophobic DOM,hydrophobic matter's contribution( HO) was more than HIM,up to 69. 43%85. 08%. For different polar fractions,H-DOM: HOA( 40. 24%) > HON( 39.10%) > HIM( 14.92%) > AIM( 3.82%) > HOB( 1.88%); L-DOM: HOA( 33. 50%) > HIM( 30. 57%) > HON( 24. 81%) > AIM( 7. 45%) > HOB( 3.68%);( 7) The presence of native DOM in soil impeded the exotic DOM adsorption by soil,especially for high hydrophobic DOM. | Wu Chunyuan Wu Dongming Li Qinfen | 2016 | Meteorological and Environmental Research2016,7,6: | 1 |
| 13 | Aquifer thermal energy storage:a numerical simulation of field experiments in China显示文摘 | XUE Yuquan XIE Chunhong LI Qinfen | 1990 | Water Resources Research1990,26,10: | 1 |
| 14 | Biodegradation of chlorpyrifos and 3,5,6-trichloro-2-pyridinol by Cupriavidus sp. DT-1显示文摘 | Peng Lu Qinfen Li Hongming Liu Zhaozhong Feng Xin Yan Qing Hong Shunpeng Li | 2013 | Bioresource Technology2013,,: | 1 |
| 15 | Metal-organic framework-derived carbon nanotubes with multi-active Fe-N/Fe sites as a bifunctional electrocatalyst for zinc-air battery显示文摘Sustainable metal-air batteries demand high-efficiency,environmentally-friendly,and non-precious metal-based electrocatalysts with bifunctionality for both the oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).In this research,novel functional carbon nanotubes with multi-active sites including well-dispersed single-atom iron throughout the walls and encapsulated ultrafine iron nanoparticles were synthesized as an electrocatalyst(FeNP@Fe-N-C)through one-step pyrolysis of metal-organic frameworks.High-resolution synchrotron powder X-ray diffraction and X-ray absorption spectroscopy were applied to characterize the unique structure of the electrocatalyst.In comparison to the commercial Pt/C and Ru O_(2)electrodes,the newly prepared FeNP@Fe-N-C presented a superb bifunctional performance with its narrow potential difference(Egap)of 0.73 V,which is ascribed to the metallic Fe nanoparticles that boosts the adsorption and activation of oxygen on the active sites with an enhanced O_(2)adsorption capacity of 7.88 cm^(3)g^(-1)and synergistically functionalizes the iron atoms dispersed on the nanotubes.A rechargeable zinc-air battery based on FeNP@Fe-N-C exhibited a superior open-circuit voltage(1.45 V),power density(106.5 m W cm^(-2)),and stable cycling performance.The green technique developed in this work for the fabrication of functional nanotubes raises the prospect of making more efficient electrocatalysts for sustainable energy cells. | Chao Yang Shanshan Shang Qinfen Gu Jin Shang Xiao-yan Li | 2022 | Journal of Energy Chemistry2022,31,3: | 1 |
| 16 | Negative thermal expansion and phase transition of low-temperature Mg_(2)NiH_(4)显示文摘The negative thermal expansion(NTE) phenomenon is of great significance in fabricating zero thermal expansion(ZTE) materials to avoid thermal shock during heating and cooling. NTE is observed in limited groups of materials, e.g., metal cyanides, oxometallates, and metalorganic frameworks, but has not been reported in the family of metal hydrides. Herein, a colossal and continuous negative thermal expansion is firstly developed in the low-temperature phases of LT1-and LT2-Mg_(2)NiH_(4) between 488 K and 733 K from in-situ transmission electron microscope(TEM) video, with the volume contraction reaching 18.7% and 11.3%, respectively. The mechanisms for volume contraction of LT1 and LT2 phases are elucidated from the viewpoints of phase transformation, magnetic transition, and dehydrogenation, which is different from common NTE materials containing flexible polyhedra units in the structure. The linear volume shrinkage of LT2 in the temperature of 488-553 K corresponds to the phase transition of LT2→HT with a thermal expansion coefficient of -799.7 × 10^(-6) K^(-1) revealed by in-situ synchrotron powder X-ray diffraction. The sudden volume contraction in LT1 between 488 and 493 K may be caused by the rapid dehydrogenation of LT1 to Mg_(2)Ni. The revealed phenomenon in single composite material with different structures would be significant for preparing zero thermal expansion materials by tuning the fraction of LT1 and LT2 phases. | Qun Luo Qi Cai Qinfen Gu Yu Shi Bin Liu Xuan Quy Tran Syo Matsumura Tong-Yi Zhang Kazuhiro Nogita Tao Lyu Qian Li Fusheng Pan | 2023 | Journal of Magnesium and Alloys2023,11,9: | 0 |
| 17 | Enhanced performance of field-effect transistors based on C_(60) single crystals with conjugated polyelectrolyte显示文摘Contact resistance at the interface between metal electrodes and semiconductors can significantly limit the performance of organic field-effect transistors,leading to a distinct voltage drop at the interface.Here,we demonstrate enhanced performance of n-channel field-effect transistors based on solution-grown C_(60) single-crystalline ribbons by introducing an interlayer of a conjugated polyelectrolyte(CPE) composed of poly[(9,9-bis(3'-((N,N-dimethyl)-N-ethylamnionium)-propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)]dibromide(PFN^+Br^-).The PFN^+Br^-interlayer greatly improves the charge injection.Consequently,the electron mobility is promoted up to 5.60 cm^2V^(-1) s^(-1) and the threshold voltage decreased dramatically with the minimum of4.90 V. | Qinfen Li Jiake Wu Ruihan Wu Yujing Liu Hongzheng Chen Fei Huang Hanying Li | 2017 | Science China Chemistry2017,60,4: | 0 |
| 18 | Hydrogen storage performance and phase transformations in as-cast and extruded Mg-Ni-Gd-Y-Zn-Cu alloys显示文摘Thermal-mechanical processing of magnesium-based materials is an effective method to tailor the hydrogen storage performance.In this study,Mg-Ni-Gd-Y-Zn-Cu alloys were prepared by Direct Chill(DC)casting,with and without extrusion process.The influences of microstructure evolution,introduced by DC casting and thermal-mechanical processing,on the hydrogen storage performance of Mg-Ni-Gd-Y-ZnCu alloys were comprehensively explored,using analytical electron microscopy and in-situ synchrotron powder X-ray diffraction.The result shows that the extruded alloy yields higher hydrogen absorption capacity and faster hydrogen ab/desorption kinetics.As subjected to extrusion processing,theα-Mg grains in the microstructure were significantly refined and a large number of 14H type long-period stacking ordered(LPSO)phases appeared on theα-Mg matrix.After activation,there were more nanosized Gd hydride/Mg2Ni intermetallics and finer chips.These modifications synergistically enhance the hydrogen storage properties.The findings have implications for the alloy design and manufacturing of magnesiumbased hydrogen storage materials with the advantages of rapid mass production and anti-oxidation. | Hu Yao Guang Zeng Xin FTan Qinfen Gu Kazuhiro Nogita Jing Guo Qian Li | 2023 | Journal of Materials Science & Technology2023,,20: | 0 |
| 19 | N-doped graphitic carbon encapsulating cobalt nanoparticles derived from novel metal–organic frameworks for electrocatalytic oxygen evolution reaction显示文摘Nitrogen-doped carbon catalysts with hierarchical porous structure are promising oxygen evolution reaction(OER)catalysts due to the faster mass transfer and better charge carrying ability.Herein,an exquisite high nitrogen-containing ligand was designed and readily synthesized from the low-cost biomolecule adenine.Accordingly,three new MOFs(TJU-103,TJU-104 and TJU-105)were prepared using the Co(II)or Mn(II)ions as metal nodes.Through rationally controlling pyrolysis condition,in virtue of the high nitrogen content in well-defined periodic structure of the pristine MOFs,TJU-104–900 among the derived MOFs with hierarchical porous structure,i.e.,N-doped graphitic carbon encapsulating homogeneously distributed cobalt nanoparticles,could be conveniently obtained.Thanks to the synergistic effect of the hierarchical structure and well dispersed active components(i.e.,C=O,Co–Nx,graphitic C and N,pyridinic N),it could exhibit an overpotential of 280 mV@10mA/cm^(2)on carbon cloth for OER activity.This work provides the inspiration for fabrication of nitrogen-doped carbon/metal electrocatalysts from cost-effective and abundant biomolecules,which is promising for practical OER application. | Yuanmeng Tian Hao Wu Aamir Hanif Yanli Niu Ying Yin Yangyi Gu Zuofeng Chen Qinfen Gu Yun Hau Ng Jin Shang Liangchun Li Mingxian Liu | 2023 | Chinese Chemical Letters2023,34,8: | 0 |
| 20 | Boosting photocatalytic activity through tuning electron spin states and external magnetic fields显示文摘Photocatalysis is considered as one of the most promising technologies to generate renewable energy and degrade environmental pollutants.Tremendous efforts have been made to improve photocatalytic efficiency.Among these,tuning spin polarization and introducing an external magnetic field are considered two promising strategies to boost photocatalytic performance.Herein this review highlights the recent breakthroughs through manipulating spin states and applying external magnetic fields for enhancing photocatalytic reactions.The relevant characterization techniques and fundamental mechanisms are summarized.Spin polarization states of photocatalysts have received considerable attention due to their unique roles,including inhibiting the recombination of photoexcited carriers owing to spin orientation constraint,enhancing the reaction product selectivity,and reducing the reaction barriers via optimizing the absorption energy and binding strength.As for the effects of external magnetic field on photocatalytic performance,we mainly discuss the separation enhancement of photoinduced carriers under static and time-varying magnetic fields and the magneto-hydrodynamic effect of charged particles.Lastly,the negative magnetoresistance effect is discussed due to the synergistic effects of the electron spin state and an external magnetic field.These discussions in this review may provide new insights into designing new semiconductors for boosting photocatalytic performance in internal and external magnetic fields. | Chengxiao Peng Wenjuan Fan Qian Li Wenna Han Xuefeng Chen Guangbiao Zhang Yuli Yan Qinfen Gu Chao Wang Huarong Zhang Peiyu Zhang | 2022 | Journal of Materials Science & Technology2022,,20: | 0 |